A research of colloidal silver immobilization in bionanocomposites of natural polymers and montmorillonite

Authors

  • Kuanyshbek Musabekov Al-Farabi Kazakh National University Al-Farabi ave., 71, Almaty, Republic of Kazakhstan, 050040, Kazakhstan https://orcid.org/0000-0003-1114-1901
  • Botagoz Zhakyp Al-Farabi Kazakh National University Al-Farabi ave., 71, Almaty, Republic of Kazakhstan, 050040, Kazakhstan https://orcid.org/0000-0002-7540-0872
  • Sagdat Tazhibayeva Al-Farabi Kazakh National University Al-Farabi ave., 71, Almaty, Republic of Kazakhstan, 050040, Kazakhstan https://orcid.org/0000-0003-3300-3235
  • Nurlan Musabekov Al-Farabi Kazakh National University Al-Farabi ave., 71, Almaty, Republic of Kazakhstan, 050040, Kazakhstan
  • Ayagoz Yergaliyeva Al-Farabi Kazakh National University Al-Farabi ave., 71, Almaty, Republic of Kazakhstan, 050040, Kazakhstan https://orcid.org/0000-0002-9570-6457

DOI:

https://doi.org/10.15587/1729-4061.2020.216995

Keywords:

colloidal silver, bionanocomposites, montmorillonite interlayer space, alginate, carboxymethylcellulose, tensile strength

Abstract

Currently, colloidal silver particles are used in the creation of electronic, optical, and sensor devices of a new generation. Silver-containing bionanocomposites (BNCs) were synthesized by immobilization of colloidal montmorillonite particles containing colloidal silver in a composition of sodium alginate and sodium salt of carboxymethylcellulose. Silver-containing montmorillonite particles Ag-Mt were obtained by replacing Na+ ions in layered silicate galleries with Ag+ ions, followed by the transformation of silver ions into silver particles. The introduction of Ag+ ions into the montmorillonite structure is justified by infrared spectroscopy. When studying the strength of bionanocomposite films, it was found that with an increase in the content of Ag-Mt particles in their composition, the strength increases and the deformation decreases.

It is found that the equilibrium values of the swelling constant are set in ~30 minutes. At the same time, with an increase in the Ag-Mt content in the bionanocomposite from 3 % to 10 %, the value of the equilibrium swelling coefficient (Kswell) decreases by 2.8 times. The replacement of Na+ ions with Ag+ ions in the montmorillonite structure is accompanied by a decrease in the swelling of bionanocomposites, which is explained by the lower hydration of Ag+ ions compared to Na+ ions. As another reason for the decrease in the swelling of bimonanocomposites with an increase in the proportion of Ag-Mt in their composition, enhancing their ability to structure formation in the prersence of a clay mineral is indicated.

The kinetics of the release of Ag+ ions from bionanocomposites into saline has been studied. It is shown that the release of Ag+ ions increases with increasing pH of the medium

Author Biographies

Kuanyshbek Musabekov, Al-Farabi Kazakh National University Al-Farabi ave., 71, Almaty, Republic of Kazakhstan, 050040

Doctor of chemical Sciences, Professor

Department of Analytical, Colloid Chemistry and Technology of Rare Elements

National Nanotechnology Laboratory of Open Type

Botagoz Zhakyp, Al-Farabi Kazakh National University Al-Farabi ave., 71, Almaty, Republic of Kazakhstan, 050040

Postgraduate Student

Department of Analytical, Colloid Chemistry and Technology of Rare Elements

Sagdat Tazhibayeva, Al-Farabi Kazakh National University Al-Farabi ave., 71, Almaty, Republic of Kazakhstan, 050040

Doctor of Chemical Sciences, Professor

Department of Analytical, Colloid Chemistry and Technology of Rare Elements

Nurlan Musabekov, Al-Farabi Kazakh National University Al-Farabi ave., 71, Almaty, Republic of Kazakhstan, 050040

PhD, Leading Researcher

National Nanotechnology Laboratory of Open Type

Ayagoz Yergaliyeva, Al-Farabi Kazakh National University Al-Farabi ave., 71, Almaty, Republic of Kazakhstan, 050040

Master

Department of Analytical, Colloid Chemistry and Technology of Rare Elements

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Published

2020-12-31

How to Cite

Musabekov, K., Zhakyp, B., Tazhibayeva, S., Musabekov, N., & Yergaliyeva, A. (2020). A research of colloidal silver immobilization in bionanocomposites of natural polymers and montmorillonite. Eastern-European Journal of Enterprise Technologies, 6(6 (108), 93–101. https://doi.org/10.15587/1729-4061.2020.216995

Issue

Vol. 6 No. 6 (108) (2020): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2020 Kuanyshbek Musabekov, Botagoz Zhakyp, Sagdat Tazhibayeva, Nurlan Musabekov, Ayagoz Yergaliyeva

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