Determination of the applicability of Zn­Al layered double hydroxide, intercalated by food dye Orange Yellow S, as a cosmetic pigment

Authors

  • Vadym Kovalenko Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000, Ukraine https://orcid.org/0000-0002-8012-6732
  • Valerii Kotok Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000, Ukraine https://orcid.org/0000-0001-8879-7189

DOI:

https://doi.org/10.15587/1729-4061.2020.214847

Keywords:

Zn-Al layered double hydroxide, pigment, gel polish, intercalation, Orange Yellow S

Abstract

Nail polish, in particular gel nail polish, is the most used cosmetic product. The components of the gel polish, which determine both toxicity and consumer color properties, are pigments. Zn-Al layered double hydroxides intercalated with anionic food dyes are promising pigments for use in gel polish. The parameters of the samples of Orange Yellow S-intercalated Zn-Al (Zn:Al=4:1 and Zn:Al=2:1) hydroxides synthesized at pH=8 and pH=11 were studied. The crystal structure of the samples was studied by X-ray phase analysis and thermogravimetry, and the pigment properties – by the method of measuring and calculating color characteristics in the CIELab and XYZ systems. The color characteristics of gel nail polish samples prepared using synthesized pigments were studied in a similar way.

X-ray phase analysis and thermogravimetry showed that Zn-Al-Orange Yellow S pigments synthesized at both Zn:Al ratios and pH were layered double hydroxides with the α-Zn(OH)2 structure. The phenomenon of the decomposition of Zn-Al LDH to ZnO during the synthesis was revealed. As a result, all Zn-Al-Orange Yellow S pigment samples contained both layered double hydroxide and zinc oxide. It was shown that all samples of the Zn-Al-Orange Yellow S pigment obtained at pH 8 and 11 and the ratios Zn:Al=4:1 and Zn:Al=2:1 had high pigment characteristics and are promising for use in gel polish. The samples of gel nail polish with synthesized pigments have a red-orange color (сolor tone 595–604 nm) with high monochromaticity (color purity 63–75 %) and color saturation (48.7–58.3)

Author Biographies

Vadym Kovalenko, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000

PhD, Associate Professor

Department of Analytical Chemistry and Chemical Technology of Food Additives and Cosmetics

Senior Researcher

Competence center "Ecological technologies and systems"

Valerii Kotok, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Vyatka State University Moskovskaya str., 36, Kirov, Russian Federation, 610000

PhD, Associate Professor

Department of Processes, Apparatus and General Chemical Technology

Senior Researcher

Competence center "Ecological technologies and systems"

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Published

2020-10-31

How to Cite

Kovalenko, V., & Kotok, V. (2020). Determination of the applicability of Zn­Al layered double hydroxide, intercalated by food dye Orange Yellow S, as a cosmetic pigment. Eastern-European Journal of Enterprise Technologies, 5(12 (107), 81–89. https://doi.org/10.15587/1729-4061.2020.214847

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Vol. 5 No. 12 (107) (2020): Materials Science

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Materials Science

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