Electrochromism of Ni(OH)2 films obtained by cathode template method with addition of Al, Zn, Co ions

Authors

  • Valerii Kotok Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000, Ukraine https://orcid.org/0000-0001-8879-7189
  • Vadym Kovalenko Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000, Ukraine https://orcid.org/0000-0002-8012-6732

DOI:

https://doi.org/10.15587/1729-4061.2017.103010

Keywords:

nickel hydroxide, Ni(OH)2, electrochromism, electrodeposition, cathodic template synthesis, polyvinyl alcohol, layered double hydroxide

Abstract

The films from mixed solutions of nickel-aluminum, nickel-zinc and nickel-cobalt have been prepared using the cathodic template synthesis with polyvinyl alcohol as a template. The prepared films have been studied by means of X-ray diffraction analysis, cyclic voltamperometry with simultaneous recording of the transparency change. The results have shown that the addition of aluminum and cobalt allows obtaining layered double hydroxides. However, the addition of aluminum leads not only to the formation of layered double hydroxide but also to poisoning of the active material.

In case of deposition from solutions containing cobalt, the obtained films have good electrochemical and electrochromic properties, and also two-stage color transition. The film obtained at a molar ratio of nickel to cobalt of 8:1 possesses the best electrochromic characteristics and coloration degree of 0.8, which is more than for the film obtained from nickel nitrate solution without additives of other metals by 0.2.

Author Biographies

Valerii Kotok, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000

PhD, Associate Professor

Department of Processes, Apparatus and General Chemical Technology

Department of Technologies of Inorganic Substances and Electrochemical Manufacturing

Vadym Kovalenko, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000

PhD, Associate Professor

Department of Analytical Chemistry and Food Additives and Cosmetics

Department of Technologies of Inorganic Substances and Electrochemical Manufacturing

References

  1. Кovalenko, V., Kotok, V., Bolotin, O. (2016). Definition of factors influencing on Ni(OH)2 electrochemical characteristics for supercapacitors. Eastern-European Journal of Enterprise Technologies, 5 (6 (83)), 17–22. doi: 10.15587/1729-4061.2016.79406
  2. Kovalenko, V. L., Kotok, V. A., Sykchin, A. A., Mudryi, I. A., Ananchenko, B. A., Burkov, A. A. et. al. (2016). Nickel hydroxide obtained by high-temperature two-step synthesis as an effective material for supercapacitor applications. Journal of Solid State Electrochemistry, 21 (3), 683–691. doi: 10.1007/s10008-016-3405-2
  3. Solovov, V., Кovalenko, V., Nikolenko, N., Kotok, V., Vlasova, E. (2017). Influence of temperature on the characteristics of Ni(II), Ti(IV) layered double hydroxides synthesised by different methods. Eastern-European Journal of Enterprise Technologies, 1 (6 (85)), 16–22. doi: 10.15587/1729-4061.2017.90873
  4. Huang, J.-J., Hwang, W.-S., Weng, Y.-C., Chou, T.-C. (2010). Transformation Characterization of Ni(OH)2/NiOOH in Ni-Pt Films Using an Electrochemical Quartz Crystal Microbalance for Ethanol Sensors. Materials Transactions, 51 (12), 2294–2303. doi: 10.2320/matertrans.m2010079
  5. Niklasson, G. A., Granqvist, C. G. (2007). Electrochromics for smart windows: thin films of tungsten oxide and nickel oxide, and devices based on these. J. Mater. Chem., 17 (2), 127–156. doi: 10.1039/b612174h
  6. Cospito, S., Beneduci, A., Veltri, L., Salamonczyk, M., Chidichimo, G. (2015). Mesomorphism and electrochemistry of thienoviologen liquid crystals. Phys. Chem. Chem. Phys., 17 (27), 17670–17678. doi: 10.1039/c5cp02350e
  7. Lampert, C. M. (2004). Chromogenic smart materials. Materials Today, 7 (3), 28–35. doi: 10.1016/s1369-7021(04)00123-3
  8. Granqvist, C. G. (2014). Electrochromics for smart windows: Oxide-based thin films and devices. Thin Solid Films, 564, 1–38. doi: 10.1016/j.tsf.2014.02.002
  9. Browne, M. P. (2016). Electrochromic Nickel Oxide Films for Smart Window Applications. International Journal of Electrochemical Science, 6636–6647. doi: 10.20964/2016.08.38
  10. Kotok, V., Kovalenko, V. (2017). The electrochemical cathodic template synthesis of nickel hydroxide thin films for electrochromic devices: role of temperature. Eastern-European Journal of Enterprise Technologies, 2 (11 (86)), 28–34. doi: 10.15587/1729-4061.2017.97371
  11. Usha, K. S., Sivakumar, R., Sanjeeviraja, C., Sathe, V., Ganesan, V., Wang, T. Y. (2016). Improved electrochromic performance of a radio frequency magnetron sputtered NiO thin film with high optical switching speed. RSC Adv., 6 (83), 79668–79680. doi: 10.1039/c5ra27099e
  12. Velevska, J., Ristova, M. (2002). Electrochromic properties of NiOx prepared by low vacuum evaporation. Solar Energy Materials and Solar Cells, 73 (2), 131–139. doi: 10.1016/s0927-0248(01)00118-0
  13. Xia, X. H., Tu, J. P., Zhang, J., Wang, X. L., Zhang, W. K., Huang, H. (2008). Electrochromic properties of porous NiO thin films prepared by a chemical bath deposition. Solar Energy Materials and Solar Cells, 92 (6), 628–633. doi: 10.1016/j.solmat.2008.01.009
  14. Dalavi, D. S., Devan, R. S., Patil, R. S., Ma, Y.-R., Patil, P. S. (2013). Electrochromic performance of sol–gel deposited NiO thin film. Materials Letters, 90, 60–63. doi: 10.1016/j.matlet.2012.08.108
  15. Franta, D., Negulescu, B., Thomas, L., Dahoo, P. R., Guyot, M., Ohlidal, I. et. al. (2005). Optical properties of NiO thin films prepared by pulsed laser deposition technique. Applied Surface Science, 244 (1-4), 426–430. doi: 10.1016/j.apsusc.2004.09.150
  16. Sharma, R., Acharya, A. D., Shrivastava, S. B., Shripathi, T., Ganesan, V. (2014). Preparation and characterization of transparent NiO thin films deposited by spray pyrolysis technique. Optik – International Journal for Light and Electron Optics, 125 (22), 6751–6756. doi: 10.1016/j.ijleo.2014.07.104
  17. Chigane, M. (1994). Enhanced Electrochromic Property of Nickel Hydroxide Thin Films Prepared by Anodic Deposition. Journal of The Electrochemical Society, 141 (12), 3439. doi: 10.1149/1.2059350
  18. Kotok, V. A., Kovalenko, V. L., Ananchenko, B. А., Levko, E. N. (2014). The deposition of electrochromic film based on nikel hydroxide by electrochemical method. XV International scientific conference «New Technologies and achievements in metallurgy, materials engineering and production engineering». Czestochowa, 448–452.
  19. Hall, D. S., Lockwood, D. J., Bock, C., MacDougall, B. R. (2014). Nickel hydroxides and related materials: a review of their structures, synthesis and properties. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 471 (2174), 20140792–20140792. doi: 10.1098/rspa.2014.0792
  20. Ten'kovcev, V. V., Centr, B. I. (1985). Osnovy teorii i ehkspluatacii germetichnyh akkumulyatorov. Leningrad, 96.
  21. Liu, B., Wang, X. Y., Yuan, H. T., Zhang, Y. S., Song, D. Y., Zhou, Z. X. (1999). Physical and electrochemical characteristics of aluminium-substituted nickel hydroxide. Journal of Applied Electrochemistry, 29 (7), 853–858. doi: 10.1023/a:1003537900947

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Published

2017-06-19

How to Cite

Kotok, V., & Kovalenko, V. (2017). Electrochromism of Ni(OH)2 films obtained by cathode template method with addition of Al, Zn, Co ions. Eastern-European Journal of Enterprise Technologies, 3(12 (87), 38–43. https://doi.org/10.15587/1729-4061.2017.103010

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Section

Materials Science