Determination of influence of pH on reaction mixture of ferritation process with electromagnetic pulse activation on the processing of galvanic sludge

Authors

DOI:

https://doi.org/10.15587/1729-4061.2021.239102

Keywords:

ferritization, galvanic sludge, heavy metals, ferrite sediment, electromagnetic pulse discharges

Abstract

This paper considers prospects for increasing the level of environmental safety of industrial enterprises as a result of the implementation of resource-saving technology of processing galvanic sludge using the ferritization method. The effectiveness of the use of electromagnetic pulse discharges for resource-saving activation of the ferritization process with the extraction of heavy metal ions from sludge (Fe, Ni, Cu, Zn) has been confirmed. The influence of key parameters of the process such as the pH value of the reaction mixture and the initial concentrations of metals in the solution on the quality of processing galvanic sludge by ferritization has been experimentally investigated. It was determined that with an increase in the pH value from 8.5 to 10.5 the residual concentrations of metal ions decrease to the values of 0.1÷0.25 mg/dm3 regardless of the total initial concentrations. It has been established that the technique of electromagnetic pulse activation ensures an adequate degree of extraction of metal ions of 99.9 %; it also has indisputable energy advantages compared to the thermal method: energy costs are reduced by more than 60 %. That indicates the suitability of purified water for reuse in galvanic production in terms of the requirements for the content of heavy metal ions in it. In addition, the structural studies of ferritization sediment samples have been carried out. The sediment is characterized by the maximum content of crystalline ferromagnetic phases of ferrite. It was established that an increase in the pH of the initial reaction mixture leads to an increase in the ferrite phase in sedimentation: at pH=10.5, phases were detected, which are characterized by a maximum ferrite content (exceeding 76 %). The proposed resource-saving ferritization process prevents environmental pollution, ensures efficient and rational utilization of raw materials and energy in the industry; it also makes it possible to obtain commodity products from industrial waste.

Author Biographies

Gennadii Kochetov, Kyiv National University of Construction and Architecture

Doctor of Technical Sciences, Professor

Department of Chemistry

Dmitry Samchenko, Kyiv National University of Construction and Architecture

PhD, Senior Researcher

Scientific Research Department

Tetiana Arhatenko, Kyiv National University of Construction and Architecture

PhD, Associate Professor

Department of Water Supply and Drainage

References

  1. Zueva, S., Ferella, F., Ippolito, N. M., Ruduka, E., De Michelis, I. (2021). Wastewater Treatment from Galvanization Industry with Zinc recovery. E3S Web of Conferences, 247, 01064. doi: https://doi.org/10.1051/e3sconf/202124701064
  2. Chelnokov, A. A., Yuschenko, L. F., Zhmykov, I. N., Yuraschik, K. K. (2018). Obraschenie s othodami. Minsk: Vysheyshaya shkola, 457. Available at: https://vshph.com/upload/inf/978-985-06-2865-7.pdf
  3. Marcus, M.-I., Vlad, M., Deak, G., Moncea, A., Panait, A.-M., Movileanu, G. (2020). Thermal Stability of Inorganic Pigments Synthesized from Galvanic Sludge. Revista de Chimie, 71 (8), 13–20. doi: https://doi.org/10.37358/rc.20.8.8274
  4. Vitkalova, I. A., Uvarova, A. S., Pikalov, E. S., Selivanov, O. G. (2020). Lanthanum oxide application for modifying the properties of chemically resistant ceramics produced with Galvanic Sludge additive. International Journal of Emerging Trends in Engineering Research, 8 (8), 4544–4547. doi: https://doi.org/10.30534/ijeter/2020/81882020
  5. Tsvetkov, M. P., Milanova, M. M., Cherkezova-Zheleva, Z. P., Tsoncheva, T. S., Zaharieva, J. T., Abrashev, M. V., Mitov, I. G. (2021). Catalytic and photocatalytic properties of zinc-nickel ferrites. Journal of Chemical Sciences, 133 (1). doi: https://doi.org/10.1007/s12039-020-01882-2
  6. Kochetov, G., Kovalchuk, O., Samchenko, D. (2020). Development of technology of utilization of products of ferritization processing of galvanic waste in the composition of alkaline cements. Eastern-European Journal of Enterprise Technologies, 5 (10 (107)), 6–13. doi: https://doi.org/10.15587/1729-4061.2020.215129
  7. Bocanegra, J. J. C., Mora, E. E., González, G. I. C. (2019). Galvanic sludges: Effectiveness of red clay ceramics in the retention of heavy metals and effects on their technical properties. Environmental Technology & Innovation, 16, 100459. doi: https://doi.org/10.1016/j.eti.2019.100459
  8. Kolosova, A., Pikalov, E., Selivanov, O. (2020). Ceramic Bricks Production Basing on Low-Plasticity Clay and Galvanic Sludge Addition. Advances in Intelligent Systems and Computing, 426–431. doi: https://doi.org/10.1007/978-3-030-57453-6_39
  9. Villamarin-Barriga, E., Canacuán, J., Londoño-Larrea, P., Solís, H., De La Rosa, A., Saldarriaga, J. F., Montero, C. (2020). Catalytic Cracking of Heavy Crude Oil over Iron-Based Catalyst Obtained from Galvanic Industry Wastes. Catalysts, 10 (7), 736. doi: https://doi.org/10.3390/catal10070736
  10. Krivenko, P., Kovalchuk, O., Pasko, A. (2018). Utilization of Industrial Waste Water Treatment Residues in Alkali Activated Cement and Concretes. Key Engineering Materials, 761, 35–38. doi: https://doi.org/10.4028/www.scientific.net/kem.761.35
  11. Makovskaya, O. Y., Kostromin, K. S. (2019). Leaching of Non-Ferrous Metals from Galvanic Sludges. Materials Science Forum, 946, 591–595. doi: https://doi.org/10.4028/www.scientific.net/msf.946.591
  12. Vilarinho, C., Teixeira, J., Araújo, J., Carvalho, J. (2017). Effect of Time and Acid Concentration on Metal Extraction From Galvanic Sludges. Volume 14: Emerging Technologies; Materials: Genetics to Structures; Safety Engineering and Risk Analysis. doi: https://doi.org/10.1115/imece2017-71370
  13. Zhang, J., Gao, X., Ma, D., He, S., Du, B., Yang, W. et. al. (2021). Copper ferrite heterojunction coatings empower polyetheretherketone implant with multi-modal bactericidal functions and boosted osteogenicity through synergistic photo/Fenton-therapy. Chemical Engineering Journal, 422, 130094. doi: https://doi.org/10.1016/j.cej.2021.130094
  14. Zhang, Y., He, H., Wang, H., Chen, G., An, X., Wang, Y. (2021). Evolution of microstructure and mechanical properties of 9Cr ferrite/martensite steels with different Si content after long-term aging at 550 °C. Journal of Alloys and Compounds, 873, 159817. doi: https://doi.org/10.1016/j.jallcom.2021.159817
  15. Zhou, X., Wang, J., Zhou, L., Wang, Y., Yao, D. (2021). Structure, magnetic and microwave absorption properties of NiZnMn ferrite ceramics. Journal of Magnetism and Magnetic Materials, 534, 168043. doi: https://doi.org/10.1016/j.jmmm.2021.168043
  16. Ying, Y., Xiong, X., Wang, N., Zheng, J., Yu, J., Li, W. et. al. (2021). Low temperature sintered MnZn ferrites for power applications at the frequency of 1 MHz. Journal of the European Ceramic Society, 41 (12), 5924–5930. doi: https://doi.org/10.1016/j.jeurceramsoc.2021.05.013
  17. Frolova, L. A. (2018). The mechanism of nickel ferrite formation by glow discharge effect. Applied Nanoscience, 9 (5), 845–852. doi: https://doi.org/10.1007/s13204-018-0767-z
  18. Khabarov, Y., Veshnyakov, V., Kuzyakov, N., Pankina, G. (2017). The Interaction of Iron(II) Cations with Chromate Anions in the Presence of Lignosulfonates. 17th International Multidisciplinary Scientific GeoConference SGEM2017, Energy and Clean Technologies. doi: https://doi.org/10.5593/sgem2017h/43/s18.031
  19. Frolova, L. A., Pivovarov, A. A., Anisimova, L. B., Yakubovskaya, Z. N., Yakubovskii, A. I. (2017). The extraction of chromium (III) from concentrated solutions by ferrite method. Voprosy Khimii i Khimicheskoi Tekhnologii, 6, 110–115. Available at: http://oaji.net/articles/2017/1954-1513764539.pdf
  20. John, M., Heuss-Aßbichler, S., Tandon, K., Ullrich, A. (2019). Recovery of Ag and Au from synthetic and industrial wastewater by 2-step ferritization and Lt-delafossite process via precipitation. Journal of Water Process Engineering, 30, 100532. doi: https://doi.org/10.1016/j.jwpe.2017.12.001
  21. Yemchura, B., Kochetov, G., Samchenko, D., Prikhna, T. (2021). Ferritization-Based Treatment of Zinc-Containing Wastewater Flows: Influence of Aeration Rates. Environmental Science and Engineering, 171–176. doi: https://doi.org/10.1007/978-3-030-51210-1_29
  22. Kochetov, G., Prikhna, T., Samchenko, D., Kovalchuk, O. (2019). Development of ferritization processing of galvanic waste involving the energy­saving electromagnetic pulse activation of the process. Eastern-European Journal of Enterprise Technologies, 6 (10 (102)), 6–14. doi: https://doi.org/10.15587/1729-4061.2019.184179
  23. Yemchura, B., Kochetov, G., Samchenko, D. (2018). Ferrit cleaning of waste water from zinc ions: influence of aeration rate. Problems of Water Supply, Sewerage and Hydraulic, 30, 14–22. doi: https://doi.org/10.32347/2524-0021.2018.30.14-22
  24. McIllece, J. J. (2018). On Generalized Variance Functions for Sample Means and Medians. JSM 2018 - Survey Research Methods Section, 584–594. Available at: https://www.bls.gov/osmr/research-papers/2018/pdf/st180080.pdf
  25. Kochetov, G., Prikhna, T., Samchenko, D., Prysiazhna, O., Monastyrov, M., Mosshchil, V., Mamalis, A. (2021). Resource-efficient ferritization treatment for concentrated wastewater from electroplating production with aftertreatment by nanosorbents. Nanotechnology Perceptions, 17, 9‒18. doi: https://doi.org/10.4024/n22ko20a.ntp.17.01

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Published

2021-08-25

How to Cite

Kochetov, G., Samchenko, D., & Arhatenko, T. (2021). Determination of influence of pH on reaction mixture of ferritation process with electromagnetic pulse activation on the processing of galvanic sludge. Eastern-European Journal of Enterprise Technologies, 4(10(112), 24–30. https://doi.org/10.15587/1729-4061.2021.239102

Issue

Vol. 4 No. 10(112) (2021): Ecology

Section

Ecology

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Copyright (c) 2021 Gennadii Kochetov, Dmitry Samchenko, Tetiana Arhatenko

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