Correlations and selection of optimum conditions for chromatography of alkylcyclohexanecarboxylate production process

Authors

DOI:

https://doi.org/10.15587/1729-4061.2016.60307

Keywords:

alkylcyclohexanecarboxylates, gas-liquid chromatography, free energy linearity principle

Abstract

A number of esters of alkylcyclohexanecarboxylic acids are synthesized. The NMR spectral analysis of the synthesized esters is carried out, and their physicochemical characteristics are identified. Optimum parameters of the isothermal gas-liquid chromatography to analyze the reaction mixtures, the interaction of acrylates and 2,3-dimethyl-1,3-butadiene are determined.

The evaluation of the efficiency of the chromatography system and resolution settings is performed. The proposed chromatography conditions provide almost complete separation of the reaction mixture substances, and the analysis time does not exceed 15 min. The free energy linearity principle for the quantitative description of the relationship between the logarithms of the retention time of the substances, which are products of cycloaddition reaction of acrylates and 2,3-dimethyl-1,3-butadiene under gas chromatography and empirical parameters of substances: polarization, polarity, basicity, electrophilicity, molar volume and enthalpy of vaporization is applied. It is shown that in all cases the polarization ability of substances plays the greatest role in the correlations of the retention time logarithms, and the enthalpy of vaporization appeared a minor parameter. The developed method of chromatography analysis is used to determine the optimum conditions of the alkylcyclohexanecarboxylate production process.

The possibility of using correlations for predicting and determining the optimum conditions for chromatography analysis to monitor the processes of producing a number of esters of alkylcyclohexanecarboxylic acids is shown.

Author Biographies

Игорь Петрович Полюжин, National university Lviv Polytechnic 12 S. Bandery str., Lviv, Ukraine, 79013

PhD, Associate professor

Department of analytical chemistry

Institute of chemistry and chemical technologies 

Ольга Игоревна Маршалок, Danylo Halytsky Lviv National Medical University 69 Pekarskaya str., Lviv, Ukraine, 79010

Candidate of chemical sciences

Department of Analytical Chemistry

Наталия Мироновна Витрикуш, National university Lviv Polytechnic 12 S. Bandery str., Lviv, Ukraine, 79013

PhD, assistant

Department of сivil security

Vyacheslav Chornovil Institute of Ecology, Nature Protection and Tourism

Галина Алексеевна Маршалок, Jan and Jedrzej Sniadecki University of Technology and Life Sciences, 7 prof. S. Kaliskiego Al., Bydgoszcz, Poland, 85-796

Doctor of Technical Sciences, Professor

Игорь Юрьевич Пыриг, Lviv Institute of medical 76 Polishchuk str., Lviv, Ukraine, 79018

Candidate of chemical science, Associate professor

Department of chemistry

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Published

2016-02-21

How to Cite

Полюжин, И. П., Маршалок, О. И., Витрикуш, Н. М., Маршалок, Г. А., & Пыриг, И. Ю. (2016). Correlations and selection of optimum conditions for chromatography of alkylcyclohexanecarboxylate production process. Eastern-European Journal of Enterprise Technologies, 1(6(79), 13–18. https://doi.org/10.15587/1729-4061.2016.60307

Issue

Vol. 1 No. 6(79) (2016): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

License

Copyright (c) 2016 Игорь Петрович Полюжин, Ольга Игоревна Маршалок, Наталия Мироновна Витрикуш, Галина Алексеевна Маршалок, Игорь Юрьевич Пыриг

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