Parallel-serial adsorption of phosphate ions by natural sorbents

Authors

  • Оксана Вікторівна Сидорчук Lviv Polytechnic National University St. Yura Square 3/4, educational building № 8, room 121, Lviv, Ukraine, 79000, Ukraine
  • Оксана Василівна Мацуська National university of veterinary medicine that biogeotechnologies of the name of S.Z. Gzhickogo St. Pekarskaya 50, Lvov, Ukraine, 79010, https://orcid.org/0000-0003-0915-8878
  • Віра Василівна Сабадаш Lviv Polytechnic National University St. Yura Square 3/4, educational building № 8, room 121, Lviv, Ukraine, 79000, Ukraine https://orcid.org/0000-0002-6091-4053
  • Ярослав Михайлович Гумницький Lviv Polytechnic National University St. Yura Square 3/4, educational building № 8, room 122a, Lviv, Ukraine, 79000, Ukraine https://orcid.org/0000-0003-0464-9782

DOI:

https://doi.org/10.15587/1729-4061.2014.30874

Keywords:

natural zeolite, modified zeolite, phosphate ions, heavy metals, adsorption, wastewater

Abstract

The process of adsorption of phosphorus compounds on natural sorbent - zeolite, which shows adsorption and ion exchange properties is considered. Phosphates belong to anthropogenic environmental pollutants. They are present in the wastewater of industrial and utility enterprises. Static activity of phosphates in zeolite in their pollution limits in wastewater is investigated. It is shown that they are in low concentrations. This process is described by Henry linear adsorption equation.

The presence of other components in the wastewater, especially ammonium compounds, complicates the adsorption process. The absorption of ammonium ions occurs mainly through ion exchange, replacing sodium, potassium and ammonium cations in the zeolite. The absorption of phosphorus compounds proceeds due to adsorption and formation of compounds with calcium and magnesium ions in zeolite pores. Parallel adsorption of two components slightly reduces static activity in relation to phosphorus compounds, but the total adsorption of the two components is higher.

The second investigated mechanism of adsorption of components from aqueous solutions by zeolite was serial adsorption. Primarily, adsorption of copper ions, for example, when treating electroplating wastewater was conducted. This process allows to modify sorbent and change its adsorption properties. The next stage was adsorption of phosphate compounds by the modified zeolite, on which these compounds form persistent connections with copper, calcium and magnesium ions, and adsorption capacity of the modified zeolite significantly increases.

The studies of parallel and serial sorption indicate the feasibility of these purification methods.

Author Biographies

Оксана Вікторівна Сидорчук, Lviv Polytechnic National University St. Yura Square 3/4, educational building № 8, room 121, Lviv, Ukraine, 79000

Postgraduate student

Department of  Ecology and Balanced Nature Use

Оксана Василівна Мацуська, National university of veterinary medicine that biogeotechnologies of the name of S.Z. Gzhickogo St. Pekarskaya 50, Lvov, Ukraine, 79010

Candidate of Аgricultural Sciences, аssistant

Department of Ecology and Biology 

Віра Василівна Сабадаш, Lviv Polytechnic National University St. Yura Square 3/4, educational building № 8, room 121, Lviv, Ukraine, 79000

Candidate of Technical Sciences, Assistant Professor

Department of  Ecology and Balanced Nature Use

Ярослав Михайлович Гумницький, Lviv Polytechnic National University St. Yura Square 3/4, educational building № 8, room 122a, Lviv, Ukraine, 79000

Gumnitsky Jaroslav

Doctor of Technical Sciences, Professor

Department of Applied Ecology and Balanced Nature Use

References

  1. Yakovenko, Yu. P., Khorunzhiy, P. D., Khomutecka, T. P. (2007). Dependence of high-quality indexes of superficial water sources of Ukraine of influence of technogenic contaminations. It is presented in Mirgorod, 24–28.
  2. Dacenko, I. I., Denisyuk, O. B., Doloshickiy, C. L. (1997). Modern problems of hygiene of environment. Lviv state medical university. Lviv, 136.
  3. Zapolskiy, A. K. (2008). Physical and chemical bases of technology of cleaning of flow waters. Kyiv, 988.
  4. Paranyak, R. P., Matsuska, O. V., Romanec, M. M. (2008). General description of natural sorbents and their use in industry and agriculture. Rural owner, 5/6, 38–42.
  5. Matsuska, O. V., Paranyak, R. P., Gumnitsky, Ya. M. (2011). Statics and kinetics of sorption of phosphates on a natural zeolite in periodic terms. The Water economy of Ukraine, 2, 25–29.
  6. Gumnitsky, Y. M., Gryshchouk, V. O. (2013). Outwardly diffusive kinetics of sorption of Kuprumu by the natural zeolite. Presented at Odessa national academy of food technologies, 43 (1), 77–78.
  7. Kuliyeva, T. L., Lebedeva, N. N., Orbuh, V. I., Sultanov, Ch. A. (2009). Natural zeolite -klinoptilolite identification. Fizika, 3, 43–45.
  8. Vasylechko, V. O., Gryshchouk, G. V., Lebedynets, L. O., Kuz'ma, Yu. B., Vasylechko, L. O., Zakordonskiy, V. P. (2000). Adsorption of Copper on Transcarpathian Clinoptilolite. Adsorption Science & Technology, 17 (2), 125–134.
  9. Malovany, M., Оdnorig, Z., Gudziova, I. (1999). Modification of natural zeolite and its application prospects. Chemical Industry of Ukraine, 5. 10–12.
  10. Sabadash, V., Akulova, A. (2013). Modification of natural zeolites by metal ions to intensify process of phosphate adsorption from wastewater. Ternopol, Prospect TNTU, 176–177.
  11. PND F 14.1:2:4.112-97. Technique for measuring the mass concentration of phosphate ions in drinking, surface and waste waters photometric method with ammonium molybdate (2011). Moscow: Ministry of environmental protection and natural resources of Russian federation.
  12. Galarneau, A., Di Renzo, F., Fajula, F., Vedrine, J. (2001). Zeolites and Mesoporous Materials at the Dawn of the 21ST Century. Vol. 135. In Book of Proceedings­Stud. Surf. Sci. Catal., Ed. by Amsterdam; London; New York; Oxford; Paris; Shannon; Tokyo, 443.
  13. Gomonay, V., Golub, N., Gomonay, P., Szekeresh, K. (1997). Preventing from ingress of radionucli­des, heavy metals and other dangerous mutagenic factors into human and animal organisms. Uzhgorod, 2, 90–96.
  14. Zorpas, A., Constantinides, T., Vlyssides, A., Haralambous, I., Loizidou, M. (2000). Heavy metals uptake by natural zeolite and metals partitioning in sewage slude compost. Bioresource Technol., 72 (2), 113–119. doi: 10.1016/s0960-8524(99)00110-8
  15. Vasylechko, V. O., Gryshchouk, G. V., Kuz’ma, Yu. B. Lebedynets, L. O., Oliyarnyk, O. Ya. (2000). Adsorption of Cadmium on Transcarpathian Clinoptilolite. Adsorption Science & Technology, 18 (7), 621–630. doi: 10.1260/0263617001493675
  16. Vasylechko, V. O., Gryshchouk, G. V., Lebedynets, L. O., Kuz’ma, Yu. B., Vasylechko, L. O., Zakordonskiy, V. P. (1999). Adsorption of Copper on Transcarpathian Clinoptilolite. Adsorption Science & Technology, 17 (2), 125–134.
  17. Mikityuk, O. M., Zlotin, O. Z., Brovdiy, V. M. (2000). Ecology of man. KHDPU of “OVS”, 207.
  18. Greg, S., Sing., K. (1984). Adsorbciya, udelnaya poverkhnost, poristost. Translations angl. Second edition. Moscow: the World, 306.

Downloads

Published

2014-12-11

How to Cite

Сидорчук, О. В., Мацуська, О. В., Сабадаш, В. В., & Гумницький, Я. М. (2014). Parallel-serial adsorption of phosphate ions by natural sorbents. Eastern-European Journal of Enterprise Technologies, 6(6(72), 56–60. https://doi.org/10.15587/1729-4061.2014.30874

Issue

Vol. 6 No. 6(72) (2014): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

License

Copyright (c) 2014 Оксана Вікторівна Сидорчук, Оксана Василівна Мацуська, Віра Василівна Сабадаш, Ярослав Михайлович Гумницький

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.