Investigation of the electrochromic properties of Ni(OH)2 films on glass with ITONi bilayer coating
DOI:
https://doi.org/10.15587/1729-4061.2018.133387Keywords:
electrochromism, electrodeposition, thin films, Ni(OH)2, nickel, indium-tin oxide, nickel hydroxideAbstract
Electrochromic films have been deposited onto glass coated with indium-tin oxide (ITO) and glass with ITO and a thin layer of metallic nickel deposited onto it. Nickel was deposited onto the surface of the ITO coating from nickel electroplating solution. The metallic nickel was deposited onto the surface of ITO at the following parameters – cathodic current density 0.5 A/dn2, deposition time 3 s. Such deposition parameters were chosen, because at longer deposition time and (or) higher current density, the deposited layer of metallic nickel became opaque. The two substrates were then used in the deposition of Ni(OH)2 electrochromic films using the cathodic template synthesis method. As a result, it was revealed that the electrochromic film deposited onto glass with ITO-Ni coating possesses higher specific characteristics than that deposited on bare ITO-coated glass: higher coloration degree and higher oxidation-reduction currents on the cyclic voltamperogram. However, it was also revealed that the film possessing better characteristics, on the contrary, has lower reversibility of the coloration-bleaching process. Based on the obtained data, the mechanism that explains the role of the intermediate metal layer was proposed. The mechanism is that the deposited layer of metallic nickel forms additional contacts between the substrate surface and the electrochromic film. The nickel layer can also assist in securing the electrochromic film, and during film deposition has a positive effect on current distribution. On the other hand, the lower reversibility of the coloration-bleaching process of the film on ITO-Ni coating can be explained by gradual oxidation of metallic nickel in the basic medium. At the same time, it was revealed that deposition of metallic nickel leads to some decrease of the substrate transparency.
References
- Rathore, M. M., Ahmad, A., Paul, A., Rho, S. (2016). Urban planning and building smart cities based on the Internet of Things using Big Data analytics. Computer Networks, 101, 63–80. doi: 10.1016/j.comnet.2015.12.023
- Khajenasiri, I., Estebsari, A., Verhelst, M., Gielen, G. (2017). A Review on Internet of Things Solutions for Intelligent Energy Control in Buildings for Smart City Applications. Energy Procedia, 111, 770–779. doi: 10.1016/j.egypro.2017.03.239
- Smart Windows: Energy Efficiency with a View. NREL. Available at: https://www.nrel.gov/news/features/2010/1555.html
- Kotok, V. A., Kovalenko, V. L., Kovalenko, P. V., Solovov, V. A., Deabate, S., Mehdi, A. et. al. (2017). Advanced electrochromic Ni(OH)2/PVA films formed by electrochemical template synthesis. ARPN Journal of Engineering and Applied Sciences, 12 (13), 3962–3977.
- Kotok, V., Kovalenko, V. (2017). The electrochemical cathodic template synthesis of nickel hydroxide thin films for electrochromic devices: role of temperature. Eastern-European Journal of Enterprise Technologies, 2 (11 (86)), 28–34. doi: 10.15587/1729-4061.2017.97371
- Kotok, V. A., Malyshev, V. V., Solovov, V. A., Kovalenko, V. L. (2017). Soft Electrochemical Etching of FTO-Coated Glass for Use in Ni(OH) 2 -Based Electrochromic Devices. ECS Journal of Solid State Science and Technology, 6 (12), P772–P777. doi: 10.1149/2.0071712jss
- Dixit, M. (1999). Zinc-Substituted α-Nickel Hydroxide as an Electrode Material for Alkaline Secondary Cells. Journal of The Electrochemical Society, 146 (1), 79. doi: 10.1149/1.1391567
- Kotok, V., Kovalenko, V., Malyshev, V. (2017). Comparison of oxygen evolution parameters on different types of nickel hydroxide. Eastern-European Journal of Enterprise Technologies, 5 (12 (89)), 12–19. doi: 10.15587/1729-4061.2017.109770
- Kovalenko, V. L., Kotok, V. A., Sykchin, A. A., Mudryi, I. A., Ananchenko, B. A., Burkov, A. A. et. al. (2016). Nickel hydroxide obtained by high-temperature two-step synthesis as an effective material for supercapacitor applications. Journal of Solid State Electrochemistry, 21 (3), 683–691. doi: 10.1007/s10008-016-3405-2
- Kovalenko, V., Kotok, V., Bolotin, O. (2016). Definition of factors influencing on Ni(OH)2 electrochemical characteristics for supercapacitors. Eastern-European Journal of Enterprise Technologies, 5 (6 (83)), 17–22. doi: 10.15587/1729-4061.2016.79406
- Amjad, M. (1977). The Oxidation of Alcohols at a Nickel Anode in Alkaline t-Butanol/Water Mixtures. Journal of The Electrochemical Society, 124 (2), 203. doi: 10.1149/1.2133266
- Lyalin, B. V., Petrosyan, V. A. (2010). Oxidation of organic compounds on NiOOH electrode. Russian Journal of Electrochemistry, 46 (11), 1199–1214. doi: 10.1134/s1023193510110017
- Rao, Y., Wang, Y., Ning, H., Li, P., Wu, M. (2016). Hydrotalcite-like Ni(OH)2 Nanosheets in Situ Grown on Nickel Foam for Overall Water Splitting. ACS Applied Materials & Interfaces, 8 (49), 33601–33607. doi: 10.1021/acsami.6b11023
- Yan, J., Wu, H., Chen, H., Pang, L., Zhang, Y., Jiang, R. et. al. (2016). One-pot hydrothermal fabrication of layered β-Ni(OH) 2 /g-C 3 N 4 nanohybrids for enhanced photocatalytic water splitting. Applied Catalysis B: Environmental, 194, 74–83. doi: 10.1016/j.apcatb.2016.04.048
- Kotok, V., Kovalenko, V. (2017). Electrochromism of Ni(OH)2 films obtained by cathode template method with addition of Al, Zn, Co ions. Eastern-European Journal of Enterprise Technologies, 3 (12 (87)), 38–43. doi: 10.15587/1729-4061.2017.103010
- Vidotti, M., van Greco, C., Ponzio, E. A., Córdoba de Torresi, S. I. (2006). Sonochemically synthesized Ni(OH)2 and Co(OH)2 nanoparticles and their application in electrochromic electrodes. Electrochemistry Communications, 8 (4), 554–560. doi: 10.1016/j.elecom.2006.01.024
- Jiang, S., Yuan, G., Hua, C., Khan, S., Wu, Z., Liu, Y. et. al. (2017). Electrochromic Properties of Ni/NiO/rGO Nanocomposite Films Prepared by a Facile Sol-Gel Technique. Journal of The Electrochemical Society, 164 (13), H896–H902. doi: 10.1149/2.1231713jes
- Zhu, L., Nuo Peh, C. K., Zhu, T., Lim, Y.-F., Ho, G. W. (2017). Bifunctional 2D-on-2D MoO3 nanobelt/Ni(OH)2 nanosheets for supercapacitor-driven electrochromic energy storage. Journal of Materials Chemistry A, 5 (18), 8343–8351. doi: 10.1039/c7ta01858d
- Dong, W., Lv, Y., Zhang, N., Xiao, L., Fan, Y., Liu, X. (2017). Trifunctional NiO–Ag–NiO electrodes for ITO-free electrochromic supercapacitors. Journal of Materials Chemistry C, 5 (33), 8408–8414. doi: 10.1039/c7tc03120c
- Lin, S.-H., Chen, F.-R., Kai, J.-J. (2008). Electrochromic properties of nano-composite nickel oxide film. Applied Surface Science, 254 (11), 3357–3363. doi: 10.1016/j.apsusc.2007.11.022
- Fortunato, E., Ginley, D., Hosono, H., Paine, D. C. (2007). Transparent Conducting Oxides for Photovoltaics. MRS Bulletin, 32 (03), 242–247. doi: 10.1557/mrs2007.29
- Mirletz, H. M., Peterson, K. A., Martin, I. T., French, R. H. (2015). Degradation of transparent conductive oxides: Interfacial engineering and mechanistic insights. Solar Energy Materials and Solar Cells, 143, 529–538. doi: 10.1016/j.solmat.2015.07.030
- Kurdesau, F., Khripunov, G., da Cunha, A. F., Kaelin, M., Tiwari, A. N. (2006). Comparative study of ITO layers deposited by DC and RF magnetron sputtering at room temperature. Journal of Non-Crystalline Solids, 352 (9-20), 1466–1470. doi: 10.1016/j.jnoncrysol.2005.11.088
- Thirumoorthi, M., Thomas Joseph Prakash, J. (2016). Structure, optical and electrical properties of indium tin oxide ultra thin films prepared by jet nebulizer spray pyrolysis technique. Journal of Asian Ceramic Societies, 4 (1), 124–132. doi: 10.1016/j.jascer.2016.01.001
- Jeyadheepa, K., Karthick, P., Vijayanara, D., Suja, S., Sridharan, M. (2015). Opto-Electronic Properties of Fluorine Doped Tin Oxide Films Deposited by Nebulized Spray Pyrolysis Method. Asian Journal of Applied Sciences, 8 (4), 259–268. doi: 10.3923/ajaps.2015.259.268
- Du, J., Chen, X., Liu, C., Ni, J., Hou, G., Zhao, Y., Zhang, X. (2014). Highly transparent and conductive indium tin oxide thin films for solar cells grown by reactive thermal evaporation at low temperature. Applied Physics A, 117 (2), 815–822. doi: 10.1007/s00339-014-8436-x
- Bicelli, L. P., Bozzini, B., Mele, C., D'Urzo, L. (2008). A Review of Nanostructural Aspects of Metal Electrodeposition. Int. J. Electrochem. Sci., 3, 356–408.
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