Development of rapid-hardening ultra-high strength cementitious composites using superzeolite and N-C-S-H-PCE alkaline nanomodifier

Authors

DOI:

https://doi.org/10.15587/1729-4061.2021.242813

Keywords:

ultra-high strength cementitious composite, superzeolite, alkaline nanomodifier, high temperatures, operational properties

Abstract

It is shown that high operational reliability of structural materials, in particular at high temperatures, is achieved through the use of ultra-high strength cement composites. Studies of various types of Portland cements with mineral additives of the CEM II/A type have established that a stone based on Portland cement with superzeolite is the most resistant to high temperatures. It has been proven that due to the "self-autoclaving" effect, the strength of a stone based on CEM II/A-P 42.5 R is 1.2–1.3 times higher than a stone based on other types of CEM II/A. To obtain fast-hardening cement composites, a nanotechnological approach based on the use of sol-gel technology has been implemented. Using the methods of IR spectroscopy, electron microscopy, the fact of obtaining, by the chemical method of synthesis, an alkaline nanomodifier N-C-S-H-PCE,
which is a nano–liquid based on nano-core seeds of sodium/calcium hydrosilicates, has been proved. It has been confirmed that the introduction of the alkaline nanomodifier
N-C-S-H-PCE provides a significant intensification of the early structure formation processes in the paste based on Portland cement with superzeolite (after 12 hours, 24 hours and 28 days, the strength is 16.9; 30.5 and 104.1 MPa). It has been established that the complex combination of Portland cement with superzeolite, corundum aggregate, basalt fiber and alkaline nanomodifier provides rapid-hardening of ultra-high strength cement composites (T=400 °C) with improved operational properties. Thus, there is reason to assert the feasibility of developing rapid-hardening ultra-high strength cementitious composites. This solves the problems associated with the need to increase their early strength and performance. As a result, it is possible to carry out repair work to protect equipment from abrasive wear at elevated temperatures

Author Biographies

Myroslav Sanytsky, Lviv Polytechnic National University

Doctor of Technical Sciences, Professor, Head of Department

Department of Building Production

Tetiana Kropyvnytska, Lviv Polytechnic National University

Doctor of Technical Sciences, Professor

Department of Building Production

Iryna Нeviuk, PJSC Ivano-Frankivskcement

PhD, Нead of Testing Laboratory

Pawel Sikora, West Pomeranian University of Technology in Szczecin

Doctor of Technical Sciences, Professor

Faculty of Civil and Environmental Engineering

Serhii Braichenko, Lviv Polytechnic National University

PhD, Senior Lecturer

Department of Building Production

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Published

2021-10-29

How to Cite

Sanytsky, M., Kropyvnytska, T., Нeviuk I., Sikora, P., & Braichenko, S. (2021). Development of rapid-hardening ultra-high strength cementitious composites using superzeolite and N-C-S-H-PCE alkaline nanomodifier. Eastern-European Journal of Enterprise Technologies, 5(6 (113), 62–72. https://doi.org/10.15587/1729-4061.2021.242813

Issue

Vol. 5 No. 6 (113) (2021): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2021 Myroslav Sanytsky, Tetiana Kropyvnytska, Iryna Нeviuk, Pawel Sikora, Serhii Braichenko

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