Improvement the dielectric and impedance properties of Pb-free Bi0.5Na0.5TiO3-SrTiO3 piezoelectric materials modified by Fe2O3

Authors

DOI:

https://doi.org/10.15587/1729-4061.2024.307930

Keywords:

piezoelectric, BNT-ST, Fe2O3 doping, electric properties, Curie temperature

Abstract

The focus of this study is on the Fe2O3-doped Bi0.5Na0.5TiO3-SrTiO3 piezoelectric material. This is important to find ecologically acceptable piezoelectric materials. This research aims to obtain a lead-free piezoelectric material because lead is a material that is not environmentally friendly. An alternative solution is a piezoelectric material based on BNT-ST, which in this case is doped with Fe2O3 material. The study of Fe2O3 doped Bi0.5Na0.5TiO3-SrTiO3 piezoelectric material prepared by the solid-state reaction method was carried out to determine the optimum composition of the material formed. Doping variations are 0; 2.5; 5; 7.5; and 10 in mol %. The examinations were performed using X-ray diffraction (XRD) spectroscopy, a Scanning Electron Microscope (SEM), and an LCR meter. The Fe2O3 doped Bi0.5Na0.5TiO3-SrTiO3 produced a new compound in the form of FeBi5Ti3O15-Na2Ti3O7-SrTiO3 with the crystal structure of cubic, orthorhombic, and monoclinic, as well as the increasing crystalline size with the addition of dopants, exclude at 5 mol % and 7.5 mol %. FeBi5Ti3O15-Na2Ti3O7-SrTiO3 also produces varying particle sizes, which are between 0.88–8.23 µm. From the obtained data, the optimum composition of Fe2O3 doped Bi0.5Na0.5TiO3-SrTiO3 was the 2.5 mol % of Fe2O3 due to it having the highest dielectric constant (er ) and temperature Curie (Tc ), and also the lowest material impedance (Z) with the er of 12.037 at Tc of 400 °C and Z of 135 kΩ. The high piezoelectricity, which is indicated by the high value of the dielectric constant and Curie temperature, is possible due to the presence of a greater number of sodium ions in the Na2Ti3O7 phase. Sodium ions are ions with good electrical storage capabilities. The increase in dielectric constant in the BNT-ST piezoelectric obtained by the addition of Fe2O3 shows that this material can be used as a substitute for lead-based piezoelectric materials so that it is secure for the environment. The piezoelectric material of BNT-ST doped with Fe2O3 earned from this research can be applied to obtain electricity with a optimal value when given mechanical pressure

Author Biographies

Mukhtar Effendi, Jenderal Soedirman University

Doctor of Engineering, Associate Professor, Researcher

Department of Physics

Research and Development Center for New and Renewable Energy

Nugraheni Puspita Rini, Jenderal Soedirman University

Master of Science (Doctor Candidate), Research Assistant

Department of Physics

Candra Kurniawan, National Research and Innovation (BRIN)

Researcher

Research Center for Advanced Material

Wahyu Tri Cahyanto, Jenderal Soedirman University

Professor

Department of Physics

Wahyu Widanarto, Jenderal Soedirman University

Professor

Department of Physics

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Improvement the dielectric and impedance properties of Pb-free Bi0.5Na0.5TiO3-SrTiO3 piezoelectric materials modified by Fe2O3

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Published

2024-08-30

How to Cite

Effendi, M., Rini, N. P., Kurniawan, C., Cahyanto, W. T., & Widanarto, W. (2024). Improvement the dielectric and impedance properties of Pb-free Bi0.5Na0.5TiO3-SrTiO3 piezoelectric materials modified by Fe2O3. Eastern-European Journal of Enterprise Technologies, 4(12 (130), 49–57. https://doi.org/10.15587/1729-4061.2024.307930

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Vol. 4 No. 12 (130) (2024): Materials Science

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Materials Science

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Copyright (c) 2024 Mukhtar Effendi, Nugraheni Puspita Rini, Candra Kurniawan, Wahyu Tri Cahyanto, Wahyu Widanarto

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