Extraneous diffusion kinetics of ammonium ions adsorption in the presence of other ions

Authors

  • Ярослав Михайлович Гумницький Lviv Polytechnic National University, St. George Square 3/4, Lviv, Ukraine, 79013, Ukraine
  • Вера Васильевна Сабадаш Lviv Polytechnic National University, St. Yura Square 3/4, educational building № 8, room 121, Lviv, Ukraine, 79000, Ukraine
  • Оксана Васильевна Мацуська Lviv National University of Veterinary Medicine and Biotehnology named after S.Z. Gzhytsky, Pekarska Str.50 , Lviv, Ukraine, 79010, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2013.16695

Keywords:

ammonium ion, zeolite, external diffusion, waste-water

Abstract

The present article substantiates theoretical foundations of competitive adsorption of multicomponent systems on mineral sorbents. Monitoring of wastewater contaminated with ammonium ions, estimation of quantities, pecularities of localization and estimation of toxicological impacts on the environment was carried out. The existing theoretical apparatus for adsorption processes description was analyzed. Adsorption process mechanism and methods for identification of experimental data to theoretical models was developed. Kinetic characteristics of adsorption of ammonium ions on natural sorbents were determined. Sorption capacity of zeolite to ammonium ions in static and dynamic conditions was experimentally investigated. Influence of presence of phosphoric compounds and proteins on equilibrium and speed of absorption of ammonium ion was determined. Experimental data and theoretical models of adsorption were identified. Kinetic coefficients of adsorption processes were set. It has been established that the presence of foreign ions in solution significantly reduces sorption capacity of zeolite on ammonium ions

Author Biographies

Ярослав Михайлович Гумницький, Lviv Polytechnic National University, St. George Square 3/4, Lviv, Ukraine, 79013

Doctor of Science Engineering professor

Department of the applied ecology and balanced natural use

Вера Васильевна Сабадаш, Lviv Polytechnic National University, St. Yura Square 3/4, educational building № 8, room 121, Lviv, Ukraine, 79000

Candidate of Technical Sciences, Assistant Professor

Department of Applied Ecology and Balanced Nature Use

Оксана Васильевна Мацуська, Lviv National University of Veterinary Medicine and Biotehnology named after S.Z. Gzhytsky, Pekarska Str.50 , Lviv, Ukraine, 79010

Assistant

Department of Ecology

References

  1. Kuliyeva, T. L. Natural zeolite -klinoptilolite identification [Text] / T. L. Kuliyeva, N. N. Lebedeva, V. I. Orbuh, Ch. A. Sultanov // Fizika. — 2009. —№ 3. —pp. 43-45.
  2. Breck, D. W. Zeolite Molecular Sieves: Structure, Chemistry and Use [Text] / D. W. Breck. — New York: Wiley, 1974. — 784 p.
  3. Vasylechko, V. O. Adsorption of Copper on Transcarpathian Clinoptilolite [Text] / V O. Vasylechko , G.V. Gryshchouk , L.O. Lebedynets , Yu.B. Kuz'ma , L.O. Vasylechko , Zakordonskiy V.P. // Adsorp. Sci. Technol. —1999. —Vol.17. —№ 2. — pp.125-134.
  4. Савченко, И. Л. Охрана среды от загрязнения отходами животноводства [Текст] / И. Л. Савченко, В. Н. Благодатный. — К.: Урожай, 1986. — 128 с.
  5. Даценко, И. И. Современные проблемы гигиены окружающей среды [Текст] / И. И. Даценко, А. Б. Денисюк, С. Л. Долошицький и др. – Львов, 1997. — 136 с.
  6. Ткаченко, С. И. Биоконверсия органических отходов АПК и экологически сбалансированные технологии [Текст] / С. И. Ткаченко, Е. П. Ларюшкин, Д. В. Степанов // Экологический вестник. — № 5-6. — 2002. — с. 6-7.
  7. Дистанов, У.Г. Природные сорбенты СССР [Текст] / У. Г. Дистанов, А. С. Михайлов, Т. П. Конюхова. – М.: Недра, 1990. – 208 с.
  8. Челышев, Н.Ф., Беренштейн Б.Г., Володин В.Ф. Цеолиты - новый тип минерального сырья [Текст] / Н.Ф. Челышев, Б.Г. Беренштейн, В.Ф. Володин. — М.: Недра, 1987. — 176 с.
  9. Petrus, R. Wymiana masy w ukladzie cialo stale - ciecz [Text] / R. Petrus , G. Akselrud, J. Gumnicki, W. Piantkowski — Rzeszow, Wyd. Politechniki Rzeszowskiej, 1998. — 365 s.
  10. Шифрин, С. М. Очистка сточных вод мясной и молочной промышленности [Текст] / С. М. Шифрин, Г. В. Иванова, Б. Микулов, Ю. А. Фенофанов. — 1981 г. — 272 с.
  11. ПНД Ф 14.1:2.1–95. МВИ массовой концентрации ионов аммония в природных и сточных водах фотометрическим методом с реактивом Несслера [Текст] — М.: Министерство охраны окружающей среды и природных ресурсов РФ, 2004.
  12. Петрушка, И. М. Внешнедиффузионная кинетика адсорбции красителя анионного красного 8С на глауконите [Текст] /И. М. Петрушка, Я. М. Гумницкий, М. С. Мальованый // Теор. основы химической технологии. — Т.47, №2.-2013.- С.191-195.
  13. Kuliyeva, T. L., Lebedeva, N. N., Orbuh, V. I., Sultanov, Ch.A. (2009). Natural zeolite — klinoptilolite identification. Fizika, № 3, 43-45.
  14. Breck, D. W. (1974). Zeolite Molecular Sieves: Structure, Chemistry and Use, Wiley, New York, USA, 784.
  15. Vasylechko, V O., Gryshchouk, G.V., Lebedynets, L.O., Kuz'ma, Yu.B., Vasylechko, L.O., Zakordonskiy, V.P. (1999). Adsorption of Copper on Transcarpathian Clinoptilolite. Adsorp. Sci. Technol. Vol.17, № 2, 125—134.
  16. Savchenko, I.L., Blagodatny, V.N. (1986). Environmental protection from contamination by wastes of stock-raising, Urojay, 128.
  17. Datsenko, I.I., Denisyuk, A.B., Doloshitskiy, S.L., Plastunov, B.A., Tolmacheva, L.I., Kokot, V.R., Lityuk, A.P. (1997). Modern problems of hygiene of environment, Lvov, 136.
  18. Tkachenko, S.I. Laryushkin, E.P., Stepanov, D.V. (2002). Biokonversion of organic wastes of APK and ecologically balanced technologies. Ecological announcer, 5-6, 6-7.
  19. Distanov, U.G., Mihaylov, A.S.. Konyuhova, T.P. (1990). Natural to sorbents of USSR. M.: Nedra, 208.
  20. Chelishev, N.F., Berenshteyn, B.G., Volodin, V.F. (1987). Zeolites - the new type of mineral raw material. M.: Nedra, 176.
  21. Petrus, R., Akselrud, G., Gumnicki, J., Piantkowski, W. (1998). Masstransfer in systems solid phase - liquid. Rzeshow, Wyd. Politechniki Rzeszowskiej, 365.
  22. Shifrin, S.M., Ivanova, G.V., Mikulov, B., Fenofanov, Yu.A. (1981). Wastewaters treatment of meat and milk industry, 272.
  23. PND F 14.1:2.1–95. MVI mass concentration of ions of ammonium in natural waters and wastewaters by a photometric method with the Nessler reagent (2004). M.: Ministry of environmental protection and natural resources of Russian federation.
  24. Petrushka, I. M., Gumnitsky, J.M., Malovany, M.S. (2013). Extraneous diffusion kinetics of ammonium ions adsorption of dye of anionic red 8С on glauconitic. Theor. Found. Chem. Eng. Theoretical bases of chemical tehnology, Vol. 47, № 2, 191-195.

Downloads

Published

2013-07-30

How to Cite

Гумницький, Я. М., Сабадаш, В. В., & Мацуська, О. В. (2013). Extraneous diffusion kinetics of ammonium ions adsorption in the presence of other ions. Eastern-European Journal of Enterprise Technologies, 4(6(64), 19–23. https://doi.org/10.15587/1729-4061.2013.16695

Issue

Vol. 4 No. 6(64) (2013): Technology of organic and inorganic substanse

Section

Technology organic and inorganic substances

License

Copyright (c) 2014 Ярослав Михайлович Гумницький, Вера Васильевна Сабадаш, Оксана Васильевна Мацуська

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.