Patterns in the synthesis processes and the characteristics of silicate-spinal ceramic pigments when introducing mineralizers

Authors

DOI:

https://doi.org/10.15587/1729-4061.2020.196725

Keywords:

ceramic pigments, mineralizers, firing, crystal-phase composition, color indicators, glaze coatings

Abstract

The synthesis of ceramic pigments is conventionally carried out at a high temperature (not less than 1,200 °C). Its reduction implies using mineralizing additives, which have a different mechanism of action on the starting components of pigment charges. The effectiveness of the mineralizers is determined by their nature, content, degree of dispersion in the activated reagent. Thus, searching for the most effective mineralizers in the synthesis, in particular, of silicate-spinel ceramic pigments is an important scientific and practical task.

We have investigated the effect of various mineralizing additives (B2O3, Na2B4O7, Na2O, NaF) on the processes of forming the crystal-phase composition of slag-containing ceramic pigments and the change in their color indicators. A direct dependence has been established between the melting point of the mineralizers and the efficiency of their influence on the formation of spinel phases, which are color carriers in such pigments. The tangible effect of the introduction of sodium fluoride, which has the highest melting point among the examined additives, is achieved as a result of the firing of pigments at a temperature not lower than 1,150 °C. The effect of sodium oxide is effective starting at a temperature of 1,100 °C. The most expedient to apply are the boron-containing compounds. Their introduction makes it possible to lower the firing temperature of slag-containing pigments to 1,050 °C while completely binding the starting components in the spinel solid solutions. The ceramic pigments that are thus synthesized enable the formation of glazed coatings, which, in terms of qualitative indicators, are not inferior to coatings obtained with the addition of high-temperature pigments (a firing temperature of 1,200–1,250 °С). The formation of silicate phases (diopside and wollastonite), which are not color carriers in the examined pigments, undergoes effective mineralized action from the supplements of NaF and B2O3

Author Biographies

Oleksandr Zaichuk, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005

Doctor of Technical Sciences, Associate Professor

Department of Chemical Technology of Ceramics, Glass and Building Materials

Аleksandra Amelina, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005

PhD

Department of Chemical Technology of Ceramics, Glass and Building Materials

Olena Khomenko, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005

PhD, Associate Professor

Department of Chemical Technology of Ceramics, Glass and Building Materials

Nataliia Sribniak, Sumy National Agrarian University Herasyma Kondratieva str., 160, Sumy, Ukraine, 40021

PhD, Associate Professor

Department of Building Structures

Liudmyla Tsyhanenko, Sumy National Agrarian University Herasyma Kondratieva str., 160, Sumy, Ukraine, 40021

PhD, Associate Professor

Department of Building Structures

Oleksandr Savchenko, Sumy National Agrarian University Herasyma Kondratieva str., 160, Sumy, Ukraine, 40021

PhD

Department of Building Structures

Oleksandr Telichenko, Sumy National Agrarian University Herasyma Kondratieva str., 160, Sumy, Ukraine, 40021

Senior Lecturer

Department of Construction Operations

References

  1. Maslennikova, G. N., Pishch, I. V. (2009). Keramicheskie pigmenty. Moscow: OOO RIF «Stroymaterialy», 224.
  2. Doynov, M., Dimitrov, T., Kozhukharov, S. (2016). Alternative technological approach for synthesis of ceramic pigments by waste materials recycling. Boletín de La Sociedad Española de Cerámica y Vidrio, 55 (2), 63–70. doi: https://doi.org/10.1016/j.bsecv.2016.01.002
  3. Hajjaji, W., Costa, G., Zanelli, C., Ribeiro, M. J., Seabra, M. P., Dondi, M., Labrincha, J. A. (2012). An overview of using solid wastes for pigment industry. Journal of the European Ceramic Society, 32 (4), 753–764. doi: https://doi.org/10.1016/j.jeurceramsoc.2011.10.018
  4. Costa, G., Della, V., Ribeiro, M., Oliveira, A., Monros, G., Labrincha, J. (2008). Synthesis of black ceramic pigments from secondary raw materials. Dyes and Pigments, 77 (1), 137–144. doi: https://doi.org/10.1016/j.dyepig.2007.04.006
  5. Li, Z., Du, Y., Chen, Z., Sun, D., Zhu, C. (2015). Synthesis and characterization of cobalt doped green ceramic pigment from tannery sludge. Ceramics International, 41 (10), 12693–12699. doi: https://doi.org/10.1016/j.ceramint.2015.06.101
  6. Prim, S. R., Folgueras, M. V., de Lima, M. A., Hotza, D. (2011). Synthesis and characterization of hematite pigment obtained from a steel waste industry. Journal of Hazardous Materials, 192 (3), 1307–1313. doi: https://doi.org/10.1016/j.jhazmat.2011.06.034
  7. Chen, Z., Du, Y., Li, Z., Sun, D., Zhu, C. (2015). Synthesis of black pigments containing chromium from leather sludge. Ceramics International, 41 (8), 9455–9460. doi: https://doi.org/10.1016/j.ceramint.2015.04.001
  8. Chavarriaga, E. A., Jaramillo, L. J., Restrepo, O. J. (2012). Ceramic Pigments with Spinel Structure Obtained by Low Temperature Methods. Characterization of Minerals, Metals, and Materials, 155–162. doi: https://doi.org/10.1002/9781118371305.ch19
  9. Minakova, N. A., Zaichuk, A. V., Belyi, Y. I. (с). The structure of borate glass. Glass and Ceramics, 65 (3-4), 70–73. doi: https://doi.org/10.1007/s10717-008-9017-2
  10. Yongvanich, N., Supanichwatin, K., Penglan, J., Triamnak, N. (2018). Synthesis and Characterizations of (CoxMg(2−x))SiO4 Forsterite Ceramic Pigments from Mirror Waste. Materials, 11 (7), 1210. doi: https://doi.org/10.3390/ma11071210
  11. Zaichuk, A. V., Amelina, A. A. (2019). Blue-green spinel-type ceramic pigments prepared from the slag of aluminothermal production of ferrotitanium. Voprosy Khimii i Khimicheskoi Tekhnologii, 4, 46–54. doi: https://doi.org/10.32434/0321-4095-2019-125-4-46-54
  12. Zaichuk, A. V., Amelina, A. A. (2017). Production of Uvarovite Ceramic Pigments Using Granulated Blast-Furnace Slag. Glass and Ceramics, 74 (3-4), 99–103. doi: https://doi.org/10.1007/s10717-017-9937-9
  13. Gargori, C., Cerro, S., Fas, N., Llusar, M., Monrós, G. (2017). Red-brown ceramic pigments based on chromium doped ferrian armalcolite, effect of mineralizers. Ceramics International, 43 (7), 5490–5497. doi: https://doi.org/10.1016/j.ceramint.2017.01.065
  14. Pishch, I. V., Maslennikova, G. N., Podbolotov, K. B., Karizna, Y. A., Belyakovich, I. V. (2011). Silica based pigments. Glass and Ceramics, 68 (3-4), 71–75. doi: https://doi.org/10.1007/s10717-011-9324-x
  15. El Hadri, M., Ahamdane, H., El Idrissi Raghni, M. A. (2017). Effect of sol–gel method on colour properties of the classical cobalt olivine (Co2SiO4) ceramic pigment. Bulletin of Materials Science, 40 (2), 375–382. doi: https://doi.org/10.1007/s12034-017-1378-0
  16. Ke, S., Wang, Y., Pan, Z. (2014). Synthesis of Nd2Si2O7 ceramic pigment with LiCl as a mineralizer and its color property. Dyes and Pigments, 108, 98–105. doi: https://doi.org/10.1016/j.dyepig.2014.04.031
  17. Zaichuk, A. V., Belyi, Y. I. (2012). Brown ceramic pigments based on open-hearth slag. Russian Journal of Applied Chemistry, 85 (10), 1531–1535. doi: https://doi.org/10.1134/s1070427212100072
  18. Zaichuk, A. V., Belyi, Y. I. (2012). Black ceramic pigments based on open-hearth slag. Glass and Ceramics, 69 (3-4), 99–103. doi: https://doi.org/10.1007/s10717-012-9423-3
  19. Lidin, R. A., Molochko, V. A., Andreeva, L. L. (1997). Himicheskie svoystva neorganicheskih veshchestv. Moscow: Himiya, 480.

Downloads

Published

2020-02-29

How to Cite

Zaichuk, O., Amelina А., Khomenko, O., Sribniak, N., Tsyhanenko, L., Savchenko, O., & Telichenko, O. (2020). Patterns in the synthesis processes and the characteristics of silicate-spinal ceramic pigments when introducing mineralizers. Eastern-European Journal of Enterprise Technologies, 1(6 (103), 18–24. https://doi.org/10.15587/1729-4061.2020.196725

Issue

Vol. 1 No. 6 (103) (2020): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

License

Copyright (c) 2020 Oleksandr Zaichuk, Аleksandra Amelina, Olena Khomenko, Nataliia Sribniak, Liudmyla Tsyhanenko, Oleksandr Savchenko, Oleksandr Telichenko

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.