Studying the influence of design and operation mode parameters on efficiency of the systems of biochemical purification of emissions

Authors

DOI:

https://doi.org/10.15587/1729-4061.2018.133316

Keywords:

biological purification of emissions, design and operation mode parameters, bioreactor, purification efficiency

Abstract

A procedure for evaluating efficiency of the systems of biological elimination of soluble and insoluble in water harmful gaseous substances as well as dissolved in water contaminants has been devised. The procedure is based on previously developed mathematical models of the corresponding non-stationary bio oxidation processes. Based on the analysis of 27 design versions, real capabilities of biological purification facilities were shown, the effect of design and operation mode parameters on efficiency of the systems of biological destruction of methane, hydrogen sulfide and formaldehyde were assessed. In quantitative terms, the results obtained in numerical experiments indicate the necessity of taking into account variation of the rate of pollutant inflow in the process of vessel filling. It was established that an increase in the facility efficiency in terms of the volume of the gas-air mixture, N, causes a decrease in methane concentration at the bioreactor entry and a reduction of the purification degree to 62 %. An increase in the rate of hydrogen sulfide inflow to the reactor leads to a reduction of the purification degree from 98 to 95 %. An increase in the initial concentration of biomass by a factor of 1.7 causes a decrease in concentration of hydrogen sulfide in water from 2.5 to 1.1 g/m3. A significant decrease in the average specific bio oxidative power with an increase in the working space in which the final stage of emission purification from formaldehyde takes place was also observed.

The revealed regularities represent a tool for improving quality of design solutions and increasing effectiveness of bio oxidation modes in operation of the systems of biological gas purification.

Author Biographies

Anna Bakharevа, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD, Associate Professor

Department of occupational safety and environmental

Oleksii Shestopalov, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD, Associate Professor

Department of chemical technique and industrial ecology

 

Olesya Filenko, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD, Associate professor

Department of chemical technique and industrial ecology

Tetyana Tykhomyrova, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD, Senior Lecturer

Department of chemical technique and industrial ecology

Olga Rybalova, National University of Civil Defence of Ukraine Chernyshevska str., 94, Kharkiv, Ukraine, 61023

PhD, Associate Professor

Department of Labour Protection and technogenic and ecological safety

Sergey Artemiev, National University of Civil Defence of Ukraine Chernyshevska str., 94, Kharkiv, Ukraine, 61023

PhD, Associate Professor

Department of Labour Protection and technogenic and ecological safety

Olena Bryhada, National University of Civil Defence of Ukraine Chernyshevska str., 94, Kharkiv, Ukraine, 61023

PhD, Associate Professor

Department of Labour Protection and technogenic and ecological safety

References

  1. Kennes, C., Rene, E. R., Veiga, M. C. (2009). Bioprocesses for air pollution control. Journal of Chemical Technology & Biotechnology, 84 (10), 1419–1436. doi: 10.1002/jctb.2216
  2. Shestopalov, O., Pitak, I. V. (2014). Analysis of existent processes and devices of bioscrubbing gas emissions. Technology audit and production reserves, 3 (5 (17)), 49–52. doi: 10.15587/2312-8372.2014.25373
  3. Seedorf, J. (2013). Biological exhaust air treatment systems as a potential microbial risk for farm animals assessed with a computer simulation. Journal of the Science of Food and Agriculture, 93 (12), 3129–3132. doi: 10.1002/jsfa.6106
  4. Iranpour, R., Cox, H. H. J., Deshusses, M. A., Schroeder, E. D. (2005). Literature review of air pollution control biofilters and biotrickling filters for odor and volatile organic compound removal. Environmental Progress, 24 (3), 254–267. doi: 10.1002/ep.10077
  5. Estrada, J. M., Bernal, O. I., Flickinger, M. C., Muñoz, R., Deshusses, M. A. (2014). Biocatalytic coatings for air pollution control: A proof of concept study on VOC biodegradation. Biotechnology and Bioengineering, 112 (2), 263–271. doi: 10.1002/bit.25353
  6. Hernández, J., Dorado, A. D., Lafuente, J., Gamisans, X., Prado, Ó. J., Gabriel, D. (2016). Characterization and evaluation of poplar and pine wood in twin biotrickling filters treating a mixture of NH3, H2S, butyric acid, and ethylmercaptan. Environmental Progress & Sustainable Energy, 36 (1), 171–179. doi: 10.1002/ep.12491
  7. Liu, D., Feilberg, A., Hansen, M. J., Pedersen, C. L., Nielsen, A. M. (2015). Modeling removal of volatile sulfur compounds in a full-scale biological air filter. Journal of Chemical Technology & Biotechnology, 91 (4), 1119–1127. doi: 10.1002/jctb.4696
  8. Rojo, N., Muñoz, R., Gallastegui, G., Barona, A., Gurtubay, L., Prenafeta-Boldú, F. X., Elías, A. (2012). Carbon disulfide biofiltration: Influence of the accumulation of biodegradation products on biomass development. Journal of Chemical Technology & Biotechnology, 87 (6), 764–771. doi: 10.1002/jctb.3743
  9. Malhautier, L., Cariou, S., Legrand, P., Touraud, E., Geiger, P., Fanlo, J.-L. (2014). Treatment of complex gaseous emissions emitted by a rendering facility using a semi-industrial biofilter. Journal of Chemical Technology & Biotechnology, 91 (2), 426–430. doi: 10.1002/jctb.4593
  10. Song, T., Yang, C., Zeng, G., Yu, G., Xu, C. (2012). Effect of surfactant on styrene removal from waste gas streams in biotrickling filters. Journal of Chemical Technology & Biotechnology, 87 (6), 785–790. doi: 10.1002/jctb.3717
  11. Álvarez-Hornos, F. J., Volckaert, D., Heynderickx, P. M., Van Langenhove, H. (2012). Removal of ethyl acetate, n-hexane and toluene from waste air in a membrane bioreactor under continuous and intermittent feeding conditions. Journal of Chemical Technology & Biotechnology, 87 (6), 739–745. doi: 10.1002/jctb.3734
  12. Nelson, M., Bohn, H. L. (2011). Soil-Based Biofiltration for Air Purification:Potentials for Environmental and Space LifeSupport Application. Journal of Environmental Protection, 02 (08), 1084–1094. doi: 10.4236/jep.2011.28125
  13. González-Sánchez, A., Arellano-García, L., Bonilla-Blancas, W., Baquerizo, G., Hernández, S., Gabriel, D., Revah, S. (2014). Kinetic Characterization by Respirometry of Volatile Organic Compound-Degrading Biofilms from Gas-Phase Biological Filters. Industrial & Engineering Chemistry Research, 53 (50), 19405–19415. doi: 10.1021/ie503327f
  14. Shareefdeen, Z., Aidan, A., Ahmed, W., Khatri, M. B., Islam, M., Lecheheb, R., Shams, F. (2010). Hydrogen Sulphide Removal Using a Novel Biofilter Media. International Journal of Chemical and Molecular Engineering, 4 (2), 145–148.
  15. Shareefdeen, Z. M., Ahmed, W., Aidan, A. (2011). Kinetics and Modeling of H2S Removal in a Novel Biofilter. Advances in Chemical Engineering and Science, 01 (02), 72–76. doi: 10.4236/aces.2011.12012
  16. Bonilla-Blancas, W., Mora, M., Revah, S., Baeza, J. A., Lafuente, J., Gamisans, X. et. al. (2015). Application of a novel respirometric methodology to characterize mass transfer and activity of H2S-oxidizing biofilms in biotrickling filter beds. Biochemical Engineering Journal, 99, 24–34. doi: 10.1016/j.bej.2015.02.030
  17. Ahmed, W., Shareefdeen, Z. M., Jabbar, N. A. (2013). Dynamic modeling and analysis of biotrickling filters in continuous operation for H2S removal. Clean Technologies and Environmental Policy, 16 (8), 1757–1765. doi: 10.1007/s10098-013-0697-0
  18. Bakharevа, A., Shestopalov, O., Semenov, Ye. O., Bukatenko, N. O. (2015). Macrokinetic mathematical model development of biological treatment process of gasiform emissions. ScienceRise, 2 (2 (7)), 12–15. doi: 10.15587/2313-8416.2015.37057
  19. Bakharevа, A., Shestopalov, O., Filenko, O., Tykhomyrova, Т. (2015). Development of a mathematical model of the process of biological treatment of gaseous emissions. Eastern-European Journal of Enterprise Technologies, 6 (6 (78)), 53–61. doi: 10.15587/1729-4061.2015.56220
  20. Bakharevа, A., Shestopalov, O., Filenko, O., Novozhylova, T., Kobilyansky, B. (2017). Development of the mathematical model of the biotreatment process of water-soluble gaseous emissions. Eastern-European Journal of Enterprise Technologies, 2 (6 (86)), 56–62. doi: 10.15587/1729-4061.2017.98675
  21. Bakharevа, A., Shestopalov, O., Filenko, O., Tykhomyrova, Т. (2016). Development of a mathematical model of the process of biological treatment of gasous effluents from formaldehyde. Eastern-European Journal of Enterprise Technologies, 1 (10 (79)), 4–10. doi: 10.15587/1729-4061.2016.59508
  22. Bakharevа, A., Shestopalov, O., Filenko, O. (2016). Development of universal model of kinetics of bioremediation stationary process with substrate inhibition. Eastern-European Journal of Enterprise Technologies, 2 (10 (80)), 19–26. doi: 10.15587/1729-4061.2016.65036

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Published

2018-06-11

How to Cite

Bakharevа A., Shestopalov, O., Filenko, O., Tykhomyrova, T., Rybalova, O., Artemiev, S., & Bryhada, O. (2018). Studying the influence of design and operation mode parameters on efficiency of the systems of biochemical purification of emissions. Eastern-European Journal of Enterprise Technologies, 3(10 (93), 59–71. https://doi.org/10.15587/1729-4061.2018.133316