The properties investigation of the faradaic supercapacitor electrode formed on foamed nickel substrate with polyvinyl alcohol using

Authors

  • Valerii Kotok Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Federal State Educational Institution of Higher Education "Vyatka State University" Moskovskaya str., 36, Kirov, Russian Federation, 610000, Ukraine https://orcid.org/0000-0001-8879-7189
  • Vadym Kovalenko Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Federal State Educational Institution of Higher Education "Vyatka State University" Moskovskaya str., 36, Kirov, Russian Federation, 610000, Ukraine https://orcid.org/0000-0002-8012-6732

DOI:

https://doi.org/10.15587/1729-4061.2017.108839

Keywords:

nickel hydroxide, Ni(OH)2, supercapacitor, electrodeposition, cathodic template synthesis, polyvinyl alcohol, discharge capacity

Abstract

The electrode materials for positive electrodes of hybrid supercapacitors were deposited on the nickel foam substrate using cathodic template method. It has been demonstrated that prepared materials are composed of polyvinyl alcohol and X-ray amorphous α-like nickel hydroxide with a large number of lattice defects, that have a flat morphology with a grid of cracks. The optimal deposition times were found to be 10 and 20 minutes. It has also been demonstrated that the greatest effect on the capacity of nickel foam substrates was caused by the treatment itself and to not by its duration or polarization with the cathodic current. It has been demonstrated that with such deposition method, the resulting capacity is constituted by two components – the capacity of PVA-Ni(OH)2 composite material and capacity of the nickel foam substrate. The maximum specific capacity obtained at a current density of 320 mA/cm2 is 2.26 F/cm2. The maximum substrate capacity was achieved after treatment with KNO3 solution for 10 minutes and is 1.58 F/cm2 at a current density of 160 mA/cm2

Author Biographies

Valerii Kotok, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Federal State Educational Institution of Higher Education "Vyatka State University" Moskovskaya str., 36, Kirov, Russian Federation, 610000

PhD, Associate Professor

Department of Processes, Apparatus and General Chemical Technology

Department of Technologies of Inorganic Substances and Electrochemical Manufacturing

Vadym Kovalenko, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Federal State Educational Institution of Higher Education "Vyatka State University" Moskovskaya str., 36, Kirov, Russian Federation, 610000

PhD, Associate Professor

Department of Analytical Chemistry and Food Additives and Cosmetics

Department of Technologies of Inorganic Substances and Electrochemical Manufacturing

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Published

2017-08-29

How to Cite

Kotok, V., & Kovalenko, V. (2017). The properties investigation of the faradaic supercapacitor electrode formed on foamed nickel substrate with polyvinyl alcohol using. Eastern-European Journal of Enterprise Technologies, 4(12 (88), 31–37. https://doi.org/10.15587/1729-4061.2017.108839

Issue

Vol. 4 No. 12 (88) (2017): Materials Science

Section

Materials Science

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Copyright (c) 2017 Valerii Kotok, Vadym Kovalenko

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