The effect of template residual content on supercapacitive characteristics of Ni(OH)2, obtained by template homogeneous precipitation

Authors

  • Vadym Kovalenko Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000, Ukraine https://orcid.org/0000-0002-8012-6732
  • Valerii Kotok Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000, Ukraine https://orcid.org/0000-0001-8879-7189

DOI:

https://doi.org/10.15587/1729-4061.2019.181020

Keywords:

nickel hydroxide, template synthesis, homogeneous precipitation, supercapacitor, binder, residual content

Abstract

Nickel hydroxide is widely used in hybrid supercapacitors. High electrochemical activity is demonstrated by α-Ni(OH)2 prepared by template homogeneous precipitation. A possible disadvantage of template synthesis is the inclusion of template into nickel hydroxide and the lack of data on its residual content. Multiple rinsing method was proposed for lowering the content of template residue. The comparative study was conducted for the influence of residual template content and its use without the introduction of external binders. To conduct the study, samples of Ni(OH)2 were prepared by template homogeneous precipitation using ether cellulose template Culminal C8465 with a concentration of 0.5 %. The structural properties of the sample were studied by means of X-ray diffraction analysis and sample morphology – by means of scanning electron microscopy. Electrochemical characteristics were studied by means of galvanostatic charge-discharge cycling of pasted electrode prepared without and with 3 % of the binder in the supercapacitor regime. It was found that with the use of an external binder, the specific capacity of the sample with a high content of template residue is very low because of blocked active surface. When this sample was used without the introduction of an external binder, the specific capacity increases by 1.8–18.4 times. The decrease in the content of template residue due to one-stage rinsing improved the specific capacity of the samples insignificantly. It was found that two- and three-stage rinsing is optimal, in which the specific capacities of the samples improved by 4.3–53.9 times, to 490 F/g and 50.7 mA·h/g. The higher number of rinsing stages (lower content of template residue) results in a decrease of specific characteristics. It is possible that there is an optimal template content, at which the negative effect of the template is balanced with blocking the active surface and the positive effect – with stabilizing the nano-sized hydroxide particles. It is recommended to experimentally establish the optimal number of rinsing stages to form the optimal content of template residue for a specific template

Author Biographies

Vadym Kovalenko, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000

PhD, Associate Professor

Department of Analytical Chemistry and Food Additives and Cosmetics

Senior Researcher

Competence center "Ecological technologies and systems"

Valerii Kotok, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000

PhD, Associate Professor

Department of Processes, Apparatus and General Chemical Technology

Senior Researcher

Competence center "Ecological technologies and systems"

References

  1. Simon, P., Gogotsi, Y. (2008). Materials for electrochemical capacitors. Nature Materials, 7 (11), 845–854. doi: https://doi.org/10.1038/nmat2297
  2. Burke, A. (2007). R&D considerations for the performance and application of electrochemical capacitors. Electrochimica Acta, 53 (3), 1083–1091. doi: https://doi.org/10.1016/j.electacta.2007.01.011
  3. Lang, J.-W., Kong, L.-B., Liu, M., Luo, Y.-C., Kang, L. (2009). Asymmetric supercapacitors based on stabilized α-Ni(OH)2 and activated carbon. Journal of Solid State Electrochemistry, 14 (8), 1533–1539. doi: https://doi.org/10.1007/s10008-009-0984-1
  4. Lang, J.-W., Kong, L.-B., Wu, W.-J., Liu, M., Luo, Y.-C., Kang, L. (2008). A facile approach to the preparation of loose-packed Ni(OH)2 nanoflake materials for electrochemical capacitors. Journal of Solid State Electrochemistry, 13 (2), 333–340. doi: https://doi.org/10.1007/s10008-008-0560-0
  5. Aghazadeh, M., Ghaemi, M., Sabour, B., Dalvand, S. (2014). Electrochemical preparation of α-Ni(OH)2 ultrafine nanoparticles for high-performance supercapacitors. Journal of Solid State Electrochemistry, 18 (6), 1569–1584. doi: https://doi.org/10.1007/s10008-014-2381-7
  6. Zheng, C., Liu, X., Chen, Z., Wu, Z., Fang, D. (2014). Excellent supercapacitive performance of a reduced graphene oxide/Ni(OH)2 composite synthesized by a facile hydrothermal route. Journal of Central South University, 21 (7), 2596–2603. doi: https://doi.org/10.1007/s11771-014-2218-7
  7. Wang, B., Williams, G. R., Chang, Z., Jiang, M., Liu, J., Lei, X., Sun, X. (2014). Hierarchical NiAl Layered Double Hydroxide/Multiwalled Carbon Nanotube/Nickel Foam Electrodes with Excellent Pseudocapacitive Properties. ACS Applied Materials & Interfaces, 6 (18), 16304–16311. doi: https://doi.org/10.1021/am504530e
  8. Hall, D. S., Lockwood, D. J., Bock, C., MacDougall, B. R. (2015). Nickel hydroxides and related materials: a review of their structures, synthesis and properties. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 471 (2174), 20140792. doi: https://doi.org/10.1098/rspa.2014.0792
  9. Solovov, V., Кovalenko, V., Nikolenko, N., Kotok, V., Vlasova, E. (2017). Influence of temperature on the characteristics of Ni(II), Ti(IV) layered double hydroxides synthesised by different methods. Eastern-European Journal of Enterprise Technologies, 1 (6 (85)), 16–22. doi: https://doi.org/10.15587/1729-4061.2017.90873
  10. Liu, C., Huang, L., Li, Y., Sun, D. (2009). Synthesis and electrochemical performance of amorphous nickel hydroxide codoped with Fe3+ and CO 3 2−. Ionics, 16 (3), 215–219. doi: https://doi.org/10.1007/s11581-009-0383-8
  11. Li, J., Luo, F., Tian, X., Lei, Y., Yuan, H., Xiao, D. (2013). A facile approach to synthesis coral-like nanoporous β-Ni(OH) 2 and its supercapacitor application. Journal of Power Sources, 243, 721–727. doi: https://doi.org/10.1016/j.jpowsour.2013.05.172
  12. Kovalenko, V. L., Kotok, V. A., Sykchin, A. A., Mudryi, I. A., Ananchenko, B. A., Burkov, A. A. et. al. (2016). Nickel hydroxide obtained by high-temperature two-step synthesis as an effective material for supercapacitor applications. Journal of Solid State Electrochemistry, 21 (3), 683–691. doi: https://doi.org/10.1007/s10008-016-3405-2
  13. Xiao-yan, G., Jian-cheng, D. (2007). Preparation and electrochemical performance of nano-scale nickel hydroxide with different shapes. Materials Letters, 61 (3), 621–625. doi: https://doi.org/10.1016/j.matlet.2006.05.026
  14. Tizfahm, J., Safibonab, B., Aghazadeh, M., Majdabadi, A., Sabour, B., Dalvand, S. (2014). Supercapacitive behavior of β-Ni(OH) 2 nanospheres prepared by a facile electrochemical method. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 443, 544–551. doi: https://doi.org/10.1016/j.colsurfa.2013.12.024
  15. Aghazadeh, M., Golikand, A. N., Ghaemi, M. (2011). Synthesis, characterization, and electrochemical properties of ultrafine β-Ni(OH)2 nanoparticles. International Journal of Hydrogen Energy, 36 (14), 8674–8679. doi: https://doi.org/10.1016/j.ijhydene.2011.03.144
  16. Kovalenko, V., Kotok, V. (2017). Obtaining of Ni-Al layered double hydroxide by slit diaphragm electrolyzer. Eastern-European Journal of Enterprise Technologies, 2 (6 (86)), 11–17. doi: https://doi.org/10.15587/1729-4061.2017.95699
  17. Kovalenko, V., Kotok, V. (2018). Comparative investigation of electrochemically synthesized (α+β) layered nickel hydroxide with mixture of α-Ni(OH)2 and β-Ni(OH)2. Eastern-European Journal of Enterprise Technologies, 2 (6 (92)), 16–22. doi: https://doi.org/10.15587/1729-4061.2018.125886
  18. Hall, D. S., Lockwood, D. J., Poirier, S., Bock, C., MacDougall, B. R. (2012). Raman and Infrared Spectroscopy of α and β Phases of Thin Nickel Hydroxide Films Electrochemically Formed on Nickel. The Journal of Physical Chemistry A, 116 (25), 6771–6784. doi: https://doi.org/10.1021/jp303546r
  19. Kovalenko, V., Kotok, V., Bolotin, O. (2016). Definition of factors influencing on Ni(OH)2 electrochemical characteristics for supercapacitors. Eastern-European Journal of Enterprise Technologies, 5 (6 (83)), 17–22. doi: https://doi.org/10.15587/1729-4061.2016.79406
  20. Hu, M., Lei, L. (2006). Effects of particle size on the electrochemical performances of a layered double hydroxide, [Ni4Al(OH)10]NO3. Journal of Solid State Electrochemistry, 11 (6), 847–852. doi: https://doi.org/10.1007/s10008-006-0231-y
  21. Vasserman, I. N. (1980). Himicheskoe osazhdenie iz rastvorov [Chemical precipitation from solutions]. Leningrad: Himiya, 208.
  22. Bora, M. (2013). Homogeneous precipitation of nickel hydroxide powders. Iowa State University, 126. doi: https://doi.org/10.31274/rtd-180813-146
  23. Tang, H. W., Wang, J. L., Chang, Z. R. (2008). Preparation and characterization of nanoscale nickel hydroxide using hydrothermal synthesis method. J. Func. Mater, 39 (3), 469–476.
  24. Tang, Y., Liu, Y., Yu, S., Zhao, Y., Mu, S., Gao, F. (2014). Hydrothermal synthesis of a flower-like nano-nickel hydroxide for high performance supercapacitors. Electrochimica Acta, 123, 158–166. doi: https://doi.org/10.1016/j.electacta.2013.12.187
  25. Yang, L.-X., Zhu, Y.-J., Tong, H., Liang, Z.-H., Li, L., Zhang, L. (2007). Hydrothermal synthesis of nickel hydroxide nanostructures in mixed solvents of water and alcohol. Journal of Solid State Chemistry, 180 (7), 2095–2101. doi: https://doi.org/10.1016/j.jssc.2007.05.009
  26. Cui, H. L., Zhang, M. L. (2009). Synthesis of flower-like nickel hydroxide by ionic liquids-assisted. J. Yanan. Univ., 28 (2), 76–83.
  27. Xu, L., Ding, Y.-S., Chen, C.-H., Zhao, L., Rimkus, C., Joesten, R., Suib, S. L. (2008). 3D Flowerlike α-Nickel Hydroxide with Enhanced Electrochemical Activity Synthesized by Microwave-Assisted Hydrothermal Method. Chemistry of Materials, 20 (1), 308–316. doi: https://doi.org/10.1021/cm702207w
  28. Córdoba de Torresi, S. I., Provazi, K., Malta, M., Torresi, R. M. (2001). Effect of Additives in the Stabilization of the α Phase of Ni(OH)[sub 2] Electrodes. Journal of The Electrochemical Society, 148 (10), A1179. doi: https://doi.org/10.1149/1.1403731
  29. Kotok, V., Kovalenko, V., Malyshev, V. (2017). Comparison of oxygen evolution parameters on different types of nickel hydroxide. Eastern-European Journal of Enterprise Technologies, 5 (12 (89)), 12–19. doi: https://doi.org/10.15587/1729-4061.2017.109770
  30. Oliva, P., Leonardi, J., Laurent, J. F., Delmas, C., Braconnier, J. J., Figlarz, M. et. al. (1982). Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides. Journal of Power Sources, 8 (2), 229–255. doi: https://doi.org/10.1016/0378-7753(82)80057-8
  31. Kotok, V., Kovalenko, V. (2017). Electrochromism of Ni(OH)2 films obtained by cathode template method with addition of Al, Zn, Co ions. Eastern-European Journal of Enterprise Technologies, 3 (12 (87)), 38–43. doi: https://doi.org/10.15587/1729-4061.2017.103010
  32. Vlasova, E., Kovalenko, V., Kotok, V., Vlasov, S., Sukhyy, K. (2017). A study of the influence of additives on the process of formation and corrosive properties of tripolyphosphate coatings on steel. Eastern-European Journal of Enterprise Technologies, 5 (12 (89)), 45–51. doi: https://doi.org/10.15587/1729-4061.2017.111977
  33. Kotok, V., Kovalenko, V. (2017). The properties investigation of the faradaic supercapacitor electrode formed on foamed nickel substrate with polyvinyl alcohol using. Eastern-European Journal of Enterprise Technologies, 4 (12 (88)), 31–37. doi: https://doi.org/10.15587/1729-4061.2017.108839
  34. Burmistr, M. V., Boiko, V. S., Lipko, E. O., Gerasimenko, K. O., Gomza, Y. P., Vesnin, R. L. et. al. (2014). Antifriction and Construction Materials Based on Modified Phenol-Formaldehyde Resins Reinforced with Mineral and Synthetic Fibrous Fillers. Mechanics of Composite Materials, 50 (2), 213–222. doi: https://doi.org/10.1007/s11029-014-9408-0
  35. Kovalenko, V., Kotok, V. (2018). Influence of ultrasound and template on the properties of nickel hydroxide as an active substance of supercapacitors. Eastern-European Journal of Enterprise Technologies, 3 (12 (93)), 32–39. doi: https://doi.org/10.15587/1729-4061.2018.133548
  36. Mehdizadeh, R., Sanati, S., Saghatforoush, L. A. (2013). Effect of PEG6000 on the morphology the β-Ni(OH)2 nanostructures: solvothermal synthesis, characterization, and formation mechanism. Research on Chemical Intermediates, 41 (4), 2071–2079. doi: https://doi.org/10.1007/s11164-013-1332-8
  37. Ecsedi, Z., Lazău, I., Păcurariu, C. (2007). Synthesis of mesoporous alumina using polyvinyl alcohol template as porosity control additive. Processing and Application of Ceramics, 1 (1-2), 5–9. doi: https://doi.org/10.2298/pac0702005e
  38. Pon-On, W., Meejoo, S., Tang, I.-M. (2008). Formation of hydroxyapatite crystallites using organic template of polyvinyl alcohol (PVA) and sodium dodecyl sulfate (SDS). Materials Chemistry and Physics, 112 (2), 453–460. doi: https://doi.org/10.1016/j.matchemphys.2008.05.082
  39. Miyake, K., Hirota, Y., Uchida, Y., Nishiyama, N. (2016). Synthesis of mesoporous MFI zeolite using PVA as a secondary template. Journal of Porous Materials, 23 (5), 1395–1399. doi: https://doi.org/10.1007/s10934-016-0199-7
  40. Wanchanthu, R., Thapol, A. (2011). The Kinetic Study of Methylene Blue Adsorption over MgO from PVA Template Preparation. Journal of Environmental Science and Technology, 4 (5), 552–559. doi: https://doi.org/10.3923/jest.2011.552.559
  41. Kotok, V. A., Malyshev, V. V., Solovov, V. A., Kovalenko, V. L. (2017). Soft Electrochemical Etching of FTO-Coated Glass for Use in Ni(OH)2-Based Electrochromic Devices. ECS Journal of Solid State Science and Technology, 6 (12), P772–P777. doi: https://doi.org/10.1149/2.0071712jss
  42. Tan, Y., Srinivasan, S., Choi, K.-S. (2005). Electrochemical Deposition of Mesoporous Nickel Hydroxide Films from Dilute Surfactant Solutions. Journal of the American Chemical Society, 127 (10), 3596–3604. doi: https://doi.org/10.1021/ja0434329
  43. Kotok, V., Kovalenko, V. (2018). A study of multilayered electrochromic platings based on nickel and cobalt hydroxides. Eastern-European Journal of Enterprise Technologies, 1 (12 (91)), 29–35. doi: https://doi.org/10.15587/1729-4061.2018.121679
  44. Parkhomchuk, E. V., Sashkina, K. A., Rudina, N. A., Kulikovskaya, N. A., Parmon, V. N. (2013). Template synthesis of 3D-structured macroporous oxides and hierarchical zeolites. Catalysis in Industry, 5 (1), 80–89. doi: https://doi.org/10.1134/s2070050412040150
  45. Gu, W., Liao, L. S., Cai, S. D., Zhou, D. Y., Jin, Z. M., Shi, X. B., Lei, Y. L. (2012). Adhesive modification of indium–tin-oxide surface for template attachment for deposition of highly ordered nanostructure arrays. Applied Surface Science, 258 (20), 8139–8145. doi: https://doi.org/10.1016/j.apsusc.2012.05.009
  46. Kovalenko, V., Kotok, V. (2017). Study of the influence of the template concentration under homogeneous precepitation on the properties of Ni(OH)2 for supercapacitors. Eastern-European Journal of Enterprise Technologies, 4 (6 (88)), 17–22. doi: https://doi.org/10.15587/1729-4061.2017.106813
  47. Ivanov, K. V., Alekseeva, O. V., Kraev, A. S., Agafonov, A. V. (2019). Template-Free Synthesis and Properties of Mesoporous Calcium Titanate. Protection of Metals and Physical Chemistry of Surfaces, 55 (4), 667–670. doi: https://doi.org/10.1134/s2070205119040063
  48. Shestakova, D. O., Sashkina, K. A., Parkhomchuk, E. V. (2019). Template-Free Synthesis of Hierarchical Zeolite ZSM-5. Petroleum Chemistry, 59 (8), 838–844. doi: http://doi.org/10.1134/S0965544119080188
  49. Bhat, K. S., Nagaraja, H. S. (2019). Morphology-dependent electrochemical performances of nickel hydroxide nanostructures. Bulletin of Materials Science, 42 (6). doi: https://doi.org/10.1007/s12034-019-1951-9
  50. Wang, R.-N., Li, Q.-Y., Wang, Z., Wei, Q., Nie, Z.-R. (2008). Synthesis of nickel hydroxide flower-like microspheres by template-free liquid process. Chemical Journal of Chinese Universities -Chinese Edition, 29 (1), 18–22.
  51. Hadden, J. H. L., Ryan, M. P., Riley, D. J. (2019). Examining the charging behaviour of nickel hydroxide nanomaterials. Electrochemistry Communications, 101, 47–51. doi: https://doi.org/10.1016/j.elecom.2019.02.012
  52. Kovalenko, V., Kotok, V. (2018). Synthesis of Ni(OH)2 by template homogeneous precipitation for application in the binder­free electrode of supercapacitor. Eastern-European Journal of Enterprise Technologies, 4 (12 (94)), 29–35. doi: https://doi.org/10.15587/1729-4061.2018.140899
  53. Kotok, V., Kovalenko, V. (2017). Optimization of nickel hydroxide electrode of the hybrid supercapacitor. Eastern-European Journal of Enterprise Technologies, 1 (6 (85)), 4–9. doi: https://doi.org/10.15587/1729-4061.2017.90810
  54. Kovalenko, V., Kotok, V., Kovalenko, I. (2018). Activation of the nickel foam as a current collector for application in supercapacitors. Eastern-European Journal of Enterprise Technologies, 3 (12 (93)), 56–62. doi: https://doi.org/10.15587/1729-4061.2018.133472

Downloads

Published

2019-10-18

How to Cite

Kovalenko, V., & Kotok, V. (2019). The effect of template residual content on supercapacitive characteristics of Ni(OH)2, obtained by template homogeneous precipitation. Eastern-European Journal of Enterprise Technologies, 5(12 (101), 29–37. https://doi.org/10.15587/1729-4061.2019.181020

Issue

Vol. 5 No. 12 (101) (2019): Materials Science

Section

Materials Science

License

Copyright (c) 2019 Vadym Kovalenko, Valerii Kotok

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.