Application of subacid cationites for water conditioning in baromembrane demineralization
DOI:
https://doi.org/10.15587/1729-4061.2013.14810Keywords:
ion exchange, cationite, demineralizatio, , nanofiltration, permiat, concentrate, regenerationAbstract
The article presents the results of studies on the stabilization treatment of water before the baromembrane demineralization. It was shown that subacid cationites in the acid form provide a complete reduction of alkalinity of water with its partial softening, and strongly acid cationites in the sodium form provide deep water softening without reducing its alkalinity. Ionites in a salt form provide effective neutralization of acidified aqueous solutions, including permiates and filtrates transferring the subacid cationites to the acid form. It was found that subacid cationites in calcium (magnesium) form are almost not regenerated by sodium chloride solutions in neutral and subacid medium. It was shown that the strongly acid cationite effectively adsorbs hardness ions with sodium ions concentration up to 143 mg-ekv/dm3, but at the same time it is effectively regenerated by 5-10% sodium chloride solutionsReferences
- Беличенко Ю.П. Замкнутые системы водообеспечения химических производств [Текст] / Ю.П. Беличенко. – М.: Химия, 1990. – 208 с.
- Гомеля, И. Н. Оценка эффективности катионитов КУ-2-8 и Aqualite R-100 FC при умягчении воды в присутствии ионов железа [Текст] / И. Н. Гомеля, Ю. А. Омельчук, В. М. Радовенчик // Экотехнологии и ресурсосбережение. –2008. – № 3. – С. 62-65.
- Голтвяницкая, Е.В. Оценка эффективности использования слабокислотного катионита Dawex MAC-3 в катионном умягчении воды[Текст] /Е.В, Голтвяницкая, Т.А. Шаблий, Н.Д. Гомеля, С.С. Ставская // Вісник НТУУ «КПІ» Серія « Хімічна інженерія , екологія та ресурсозбереження». – 2011. – № 2(8). – С. 87-92
- Гомеля, Н.Д. Кондиционирование воды для ресурсосберегающих систем водопользования [Текст] / Н.Д. Гомеля, Т.А. Шаблий, Ю.В. Носачева // Экотехнологии и ресурсосбережение. – 2004. – №4. – С.55-58.
- Шаблий, Т.А. Разработка эффективной технологи умягчения воды для промышленного водопотребления [Текст] / Т.А. Шаблий, И.Н. Макаренко, Е.В. Голтвяницкая // Энерготехнологии и ресурсосбережение. – 2010– №1. – С.53-58.
- Рисухін , В.В. Вплив концентрації розчинів сірчаної кислоти, форми катіоніту DOWEX-MAC-3 на ефективність його регенерації [Текст] / В.В. Рисухін, О.В. Глушко, І.М. Макаренко // Вісник Національнорго технічного університету «ХПІ». – 2012 – № 34. – С. 137-145
- Макаренко, І.М. Застосування слабокислотного катіоніту Dowex MAC-3 для стабілізаційної обробки води [Текст] / І. М. Макаренко, О.В. Глушко, В.В. Рисухін, В.П. Малін // Східно- Європейський журнал передових технологій. – 2012. – №3/6(57). –С.16-21.
- Спосіб відновлення регенераційних розчинів натрій-катіонного пом’якшення води [Текст] : пат. 43183 Україна, МПК9 В 01 Д 33/04 / Згуровсткий М.З., Гомеля І.М., Рисухін В.В., Ільченко М.Ю., Радовенчик В.М., Камаєв В.С., Черноволов Г.Ю.,; заявитель и патентообладатель НТУУ»КПИ». – № 200901203; заявл. 16.02.2009; опубл. 10.08.2009. Бюл. №15. – 3 с.
- Андрияш, С.В. Регенерация катионита КУ-2-8 при создании малоотходных технологий умягчения и обессоливания воды [Текст] / С.В. Андрияш, И.Н. Гомеля, Т.А. Шаблий // Экотехнологии и ресурсосбережение. – 2007. – №2. – С. 34-39.
- Гомеля, Н.Д. Разработка доступных ионитов для ресурсосберегающих процессов умягчения воды [Текст] / Н.Д. Гомеля, Ю.В. Носачева // Экотехнологии и ресурсосбережение. – 2004. – №6. – С. 51-54.
- Belichenko, U.P.( 1990). The closed water system chemical industry . Mosscov: Chemistry
- Gomelya, I.N., Omelchuk ,Y.A., Radovenchik ,V.M . (2008). Evaluation of cation exchangers KU-2-8 and Aqualite R-100 FC during the softening of water in the presence of iron ions . Eco-technologies and resources, № 3, 62-65.
- Goltvyanitskaya, E.V., Shabliy, T.A., Gomelya, N.D., Stavska, S.S. (2011). Evaluating the effectiveness of the use of weak acid cation resin Dawex MAC-3 in the cationic water softening . News of NTU "KPI" Serіya "Hіmіchna іnzhenerіya, ekologіya that resursozberezhennya.", № 2 (8), 87-92
- Gomelya, N.D. , Shabliy, T.A., Nosacheva U.V. (2004). Water conditioning systems for water resource . Environmental Technology and Resources., № 4, 55-58.
- Shabliy, T.A., Makarenko , I.N., Goltvyanitskaya, E.V. (2010) . Development of efficient technologies for industrial water softening water consumption . Power Technologies and Resources, № 1, 53-58.
- Risuhin, V.V., Glushko , E.V., Makarenko , I.N. (2012) . Effect of concentration of sulfuric acid cation form DOWEX-MAC-3 for the effectiveness of its regeneration . Bulletin Natsionalnorho Technical University "KPI", № 34, 137-145
- Makarenko, I.N., Glushko , E.V., Risuhin, V.V., Malin, V.P. Application slabokyslotnoho cation Dowex MAC-3 for stabilizing treatment . Eastern European journal of advanced technology, № 3/6 (57), 16-21.
- Method of restoring regenerative sodium-cation water softener . pat. 43183 Ukraine, MPK9 B 01 D 33/04 / Zhurovstkyy ,M.Z., Gomelya, I.M., Risuhin, V.V. Il'chenko, M.Y., Radovenchyk, V.M., Kamayev, V.S., Chernovolov, G. Y,; zayavytel and patentoobladatel NTU "KPI". - № 200901203, appl. 16.02.2009, publ. 10.08.2009. Bull. Number 15
- Andriyash, S.V., Gomelya, I.N., . Shabliy, T.A. (2007). Regeneration of the cation exchanger KU-2-8 when creating a low-waste technologies softening and desalination of water . Environmental Technology and Resources, № 2, 34-39.
- Gomelya, N.D., Nosacheva , U.V. (2004). The development of available ion-exchange resins for water softening processes of resource. Environmental Technology and Resources, № 6, 51-54.
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Copyright (c) 2014 Ірина Миколаївна Макаренко, Олена Володимирівна Глушко, Володимир Володимирович Рисухін, Оксана Миколаївна Терещенко
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