Investigation of kinetics of steam reforming of C3-C4 hydrocarbons by aerosol nanocatalysis technology

Authors

  • Марат Аронович Глікін Volodymyr Dahl East Ukrainian National University Soviet Ave, 59a, Severodonetsk, Luhansk region., 93400, Ukraine
  • Саіф Махммод Volodymyr Dahl East Ukrainian National University Soviet Ave, 59a, Severodonetsk, Luhansk region., 93400, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2013.12264

Keywords:

Steam conversion, hydrocarbons, aerosol catalysis, vibroliquated layer, synthesis-gas temperature, product yield, activation energy, degree of conversion

Abstract

Having analyzed the existing technologies of hydrocarbon conversion and their disadvantages, we proposed to apply the technology of aerosol nanocatalysis to get the synthesis-gas. The process was implemented in a reactor with a vibroliquated layer of the catalytic system (dispersive stuff and the catalyst powder). Such instrument design of steam conversion of С3-С4 hydrocarbons increased the reaction rate, the degree of conversion of stuff and reduced the concentration of catalyst in the reaction zone up to 2,5-25 г/м3 of the reactor. The studied NiO catalyst showed high activity and product yield close to equilibrium. We studied the effect of temperature on the process of steam conversion of hydrocarbons. As a result of mathematical processing of the data, we have defined the order of the reaction and the activation energy, which amounted to 178 kJ / mol that permitted suggesting the kinetic region of the reaction

Author Biographies

Марат Аронович Глікін, Volodymyr Dahl East Ukrainian National University Soviet Ave, 59a, Severodonetsk, Luhansk region., 93400

Doctor of Technical Sciences, professor

Department of Technology of organic substances, fuels and polymers

Саіф Махммод, Volodymyr Dahl East Ukrainian National University Soviet Ave, 59a, Severodonetsk, Luhansk region., 93400

Applicant

Department of Technology of organic substances, fuels and polymers

References

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Published

2013-04-25

How to Cite

Глікін, М. А., & Махммод, С. (2013). Investigation of kinetics of steam reforming of C3-C4 hydrocarbons by aerosol nanocatalysis technology. Eastern-European Journal of Enterprise Technologies, 2(6(62), 11–16. https://doi.org/10.15587/1729-4061.2013.12264

Issue

Vol. 2 No. 6(62) (2013): Technologies of organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2014 Марат Аронович Глікін, Саіф Махммод

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