Synthesis of nanocomposites reduced graphene oxide-silver nanoparticles prepared by hydrothermal technique using sodium borohydride as a reductor for photocatalytic degradation of Pb ions in aqueous solution

Authors

DOI:

https://doi.org/10.15587/1729-4061.2022.269844

Keywords:

lead, reduced graphene oxide, silver nanoparticles, rGO/AgNPs nanocomposite, sodium borohydrate

Abstract

Heavy metals are pollutants that are harmful to living things and the environment can be degraded by microbes or understood by other living things so that they can cause health problems. One of the heavy metals that is often found in wastewater is lead. Lead is widely used in the manufacture of batteries, metal products such as ammunition, cable coatings, Polyvinyl Chloride (PVC) tubing, solder, chemicals and dyes

This use causes humans to be exposed to large amounts of lead. One method to deal with lead pollution is to use photocatalysts. Photocatalysts react with heavy metals and reduce them so that the level of toxicity becomes lower than before through photocatalytic reactions. In this study, synthesis of reduced graphene oxide/silver nanoparticle nanoparticles was performed by facile hydrothermal methods for photocatalytic degradation of Pb ion. The characterization results indicate that the synthesis has been successfully carried out. The successful result of rGO/AgNPs nanocomposites synthesis was proved by several techniques such as X-ray diffraction analysis, Raman, UV-Vis spectroscopy, Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray analysis (EDX). This indicates the presence of these groups in the graphene oxide and rGO/AgNPs samples, respectively. The resulting rGO/AgNPs nanocomposite has an absorbance peak at a wavelength of 267 nm. The diffraction peaks for nanocomposites rGO/AgNPs and their Miller indices were 38.08° (111), 44.16° (200), 64.44° (220), and 77.44° (311). The Raman spectra of rGO/AgNPs exhibits D bands at 1334,13 with intensity of 630,60 cm−1 and G band at 1594,61 with intensity of 477,29 cm−1. The ID/IG ratio rGO/AgNPs-NaBH4 is ~1,32. Furthermore, the photocatalytic activity test results showed that the rGO/AgNPs nanocomposite was able to reduce Pb2+ to Pb with a maximum exposure time of 1.5 hours

Supporting Agency

  • The research was carried out using laboratories at the Metallurgical Research Center, National Innovation Research Agency (BRIN) and material characterization from the analytical instrumentation facility ELSA (E-Layanan Sains).

Author Biographies

Nurhayati Indah Ciptasari, National Research and Innovation Agency (BRIN); Universitas Indonesia

Master of Science

Research Center for Metallurgy

Department of Metallurgy and Materials

Murni Handayani, National Research and Innovation Agency (BRIN)

Doctor of Philosophy (PhD)

Research Center for Advanced Materials

Caesart Leonardo Kaharudin, Universitas Gadjah Mada

Bachelor of Science

Department of Chemistry

Afif Akmal Afkauni, Universitas Gadjah Mada

Bachelor of Science

Department of Chemistry

Adhi Dwi Hatmanto, Universitas Gadjah Mada

Doctor of Philosophy, PhD

Department of Chemistry

Isa Anshori, Bandung Institute of Technology

Doctor of Philosophy, PhD

Department of Biomedical Engineering

School of Electrical Engineering and Informatics

Research Center for Nanosciences and Nanotechnology (RCNN)

Ahmad Maksum, Politeknik Negeri Jakarta

Doctor of Engineering, Assistant Professor

Research Center for Eco-Friendly Technology

Department of Mechanical Engineering

Rini Riastuti, Universitas Indonesia

Doctor of Engineering, Associate Professor

Johny Wahyuadi's Laboratory

Department of Metallurgy and Materials

Johny Wahyuadi Soedarsono, Universitas Indonesia

Doctor of Engineering, Professor

Johny Wahyuadi's Laboratory

Department of Metallurgy and Materials

References

  1. Masindi, V., Muedi, K. L. (2018). Environmental Contamination by Heavy Metals. Heavy Metals. doi: https://doi.org/10.5772/intechopen.76082
  2. Jaishankar, M., Tseten, T., Anbalagan, N., Mathew, B. B., Beeregowda, K. N. (2014). Toxicity, mechanism and health effects of some heavy metals. Interdisciplinary Toxicology, 7 (2), 60–72. doi: https://doi.org/10.2478/intox-2014-0009
  3. Litter, M. I. (2015). Mechanisms of removal of heavy metals and arsenic from water by TiO2-heterogeneous photocatalysis. Pure and Applied Chemistry, 87 (6), 557–567. doi: https://doi.org/10.1515/pac-2014-0710
  4. Gusain, R., Kumar, N., Ray, S. S. (2020). Factors Influencing the Photocatalytic Activity of Photocatalysts in Wastewater Treatment. Photocatalysts in Advanced Oxidation Processes for Wastewater Treatment, 229–270. doi: https://doi.org/10.1002/9781119631422.ch8
  5. Fröschl, T., Hörmann, U., Kubiak, P., Kučerová, G., Pfanzelt, M., Weiss, C. K. et al. (2012). High surface area crystalline titanium dioxide: potential and limits in electrochemical energy storage and catalysis. Chemical Society Reviews, 41 (15), 5313. doi: https://doi.org/10.1039/c2cs35013k
  6. Setvín, M., Aschauer, U., Scheiber, P., Li, Y.-F., Hou, W., Schmid, M. et al. (2013). Reaction of O2 with subsurface oxygen vacancies on TiO2 anatase (101). Science, 341 (6149), 988–991. doi: https://doi.org/10.1126/science.1239879
  7. Wang, L., Wei, H., Fan, Y., Liu, X., Zhan, J. (2009). Synthesis, Optical Properties, and Photocatalytic Activity of One-Dimensional CdS@ZnS Core-Shell Nanocomposites. Nanoscale Research Letters, 4 (6). doi: https://doi.org/10.1007/s11671-009-9280-3
  8. Chen, P., Wang, F., Chen, Z.-F., Zhang, Q., Su, Y., Shen, L. et al. (2017). Study on the photocatalytic mechanism and detoxicity of gemfibrozil by a sunlight-driven TiO2/carbon dots photocatalyst: The significant roles of reactive oxygen species. Applied Catalysis B: Environmental, 204, 250–259. doi: https://doi.org/10.1016/j.apcatb.2016.11.040
  9. Lv, N., Li, Y., Huang, Z., Li, T., Ye, S., Dionysiou, D. D., Song, X. (2019). Synthesis of GO/TiO2/Bi2WO6 nanocomposites with enhanced visible light photocatalytic degradation of ethylene. Applied Catalysis B: Environmental, 246, 303–311. doi: https://doi.org/10.1016/j.apcatb.2019.01.068
  10. Fan, W., Zhou, Z., Wang, W., Huo, M., Zhang, L., Zhu, S. et al. (2019). Environmentally friendly approach for advanced treatment of municipal secondary effluent by integration of micro-nano bubbles and photocatalysis. Journal of Cleaner Production, 237, 117828. doi: https://doi.org/10.1016/j.jclepro.2019.117828
  11. Kumar, A., Khan, M., Fang, L., Lo, I. M. C. (2019). Visible-light-driven N-TiO2@SiO2@Fe3O4 magnetic nanophotocatalysts: Synthesis, characterization, and photocatalytic degradation of PPCPs. Journal of Hazardous Materials, 370, 108–116. doi: https://doi.org/10.1016/j.jhazmat.2017.07.048
  12. Kar, P., Zeng, S., Zhang, Y., Vahidzadeh, E., Manuel, A., Kisslinger, R. et al. (2019). High rate CO2 photoreduction using flame annealed TiO2 nanotubes. Applied Catalysis B: Environmental, 243, 522–536. doi: https://doi.org/10.1016/j.apcatb.2018.08.002
  13. Méndez-Medrano, M. G., Kowalska, E., Lehoux, A., Herissan, A., Ohtani, B., Bahena, D. et al. (2016). Surface Modification of TiO2 with Ag Nanoparticles and CuO Nanoclusters for Application in Photocatalysis. The Journal of Physical Chemistry C, 120 (9), 5143–5154. doi: https://doi.org/10.1021/acs.jpcc.5b10703
  14. Kamat, P. V. (2011). Graphene-Based Nanoassemblies for Energy Conversion. The Journal of Physical Chemistry Letters, 2 (3), 242–251. doi: https://doi.org/10.1021/jz101639v
  15. Yuan, L., Zhang, C., Zhang, X., Lou, M., Ye, F., Jacobson, C. R. et al. (2019). Photocatalytic Hydrogenation of Graphene Using Pd Nanocones. Nano Letters, 19 (7), 4413–4419. doi: https://doi.org/10.1021/acs.nanolett.9b01121
  16. Guo, H., Jiang, N., Wang, H., Shang, K., Lu, N., Li, J., Wu, Y. (2019). Enhanced catalytic performance of graphene-TiO2 nanocomposites for synergetic degradation of fluoroquinolone antibiotic in pulsed discharge plasma system. Applied Catalysis B: Environmental, 248, 552–566. doi: https://doi.org/10.1016/j.apcatb.2019.01.052
  17. Russo, P., Hu, A., Compagnini, G. (2013). Synthesis, Properties and Potential Applications of Porous Graphene: A Review. Nano-Micro Letters, 5 (4), 260–273. doi: https://doi.org/10.1007/bf03353757
  18. Pastrana-Martínez, L. M., Morales-Torres, S., Figueiredo, J. L., Faria, J. L., Silva, A. M. T. (2018). Graphene photocatalysts. Multifunctional Photocatalytic Materials for Energy, 79–101. doi: https://doi.org/10.1016/b978-0-08-101977-1.00006-5
  19. Lee, C., Wei, X., Kysar, J. W., Hone, J. (2008). Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene. Science, 321 (5887), 385–388. doi: https://doi.org/10.1126/science.1157996
  20. Mayorov, A. S., Gorbachev, R. V., Morozov, S. V., Britnell, L., Jalil, R., Ponomarenko, L. A. et al. (2011). Micrometer-Scale Ballistic Transport in Encapsulated Graphene at Room Temperature. Nano Letters, 11 (6), 2396–2399. doi: https://doi.org/10.1021/nl200758b
  21. Park, S., Ruoff, R. S. (2009). Chemical methods for the production of graphenes. Nature Nanotechnology, 4 (4), 217–224. doi: https://doi.org/10.1038/nnano.2009.58
  22. Morales-Torres, S., Pastrana-Martínez, L. M., Figueiredo, J. L., Faria, J. L., Silva, A. M. T. (2012). Design of graphene-based TiO2 photocatalysts – a review. Environmental Science and Pollution Research, 19 (9), 3676–3687. doi: https://doi.org/10.1007/s11356-012-0939-4
  23. Kamat, P. V. (2009). Graphene-Based Nanoarchitectures. Anchoring Semiconductor and Metal Nanoparticles on a Two-Dimensional Carbon Support. The Journal of Physical Chemistry Letters, 1 (2), 520–527. doi: https://doi.org/10.1021/jz900265j
  24. Handayani, M., Mulyaningsih, Y., Aulia Anggoro, M., Abbas, A., Setiawan, I., Triawan, F. et al. (2022). One-pot synthesis of reduced graphene oxide/chitosan/zinc oxide ternary nanocomposites for supercapacitor electrodes with enhanced electrochemical properties. Materials Letters, 314, 131846. doi: https://doi.org/10.1016/j.matlet.2022.131846
  25. Handayani, M., Suwaji, B. I., Ihsantia Ning Asih, G., Kusumaningsih, T., Kusumastuti, Y., Rochmadi, Anshori, I. (2022). In-situ synthesis of reduced graphene oxide/silver nanoparticles (rGO/AgNPs) nanocomposites for high loading capacity of acetylsalicylic acid. Nanocomposites, 8 (1), 74–80. doi: https://doi.org/10.1080/20550324.2022.2054210
  26. Wang, N., Zhang, F., Mei, Q., Wu, R., Wang, W. (2020). Photocatalytic TiO2/rGO/CuO Composite for Wastewater Treatment of Cr(VI) Under Visible Light. Water, Air, & Soil Pollution, 231 (5). doi: https://doi.org/10.1007/s11270-020-04609-8
  27. Chong, M. N., Jin, B., Chow, C. W. K., Saint, C. (2010). Recent developments in photocatalytic water treatment technology: A review. Water Research, 44 (10), 2997–3027. doi: https://doi.org/10.1016/j.watres.2010.02.039
  28. Sarina, S., Waclawik, E. R., Zhu, H. (2013). Photocatalysis on supported gold and silver nanoparticles under ultraviolet and visible light irradiation. Green Chemistry, 15 (7), 1814. doi: https://doi.org/10.1039/c3gc40450a
  29. Tarcan, R., Todor-Boer, O., Petrovai, I., Leordean, C., Astilean, S., Botiz, I. (2020). Reduced graphene oxide today. Journal of Materials Chemistry C, 8 (4), 1198–1224. doi: https://doi.org/10.1039/c9tc04916a
  30. Latiff, N. M., Fu, X., Mohamed, D. K., Veksha, A., Handayani, M., Lisak, G. (2020). Carbon based copper(II) phthalocyanine catalysts for electrochemical CO2 reduction: Effect of carbon support on electrocatalytic activity. Carbon, 168, 245–253. doi: https://doi.org/10.1016/j.carbon.2020.06.066
  31. Ciptasari, N. I., Darsono, N., Handayani, M., Soedarsono, J. W. (2021). Synthesis of graphite oxide using hummers method: Oxidation time influence. AIP Conference Proceedings. doi: https://doi.org/10.1063/5.0061586
  32. Aliyev, E., Filiz, V., Khan, M. M., Lee, Y. J., Abetz, C., Abetz, V. (2019). Structural Characterization of Graphene Oxide: Surface Functional Groups and Fractionated Oxidative Debris. Nanomaterials, 9 (8), 1180. doi: https://doi.org/10.3390/nano9081180
  33. Handayani, M., Sulistiyono, E., Rokhmanto, F., Darsono, N., Fransisca, P. L., Erryani, A., Wardono, J. T. (2019). Fabrication of Graphene Oxide/Calcium Carbonate/Chitosan Nanocomposite Film with Enhanced Mechanical Properties. IOP Conference Series: Materials Science and Engineering, 578 (1), 012073. doi: https://doi.org/10.1088/1757-899x/578/1/012073
  34. Handayani, M., Kepakisan, K. A. A., Anshori, I., Darsono, N., Nugraha T., Y. (2021). Graphene oxide based nanocomposite modified screen printed carbon electrode for qualitative cefixime detection. AIP Conference Proceedings. doi: https://doi.org/10.1063/5.0060625
  35. Zhang, L., Tan, Q., Kou, H., Wu, D., Zhang, W., Xiong, J. (2019). Highly Sensitive NH3 Wireless Sensor Based on Ag-RGO Composite Operated at Room-temperature. Scientific Reports, 9 (1). doi: https://doi.org/10.1038/s41598-019-46213-9
  36. Krisnandi, Y. K., Abdullah, I., Prabawanta, I. B. G., Handayani, M. (2020). In-situ hydrothermal synthesis of nickel nanoparticle/reduced graphene oxides as catalyst on CO2 methanation. AIP Conference Proceedings. doi: https://doi.org/10.1063/5.0007992
  37. Liu, G., Huang, L., Wang, Y., Tang, J., Wang, Y., Cheng, M. et al. (2017). Preparation of a graphene/silver hybrid membrane as a new nanofiltration membrane. RSC Adv., 7 (77), 49159–49165. doi: https://doi.org/10.1039/c7ra07904d
  38. Gurunathan, S., Han, J. W., Park, J. H., Kim, E., Choi, Y., Kwon, D., Kim, J. (2015). Reduced graphene oxide–silver nanoparticle nanocomposite: a potential anticancer nanotherapy. Int J Nanomedicine, 10 (1), 6257–6276. doi: https://doi.org/10.2147/ijn.s92449
  39. Ciotta, E., Prosposito, P., Tagliatesta, P., Lorecchio, C., Stella, L., Kaciulis, S. et al. (2018). Discriminating between Different Heavy Metal Ions with Fullerene-Derived Nanoparticles. Sensors, 18 (5), 1496. doi: https://doi.org/10.3390/s18051496
Synthesis of nanocomposites reduced graphene oxide-silver nanoparticles prepared by hydrothermal technique using sodium borohydride as a reductor for photocatalitic degradation of Pb ions in aqueous solution

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Published

2022-12-30

How to Cite

Ciptasari, N. I., Handayani, M., Kaharudin, C. L., Afkauni, A. A., Hatmanto, A. D., Anshori, I., Maksum, A., Riastuti, R., & Soedarsono, J. W. (2022). Synthesis of nanocomposites reduced graphene oxide-silver nanoparticles prepared by hydrothermal technique using sodium borohydride as a reductor for photocatalytic degradation of Pb ions in aqueous solution. Eastern-European Journal of Enterprise Technologies, 6(5 (120), 54–62. https://doi.org/10.15587/1729-4061.2022.269844

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Section

Applied physics