The researches of the processes of a desorption from the calcinated synthetic anionic clays

Authors

  • Елеонора Олегівна Бутенко Azov State Technical University Str. Varsity, 7, Mariupol, Ukraine, 87500, Ukraine
  • Олексій Євгенович Капустін Azov State Technical University Str. Varsity, 7, Mariupol, Ukraine, 87500, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2013.12278

Keywords:

Synthetic anion clays, sorption, spinels, thermal researches

Abstract

The Layered Double Hydroxides (LDH) can occlude pollutants as on the mechanism of physical sorption, so on the ion-exchange mechanism. However, in both cases course of process of the return desorption of toxic components after their burial is possible. For prevention of process of the return desorption the fulfilled LDH can be subjected to heat treatment at high temperatures that leads to formation of spinels. The structure of the layered double hydroxides was calcinated at temperatures below 500 ° C, completely is restored at interaction with water, and at temperatures of heat treatment of sorbents higher than 600 ° C process of adsorption is irreversible, the hydroxide structure isn't restored, process of a desorption of sorbed components in environment doesn't happen

Author Biographies

Елеонора Олегівна Бутенко, Azov State Technical University Str. Varsity, 7, Mariupol, Ukraine, 87500

PhD, Researcher

Department of Chemistry

Олексій Євгенович Капустін, Azov State Technical University Str. Varsity, 7, Mariupol, Ukraine, 87500

Doctor of Science, Head. Department

Department of Chemistry

References

  1. Kozykina, M. Study of carbon fibre sorbents by the method of dynamic sorption [Текст] / M. Kozykina, V. Varshavskii, E. Monastyrskaya // Springer New York. – 1996. – V. 27. – p. 419 – 422.
  2. Lyi, N. Factors influencing the hydration of layered double hydroxides (LDHs) and the appearance of an intermediate second staging phase [Текст] / N. Lyi, K. Fujii, K. Okamoto // Applied Clay Science. – 2007. – p. 218-227.
  3. Капустин, А.Е. Научные проблемы современной технологии [Текст] / А.Е. Капустин. – 2007. – Т. 16. – c. 267-275; Kapustin A.E. // Scientific problems of modern technology. – 2007. – V. 16. – P. 267-275.
  4. Капустин, А.Е. Успехи химии [Текст] / Kapustin A.E. – 1991. – Т. 60. – № 12. – С. 2685-2717;
  5. Муханов, И. М. / Известия вузов. Химия и хим. Технология [Текст] / Muhanov I.M., Onuchak L.A., Sokolova E.P. // Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. – 2002. – V. 45 (5). – P. 58-62.
  6. Bolongini, М. Mg / Al mixed oxides prepared by coprecipitation and sol-gel routes: a comparison of their physico-chemical features and performance in m-cresol methylation [Текст] / Bolongini М., Cavani F., Perego C. // Microporous and Mesoporous Materials. – 2003. – V. 66. – Р. 77 – 89.
  7. Chizalett, C. Thermodynamic bronsted basicity of clean MgO surface determined by their deportation ability: Role of Mg2+ - O2- pairs [Текст] / Chizalett C., Bailly M.L., Gostentin G. // Catalysis Today. – 2006. – V. 116 (2). – P. 196-205.
  8. Муханов, И.М. Известия вузов [Текст] / Муханов И.М., Онучак Л.А., Соколова Е.П. // Химия и хим. технология. – 2002. – Т. 45 (5). – С. 58-62.
  9. Bolongini, М. Mg/Al mixed oxides prepared by coprecipitation and sol-gel routes: a comparison of their physico-chemical features and performance in m-cresol methylation [Текст] / Bolongini М., Cavani F., Perego C. // Mi¬croporous and Mesoporous Materials. – 2003. – V. 66. – Р. 77 – 89.
  10. Chizalett, C. Thermodynamic bronsted basicity of clean MgO surface determined by their deportation ability: Role of Mg2+ - O2- pairs [Текст] / Chizalett C., Bailly M.L., Gostentin G. // Catalysis Today. – 2006. – V. 116 (2). – P. 196-205.
  11. Bish, D. Anion-exchange in takovite: applications to other minerals [Текст] / D. Bish // Bulletin de Mineralogia. – 1980. – V. 103. – P. 170 – 175.
  12. Kozykina, M., Varshavskii, V., Monastyrskaya, E. . (1996) Study of carbon fibre sorbents by the method of dynamic sorption. Springer New York, 27, 419 – 422.
  13. Lyi N., Fujii, K., Okamoto, K. (2007) Factors influencing the hydration of layered double hydroxides (LDHs) and the appearance of an intermediate second staging phase. Applied Clay Science, 218-227.
  14. Kapustin A.E. (2007) Scientific problems of modern technology, 16, 267-275.
  15. Kapustin A. E. (1991) Successes of chemistry, 60(12), 2685-2717.
  16. Muhanov, I. M., Onuchak L.A., Sokolova E.P. // Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. – 2002. – V. 45. (5). – P. 58-62.
  17. Bolongini, М., Cavani, F., Perego, C. (2003) Mg/Al mixed oxides prepared by coprecipitation and sol-gel routes: a comparison of their physico-chemical features and performance in m-cresol methylation. Microporous and Mesoporous Materials, 66, 77 – 89.
  18. Chizalett, C., Bailly, M. L., Gostentin, G. (2006) Thermodynamic bronsted basicity of clean MgO surface determined by their deportation ability: Role of Mg2+ - O2- pairs. Catalysis Today, 116, 196-205.
  19. Muhanov, I. M., Onuchak, L. A., Sokolova, E. P. (2002) Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol, 45(5), 58-62.
  20. Bolongini, М., Cavani, F., Perego, C. (2003) Mg/Al mixed oxides prepared by coprecipitation and sol-gel routes: a comparison of their physico-chemical features and performance in m-cresol methylation. Mi¬croporous and Mesoporous Materials, 66, 77 – 89.
  21. Chizalett, C., Bailly, M.L., Gostentin, G. (2006) Thermodynamic bronsted basicity of clean MgO surface determined by their deportation ability: Role of Mg2+ - O2- pairs // Catalysis Today, 116 (2), 196-205.
  22. Bish, D. (1980) Anion-exchange in takovite: applications to other minerals / D. Bish // Bulletin de Mineralogia, 103,170 – 175.

Published

2013-04-25

How to Cite

Бутенко, Е. О., & Капустін, О. Є. (2013). The researches of the processes of a desorption from the calcinated synthetic anionic clays. Eastern-European Journal of Enterprise Technologies, 2(6(62), 59–61. https://doi.org/10.15587/1729-4061.2013.12278

Issue

Section

Technology organic and inorganic substances