The influence of surfactants on rheology of water dispersions of wollastonite

Authors

  • Олексій Володимирович Миронюк National Technical University of Ukraine "Kyiv Polytechnic Institute" Peremohy Ave, 37, Kiev, 03056, Ukraine https://orcid.org/0000-0003-0499-9491
  • Олексій Олексійович Сікорський National Technical University of Ukraine "Kyiv Polytechnic Institute" Peremohy Ave, 37, Kiev, 03056, Ukraine https://orcid.org/0000-0002-3730-2016
  • Валентин Анатолійович Свідерський National Technical University of Ukraine "Kyiv Polytechnic Institute" Peremohy Ave, 37, Kiev, 03056, Ukraine https://orcid.org/0000-0002-4457-6875

DOI:

https://doi.org/10.15587/1729-4061.2013.12277

Keywords:

Wollastonite, surfactants, modification, suspension, rheological behavior, grain-size particle distribution

Abstract

Despite a great number of studies on the rheology of water suspensions of fillers up to now there is no systematic approach to evaluate the influence of surfactants of different nature on the stability and rheological properties of microfillers. The article presents the study of interaction of wollastonite with different characteristic relations of sides with surfactants of anionic and non-ionic type, which is interesting from both technological and economical point of view, since it would significantly alter the rheological properties of compositions. It was found that the introduction of surfactants to the system decreases significantly the rheological characteristics; and that the anionic modifiers decrease the stability of coagulation structure of suspensions, leading to transition from pseudoplastic to dilatant behavior. Further studies of ways to increase the stability of the modified systems are planned, with low values of dynamic indices and pseudoplastic behavior of suspensions, using a range of non-selective aluminosilicate thickeners with respect to specified surfactants

Author Biographies

Олексій Володимирович Миронюк, National Technical University of Ukraine "Kyiv Polytechnic Institute" Peremohy Ave, 37, Kiev, 03056

Ph.D., assistant

The chair of polymer and composite materials

Олексій Олексійович Сікорський, National Technical University of Ukraine "Kyiv Polytechnic Institute" Peremohy Ave, 37, Kiev, 03056

Graduate

The chair of polymer and composite materials

Валентин Анатолійович Свідерський, National Technical University of Ukraine "Kyiv Polytechnic Institute" Peremohy Ave, 37, Kiev, 03056

Doctor of Technical Sciences, Professor

The chair of polymer and composite materials

References

  1. Свідерський, В. А. Визначення ступеня контакту між плівкоутворювачем та наповнювачем в композиційних покриттях методом хроматографії [Текст] / В. А. Свідерський, О. В. Миронюк // Вісник національного технічного університету „ХПІ”. – 2008. – № 39. – С. 9–18.
  2. Permen, T. The rheological and colloidal properties of bentonite dispersions in the presence of organic compounds V. Bentonite and sodium montmorillonite and surfactants [Text] / T. Permen, G. Lagaly // Clay and clay minerals. – 1995. – Vol. 43, №2. – Р. 229–236.
  3. Mikanovic, N. Influence of Surfactant Chemical Admixtures on the Stability and Rheological Properties of Calcium Carbonate and Cement Pastes [Text] / N. Mikanovic, C. Jolicoeur and M. Page // Proceedings of conference “Recent developments in superplasticizers”. – 2006. – Vol. 239, october. – P. 321–344.
  4. Panya, P. The effects of ionic surfactant adsorption on the rheology of ceramic glaze suspensions [Text] / P. Panya, E. Wanless, O. Arquero, G. Franks // Journal of the American Ceramic Society. – 2005. – vol. 88, No. 3. – P. 540–546.
  5. Heilen, W. Additives for waterborne coatings [Text] / W. Heilen. – Vincentz Network GmbH, 2009. – 222 p.
  6. Hare, C. H. Mechanisms of corrosion protection with surface-treated wollastonite pigments [Text] / C. H. Hare // Paint and coatings industry magazine. – 1998. – Vol. 1, No 40. – P. 74–82.
  7. Kundu, T. K. Atomistic simulation of the surface structure of wollastonite [Text] / T. K. Kundu, K. H. Rao, S. C. Parker // Chemical Physics Letters. – 2003. – Vol. 377. – P. 81–92.
  8. Ding, H. Surface modification of wollastonite by the mechano-activated method and its properties [Text] / H. Ding, S. Lu, G. Du // International journal of Minerals, Metalurgy and Materials. – 2011. – Vol. 18, No. 1. – P. 83–88.
  9. Koleske, J. V. Paint and Coating Testing Manual [Text] / J. V. Koleske. – ASTM International, 1995. – 925 p.
  10. Gosh, P. Adhesive and Coating Technology [Text] / P. Gosh. – Tata Mc-Graw-Hill Education, 2008. – 172 p.
  11. Svidersky V.A., Myronyuk O.V. (2008). Research of contact grade between film forming agent and the filler in composition coatings by chromatography. Proceedings of National Technical University “CPI”, 39, 9-18
  12. Permen T., Lagaly G. (1995). The rheological and colloidal properties of bentonite dispersions in the presence of organic compounds V. Bentonite and sodium montmorillonite and surfactants. Clay and clay minerals, 43(2), 229-236.
  13. Mikanovic N., Jolicoeur C., Page M. (2006). Influence of Surfactant Chemical Admixtures on the Stability and Rheological Properties of Calcium Carbonate and Cement Pastes. Proceedings of conference “Recent developments in superplasticizers”, 239, 321 – 344.
  14. Panya P., Wanless E., Arquero O., Franks G. (2005). The effects of ionic surfactant adsorption on the rheology of ceramic glaze suspensions. Journal of the American Ceramic Society, 88(3), 540-546.
  15. Heilen W. (2009) Additives for waterborne coatings. Vincentz Network GmbH, 222.
  16. Hare C.H. (1998). Mechanisms of corrosion protection with surface-treated wollastonite pigments. Paint and coatings industry magazine, 1(40), 74-82.
  17. Kundu T.K., Rao K.H., Parker S.C. (2003). Atomistic simulation of the surface structure of wollastonite. Chemical Physics Letters, 377, 81-92.
  18. Ding H., Lu S., Du G. (2011). Surface modification of wollastonite by the mechano-activated method and its properties. International journal of Minerals, Metalurgy and Materials, 18(1), 83-88.
  19. Koleske J.V. (1995). Paint and Coating Testing Manual. ASTM International, 925.
  20. Gosh P. (2008). Adhesive and Coating Technology. Tata Mc-Graw-Hill Education, 172.

Downloads

Published

2013-04-25

How to Cite

Миронюк, О. В., Сікорський, О. О., & Свідерський, В. А. (2013). The influence of surfactants on rheology of water dispersions of wollastonite. Eastern-European Journal of Enterprise Technologies, 2(6(62), 55–58. https://doi.org/10.15587/1729-4061.2013.12277

Issue

Vol. 2 No. 6(62) (2013): Technologies of organic and inorganic substances

Section

Technology organic and inorganic substances

License

Copyright (c) 2014 Олексій Володимирович Миронюк, Олексій Олексійович Сікорський, Валентин Анатолійович Свідерський

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.