DOI: https://doi.org/10.15587/1729-4061.2019.170488

Principles of the progress of reactions involving deep oxidation of isopropyl alcohol under conditions of aerosol nanocatalysis technology

Tobenna Chimdiadi Philips, Sergey Kudryavtsev, Irene Glikina, Danil Korol

Abstract


We studied the process of deep oxidation of isopropyl alcohol under conditions of aerosol nanocatalysis technology. The process was carried out in a reactor with a vibro-fluidized bed of a catalytic system, which consists of powder of a catalytically active Fe2O3 substance and dispersing material. We performed a study for the further development of an environmentally friendly catalytic heat generator, which would operate in accordance with principles of nanotechnology. It was noted that the main controlling factors in the applied method of aerosol nanocatalysis are temperature and mechanical-and-chemical activation of a catalyst. Mechanical-and-chemical activation makes it possible to adjust a mode of vibro-fluidization to obtain the required reaction products. We modernized the laboratory unit to study the processes by the method of aerosol nanocatalysis in a vibro-fluidized bed of a catalytic system for tasks of deep catalytic oxidation of isopropanol.

We carried out experimental studies into the effect of temperature on carbon monoxide content in oxidation gases, a degree of isopropanol transformation, and selectivity of the deep oxidation process. It has been shown that it is possible to achieve almost 100 % oxidation of isopropanol to СО2 in aerosol of nanoparticles of iron oxide at temperatures below 630 °C. The mentioned fact makes it possible to use low-alloyed steels and to reduce equipment costs in future technology. The results of the study give a possibility to determine a direction of the further research to optimize parameters of the process of control of oxidation of isopropyl alcohol for its deep oxidation and to obtain free energy for further use. We performed comparison of some technical-and-economic parameters of the process being developed with the processes based on heterogeneous catalysis.


Keywords


aerosol nanocatalysis; mechanical-and-chemical activation; oxidation; isopropyl alcohol; frequency; catalytic heat generator

References


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Nulevoy sbor: v Minagropolitiki hotyat obnulit' aktsiz na etiloviy spirt. Available at: http://dengi.ua/business/285126-Nylevoi-sbor-v-Minagropolitiki-hotyat-obnylit-akciz-na-etilovii-spirt

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Dimov, S., Gasenko, O. (2017). Catalytic combustion and steam reforming of hydrocarbons in microreactor. MATEC Web of Conferences, 115, 03011. doi: https://doi.org/10.1051/matecconf/201711503011

Vereshchagin, S. N., Solov’ev, L. A., Rabchevskii, E. V., Dudnikov, V. A., Ovchinnikov, S. G., Anshits, A. G. (2015). New method for regulating the activity of ABO3 perovskite catalysts. Kinetics and Catalysis, 56 (5), 640–645. doi: https://doi.org/10.1134/s0023158415040199

Chang, Y.-J., Lin, C.-H., Hwa, M.-Y. et. al. (2010). Study on the decomposition of isopropyl alcohol by using microwave/Fe3O4 catalytic system. J. Environ. Eng. Manage, 20 (2), 63–68.

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McCarthy, J. G., Chang, Y. F., Wong, V. L., Johansson, E. M. (1997). Kinetics of high temperature methane combustion by metal oxide catalysts. Div. Petrol. Chem., 42, 158–165.

Vayenas, C. G., Bebelis, S., Pliangos, C., Brosda, S., Tsiplakides, D. (2001). Electrochemical Activation of Catalysis. Promotion, Electrochemical Promotion, and Metal-Support Interactions. Springer, 574. doi: https://doi.org/10.1007/b115566

Glikin, M. A. (1996). Aerozol'niy kataliz. Teoreticheskie osnovy himicheskoy tekhnologii, 30 (4), 430–435.

Spivey, J. J, Roberts, G. W. (2004). Catalysis. The Royal Society of Chemistry, 17, 1–115.

Zwinkels, M. F. M., Järås, S. G., Menon, P. G., Griffin, T. A. (1993). Catalytic Materials for High-Temperature Combustion. Catalysis Reviews, 35 (3), 319–358. doi: https://doi.org/10.1080/01614949308013910

Sheludyakov, E. P. (2009). Pat. No. 2406954 RF. Kataliticheskiy generator tepla. No. 2009127412/06; declareted: 16.07.2009; published: 20.12.2010. Bul. No. 35, 5.

Strizhak, P. Y., Solovyov, S. O., Trypolsky, A. I., Kirienko, P. I., Stoliarchuk, I. L. (2016). Self-Sustained Flameless Heat Generator Based on Catalytic Oxidation of Methane or Propane-Butane Mixture for Various Object Heating Including Field Heating. Nauka ta innovacii, 12 (5), 32–46. doi: https://doi.org/10.15407/scin12.05.032

Simonov, A. D., Fedorov, I. A., Dubinin, Y. V., Yazikov, N. A., Yakovlev, V. A., Parmon, V. N. (2012). Catalytic thermal systems for industrial heating. Kataliz v promyshlennosti, 3, 50–57.

Hayes, R. E., Kolackkowski, S. T. (1997). Introduction to catalytic combustion. Gordon & Breach, 681.

Glikin, M. А., Kudryavtsev, S. A., Glikina, I. M. (2016). Improvement of production by aerosol nanocatalysis technology with mechanical activation of catalyst particles. Technology audit and production reserves, 6 (3 (32)), 4–8. doi: https://doi.org/10.15587/2312-8372.2016.85475

Glikin, M. A., Glikina, I. M., Kauffeldt, E. (2005). Investigations and Applications of Aerosol Nano-Catalysis in a Vibrofluidized (Vibrating) Bed. Adsorption Science & Technology, 23 (2), 135–143. doi: https://doi.org/10.1260/0263617054037781

Luhovskoi, A., Glikin, M., Kudryavtsev, S., Glikina, I. (2017). Obtaining synthesis-gas by the stone coal steam conversion using technology of aerosol nanocatalysis. Eastern-European Journal of Enterprise Technologies, 6 (6 (90)), 53–58. doi: https://doi.org/10.15587/1729-4061.2017.118396


GOST Style Citations


Donmez E. Catalytic combustion of methanol on structured catalyst for direct methanol fuel cell. Izmir, 2011. 69 p.

Nulevoy sbor: v Minagropolitiki hotyat obnulit' aktsiz na etiloviy spirt. URL: http://dengi.ua/business/285126-Nylevoi-sbor-v-Minagropolitiki-hotyat-obnylit-akciz-na-etilovii-spirt

High-purity propylene from refinery LPG / Palmer E. D., Glasgow I., Nijhawan S., Clark D., Guzman L.  // Crambeth Allen Publishing Ltd. 2012. URL: https://www.digitalrefining.com/article/1000361,High_purity_propylene_from_refinery_LPG.html#.XObYvFYzbIU

Prasad R., Kennedy L. A., Ruckenstein E. Catalytic Combustion // Catalysis Reviews. 1984. Vol. 26, Issue 1. P. 1–58. doi: https://doi.org/10.1080/01614948408078059 

Glikin M. An alternative technology for catalytical processes. the aerosol nanocatalysis // Eastern-European Journal of Enterprise Technologies. 2014. Vol. 5, Issue 6 (71). P. 4–11. doi: https://doi.org/10.15587/1729-4061.2014.27700 

Dimov S., Gasenko O. Catalytic combustion and steam reforming of hydrocarbons in microreactor // MATEC Web of Conferences. 2017. Vol. 115. P. 03011. doi: https://doi.org/10.1051/matecconf/201711503011 

New method for regulating the activity of ABO3 perovskite catalysts / Vereshchagin S. N., Solov’ev L. A., Rabchevskii E. V., Dudnikov V. A., Ovchinnikov S. G., Anshits A. G. // Kinetics and Catalysis. 2015. Vol. 56, Issue 5. P. 640–645. doi: https://doi.org/10.1134/s0023158415040199 

Study on the decomposition of isopropyl alcohol by using microwave/Fe3O4 catalytic system / Chang Y.-J., Lin C.-H., Hwa M.-Y. et. al. // J. Environ. Eng. Manage. 2010. Vol. 20, Issue 2. P. 63–68.

Tu Y.-J., Lou J. C. Isopropyl alcohol combustion on ferrite catalyst NiFe2O4 // Proc. of the 3rd IASME/WSEAS int. conf. on Energy Environment, Ecosystems and Sustainabele Development. Agios Nikolaos, 2007. P. 307–312.

Kinetics of high temperature methane combustion by metal oxide catalysts / McCarthy J. G., Chang Y. F., Wong V. L., Johansson E. M. // Div. Petrol. Chem. 1997. Vol. 42. P. 158–165.

Electrochemical Activation of Catalysis. Promotion, Electrochemical Promotion, and Metal-Support Interactions / Vayenas C. G., Bebelis S., Pliangos C., Brosda S., Tsiplakides D. Springer, 2001. 574 p. doi: https://doi.org/10.1007/b115566 

Glikin M. A. Aerozol'niy kataliz // Teoreticheskie osnovy himicheskoy tekhnologii. 1996. Vol. 30, Issue 4. P. 430–435.

Spivey J. J, Roberts G. W. Catalysis // The Royal Society of Chemistry. 2004. Vol. 17. Р. 1–115.

Catalytic Materials for High-Temperature Combustion / Zwinkels M. F. M., Järås S. G., Menon P. G., Griffin T. A. // Catalysis Reviews. 1993. Vol. 35, Issue 3. P. 319–358. doi: https://doi.org/10.1080/01614949308013910 

Sheludyakov E. P. Kataliticheskiy generator tepla: Pat. No. 2406954 RF. No. 2009127412/06; declareted: 16.07.2009; published: 20.12.2010. Bul. No. 35. 5 p.

Self-Sustained Flameless Heat Generator Based on Catalytic Oxidation of Methane or Propane-Butane Mixture for Various Object Heating Including Field Heating / Strizhak P. Y., Solovyov S. O., Trypolsky A. I., Kirienko P. I., Stoliarchuk I. L. // Nauka ta innovacii. 2016. Vol. 12, Issue 5. P. 32–46. doi: https://doi.org/10.15407/scin12.05.032 

Catalytic thermal systems for industrial heating / Simonov A. D., Fedorov I. A., Dubinin Y. V., Yazikov N. A., Yakovlev V. A., Parmon V. N. // Kataliz v promyshlennosti. 2012. Issue 3. P. 50–57.

Hayes R. E., Kolackkowski S. T. Introduction to catalytic combustion. Gordon & Breach, 1997. 681 р.

Glikin M. А., Kudryavtsev S. A., Glikina I. M. Improvement of production by aerosol nanocatalysis technology with mechanical activation of catalyst particles // Technology audit and production reserves. 2016. Vol. 6, Issue 3 (32). P. 4–8. doi: https://doi.org/10.15587/2312-8372.2016.85475 

Glikin M. A., Glikina I. M., Kauffeldt E. Investigations and Applications of Aerosol Nano-Catalysis in a Vibrofluidized (Vibrating) Bed // Adsorption Science & Technology. 2005. Vol. 23, Issue 2. P. 135–143. doi: https://doi.org/10.1260/0263617054037781 

Obtaining synthesis-gas by the stone coal steam conversion using technology of aerosol nanocatalysis / Luhovskoi A., Glikin M., Kudryavtsev S., Glikina I. // Eastern-European Journal of Enterprise Technologies. 2017. Vol. 6, Issue 6 (90). P. 53–58. doi: https://doi.org/10.15587/1729-4061.2017.118396 







Copyright (c) 2019 Tobenna Chimdiadi Philips, Sergey Kudryavtsev, Irene Glikina, Danil Korol

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ISSN (print) 1729-3774, ISSN (on-line) 1729-4061