Defining patterns in the influence exerted by the interelated biochemical corrosion on concrete building structures under the conditions of a chemical enterprise

Authors

DOI:

https://doi.org/10.15587/1729-4061.2021.226587

Keywords:

biochemical corrosion of concrete, sulfate acid, Thiobacillus thiooxidans bacterium, Aspergillus fumigatus micromycetes

Abstract

The effect of microbial and chemical corrosion on concrete structures operated in the conditions of chemical enterprises has been established that makes it possible to reliably predict the timing of their decommissioning in order to prevent industrial disasters. Even though the construction complies with all building codes, concrete structures eventually undergo chemical and biological corrosion.

The innovation proposed in this study implies investigating the depth and degree of damage to concrete at the microscopic level by the method of raster electron microscopy. In addition, the TPD-MS method has been suggested for determining the quantitative and qualitative state of the carbonate components of concrete and sulfur compounds.

This study has found that in concrete samples from the titanium dioxide production plant, the amount of carbon dioxide release is twice less than in control samples at t=600 °C while the level of sulfur dioxide, on the contrary, increases. This is due to the ability of thionic bacteria to accumulate sulfate acid that destroys the cementing component in concrete. The reported results confirm the impact of products of the activity of Acidithiobacillus thiooxidans microorganisms on corrosion processes in concrete.

In addition, when using the TPD-MS method, it was established in the storage room of the finished product that heating the control sample of concrete leads to a release of the significant amount of СО2 at t=580–600 °C. However, the experimental samples of concrete are almost lacking carbon compounds because the acid metabolites of microfungi interfere with its formation. Microscopic and REM studies revealed the localization of Acidithiobacillus thiooxidans and Aspergillus fumigatus in concrete.

This study has established patterns related to the mechanism that forms chemical compounds in concrete and the metabolism of microorganisms

Author Biographies

Oksana Shkromada, Sumy National Agrarian University

Doctor of Veterinary Sciences, Professor

Department of Obstetrics and Surgery

Viktoriia Ivchenko, Sumy National Agrarian University

PhD, Associate Professor

Department of Therapy, Pharmacology, Clinical Diagnostics and Chemistry

Vadym Chivanov, Institute of Applied Physics, National Academy of Sciences of Ukraine

Doctor of Agricultural Sciences, Associate Professor

Depatrment of Radiation Biophysics

Liudmyla Tsyhanenko, Sumy National Agrarian University

PhD, Associate Professor

Department of Building Structures

Hennadii Tsyhanenko, Sumy National Agrarian University

Senior Lecturer

Department of Building Structures

Volodymir Moskalenko, Institute of Applied Physics, National Academy of Sciences of Ukraine

Chief Engineer of Complex Installation

Department of Nuclear Physics Research

Іryna Kyrchata, Kharkiv National Automobile and Highway University

PhD, Associate Professor

Department of Economics and Business

Olena Shersheniuk, Kharkiv National Automobile and Highway University

PhD, Associate Professor

Department of Economics and Business

Yuliia Litsman, Sumy State University

PhD, Associate Professor

Department of  Theoretical and Applied Chemistry

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Published

2021-04-12

How to Cite

Shkromada, O., Ivchenko, V., Chivanov, V., Tsyhanenko, L., Tsyhanenko, H., Moskalenko, V., Kyrchata І. ., Shersheniuk, O., & Litsman, Y. (2021). Defining patterns in the influence exerted by the interelated biochemical corrosion on concrete building structures under the conditions of a chemical enterprise . Eastern-European Journal of Enterprise Technologies, 2(6 (110), 52–60. https://doi.org/10.15587/1729-4061.2021.226587

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Section

Technology organic and inorganic substances