Study of effectiveness of heavy metals ions as the inhibitors of steel corrosion

Authors

DOI:

https://doi.org/10.15587/1729-4061.2017.106974

Keywords:

corrosion, inhibitors, heavy metals, stabilizers of scale formation, closed water-circulation systems

Abstract

The effect of ions of d-metals on the processes of corrosion in a movable and immovable neutral aqueous environment has been investigated. It was shown that a number of ions, such as zinc, chromium, lead, under conditions of high aeration and temperature of 20 ºС at concentrations of 2−5 mg/dm3, are effective inhibitors of steel corrosion. This is due to the formation of a passivation oxygen film on the surface of metal. The degree of corrosion protection is maintained at the level of 80−90 %. In the case of elevating the temperature to 50 ºС, a significant (up to 40 %) decrease in the inhibitory properties of ions of d-metals is observed. This is due both to the destabilization of the oxygen passivation film and the growth of oxidation rate of steel with increasing temperature.

It was demonstrated that phosphonic acids, such as oxyethyldidiphosphone acid, nitrilotrimethylphosphonium acid, due to the interaction of complexons with the surface of metals, stabilize the passivation oxygen film, providing a degree of protection against corrosion at 95−98 % at acid dose of 10 mg/dm3. However, when the temperature rises to 50 °C, a protective effect is reduced.

It was established that the use of compositions based on OEDPhA/NTMPhA and Zn/Pb/Cr ions in the range of temperatures 20−50 oC provides a degree of protection of steel from corrosion at the level of 90 %. This is explained by the formation of three-dimensional complexes of phosphonic acids with metal ions and corroded iron

Author Biographies

Tatiana Shabliy, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute" Peremohy ave., 37, Kyiv, Ukraine, 03056

Doctor of Technical Science, Professor

Department of Ecology and technology оf Plant Polymers

Julia Nosachova, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute" Peremohy ave., 37, Kyiv, Ukraine, 03056

PhD, Associate Professor

Department of Ecology and technology of Plant Polymers

Yaroslav Radovenchik, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute" Peremohy ave., 37, Kyiv, Ukraine, 03056

PhD, Associate Professor

Department of Ecology and technology of Plant Polymers

Valeriya Vember, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute" Peremohy ave., 37, Kyiv, Ukraine, 03056

PhD, Associate Professor

Department of Ecology and technology of Plant Polymers

References

  1. Trus, I. N., Gomelya, N. D., Shabliy, T. A. (2014). Razdelenie hloridov i sul'fatov pri ionoobmennom obessolivanii vody. Metallurgicheskaya i gornorudnaya promyshlennost', 5, 119–122.
  2. Chichenin, V. V., Kishnevskiy, V. A., Gricaenko, A. S., Ahrameev, V. G., Shulyak, I. D. (2015). Study of corrosion rate and accumulation of deposits under circulating water concentration in bench experiments. Eastern-European Journal of Enterprise Technologies, 5 (8 (77)), 14–20. doi: 10.15587/1729-4061.2015.51205
  3. Pilipenko, A., Pancheva, H., Reznichenko, A., Myrgorod, O., Miroshnichenko, N., Sincheskul, A. (2017). The study of inhibiting structural material corrosion in water recycling systems by sodium hydroxide. Eastern-European Journal of Enterprise Technologies, 2 (1 (86)), 21–28. doi: 10.15587/1729-4061.2017.95989
  4. Cervova, J., Hagarova, M., Lackova, P. (2014). Corrosive protection of metal materials in cooling water. American Journal of Materials Science and Application, 29 (1), 6–10.
  5. Tamazashvili, A. T., Mazna, Yu. I., Sirenko, L. V. (2012). Comparison of the efficiency of phosphate inhibitors of steel corrosion in tap water. Eastern-European Journal of Enterprise Technologies, 2 (13 (56)), 28–31. Available at: http://journals.uran.ua/eejet/article/view/3943/3611
  6. Gomelya, N. D., Shabliy, T. A., Trohimenko, A. G., Shuriberko, M. M. (2017). Novye ingibitory korrozii i otlozheniya osadkov dlya sistem vodocirkulyacii. Himiya i tekhnologiya vody, 39 (2), 169–177.
  7. Stepin, S. N., Kuznecova, O. P., Vahin, A. V., Habibrahmanov, B. I. (2012). Primenenie fosforsoderzhashchih kompleksonov i kompleksonatov v kachestve ingibitrov korrrozii metallov. Vestnik Kazanskogo tekhnologicheckogo universiteta, 15 (13), 88–98.
  8. Liu, S. H., Wang, Y. N., Yuan, B. X., Dong, W. T. et. al. (2016). Corrosion inhibition of a composite inhibitor containing imidazoline on carbon steel in simulated reverse osmosis product water of seawater. International Journal of Corrosion and Scale Inhibition, 5 (4), 325–332. doi: 10.17675/2305-6894-2016-5-4-3
  9. Muthumani, N., Rajendran, S., Pandiarajan, M., Christy, J. L., Nagalakshmi, R. (2012). Corrosion Inhibition by Amino Trimethylene Phosphonic Acid (ATMP) – Zn2+ System for Carbon Steel in Ground Water. Portugaliae Electrochimica Acta, 30 (5), 307–315. doi: 10.4152/pea.201205307
  10. Barthelemy, B., Kanoufi, F., Combellas, C., Delhalle, J., Mekhalif, Z. (2014). Phynox Improved Corrosion Resistance with MPC Initiated from Mixed Monolayers of Phosphonic Acids. Journal of the Electrochemical Society, 161 (12), C544–C549. doi: 10.1149/2.0531412jes
  11. Mobin, M., Malik, A. U., Andijani, I. N. (2007). The effect of heavy metal ions on the localized corrosion behavior of steels. Desalination, 217 (1-3), 233–241. doi: 10.1016/j.desal.2007.03.005
  12. Prabakaran, M., Venkatesh, M., Ramesh, S., Periasamy, V. (2013). Corrosion inhibition behavior of propyl phosphonic acid–Zn2+ system for carbon steel in aqueous solution. Applied Surface Science, 276, 592–603. doi: 10.1016/j.apsusc.2013.03.138
  13. Manivannan, M., Rajendra, S. (2012) Ethylenediaminetetraacetic acsd–Zn2+ system as corrosion inhibition for carbon steel in seawater. Asian journal of chemistry, 10, 4713–4716.
  14. Prabakaran, M., Ramesh, S., Periasamy, V., Sreedhar, B. (2014). The corrosion inhibition performance of pectin with propyl phosphonic acid and Zn2+ for corrosion control of carbon steel in aqueous solution. Research on Chemical Intermediates, 41 (7), 4649–4671. doi: 10.1007/s11164-014-1558-0
  15. Prabakaran, M., Durainatarajan, P., Ramesh, S., Periasamy, V. (2016). Enhanced corrosion inhibition behavior of carbon steel in aqueous solution by Phosphoserine-Zn2+system. Journal of Adhesion Science and Technology, 30 (14), 1487–1509. doi: 10.1080/01694243.2016.1150661
  16. DSanPiN 2.2.4-171-10 Hihienichni vymohy do vody pytnoi, pryznachenoi dlia spozhyvannia liudynoiu (2010). Ministerstvo okhorony zdorovia, No. 452/17747.
  17. Saida, T., Sato, K., Kuroda, K., Okido, M. (2013). Effects of Temperature and Anion-species on the Susceptibility to Chloride Stress Corrosion Cracking of Stainless Steels in Hot Water. Zairyo-to-Kankyo, 62 (6), 224–230. doi: 10.3323/jcorr.62.224
  18. Gomelya, N. D., Omel'chuk, Yu. A., Nezviskaya, T. A. (2007). Vliyanie osnovnyh reagentov na korroziyu stali v vode pri povyshennyh temperaturah. Ehkotekhnologii i resursosberezhenie, 6, 57–60.
  19. Thangakani, J. A., Rajendran, S., Sathiabama, J., Rathish, R. J., Santhanaprabha, S. (2017). Corrosion Inhibition of Carbon Steel in Well Water by L-Cysteine-Zn2+ System. Portugaliae Electrochimica Acta, 35 (6), 13–25. doi: 10.4152/pea.201701013
  20. Chausov, F. F., Naimushina, E. A., Shabanova, I. N., Somov, N. V. (2015). Synthesis and structure of tetrasodium nitrilotrismethylenephosphonato zincate tridecahydrate Na4[ZnN(CH2PO3)3]·13H2O, a corrosion inhibitor. Journal of Structural Chemistry, 56 (3), 582–588. doi: 10.1134/s0022476615030270
  21. Chausov, F. F., Somov, N. V., Zakirova, R. M., Alalykin, A. A., Reshetnikov, S. M., Petrov, V. G. et. al. (2017). Linear organic–inorganic heterometallic copolymers [(Fe, Zn)(H2O)3{NH(CH2PO3H)3}] n and [(Fe, Cd)(H2O)3{NH(CH2PO3H)3}] n : The missing link in the mechanism of inhibiting local steel corrosion with phosphonates. Bulletin of the Russian Academy of Sciences: Physics, 81 (3), 365–367 doi: 10.3103/s106287381703008x

Downloads

Published

2017-08-29

How to Cite

Shabliy, T., Nosachova, J., Radovenchik, Y., & Vember, V. (2017). Study of effectiveness of heavy metals ions as the inhibitors of steel corrosion. Eastern-European Journal of Enterprise Technologies, 4(12 (88), 10–17. https://doi.org/10.15587/1729-4061.2017.106974

Issue

Vol. 4 No. 12 (88) (2017): Materials Science

Section

Materials Science

License

Copyright (c) 2017 Tatiana Shabliy, Julia Nosachova, Yaroslav Radovenchik, Valeriya Vember

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.