Modeling of gas-phase compression for carbon-carbon composites
DOI:
https://doi.org/10.15587/1729-4061.2013.12396Keywords:
Carbon-carbon composites, gas phase, pyrocarbon, compression methods, mathematical modelsAbstract
Compression of carbon-carbon composites is carried out in thermo-chemical reactor of flowing type by filling the porous structure with pyrocarbon deposited from the gas phase during the pyrolysis of hydrocarbons. Homogeneous processes create the complex of saturated and unsaturated hydrocarbons and a number of radicals. The products of homogeneous processes and source hydrocarbon diffuse into the porous structure and form a solid residue – pyrocarbon, decomposing on the heated sides of pores.
Practical implementation of the compression of the composites can be fulfilled by isothermal and nonisothermal methods under static and pulsating pressure, as well as with and without the forced convection.
It follows from the analysis of mathematical models of different methods of gas-phase compression of carbon-carbon composites that use of processes with pulsating pressure does not lead to decrease in the duration of compression and increase of deposition of pyrocarbon in the porous structure. Forced feed of the reaction gas into the porous structure during the isothermal process increases the amount of pyrocarbon deposited in the volume of the composite. However, the efficiency of the process is limited by the moment of overgrowing of pore throats. During the thermogradient process, the forced feed of the reaction gas increases the rate of deposition of pyrocarbon along a pore and reduces the duration of the compressionReferences
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Copyright (c) 2014 Віктор Олексійович Скачков, Віктор Ілліч Іванов, Сергій Анатолійович Воденніков, Юрій Вікторович Мосейко
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