Evaluation of influence of multyfunctional additives on operational and technical parameters of petrol
DOI:
https://doi.org/10.15587/1729-4061.2013.14782Keywords:
petrol, additives, antioxidants, surfactants, antiknock value, cool-flaming oxidation octanometer, thermal effect, induction time, characteristicsAbstract
The article grounds the usefulness of multifunctional additives for petrol in order to improve the environmental characteristics of the performance of internal combustion engines. On the basis of surfactants and antioxidants a number of additives was developed. Choosing antioxidants was based on determination of their thermal stability. The influence of additives on the octane number of petrol and the process of cool-flaming oxidation of hydrocarbon fuel was studied. For the research a high-precision octanometer was used, where the octane number of petrol is determined solely by the nature and magnitude of the thermal effects associated with the occurrence of only cool-flaming oxidation reactions. Test results show that additives influence the nature of the oxidation processes. The greatest positive effect of the antioxidant 4,4 '-dioctyldiphenylamine was revealed. According to the results it was concluded that it is reasonable to use the high-temperature antioxidant 4,4 '-dioctyldiphenylamine to modify petrol.
References
- Гуреев, А. А. Автомобильные бензины. Свойства и применение [Текст] / А. А. Гуреев, В. С. Азев – М.: Нефть и газ, 1996. – 444 с.
- Громадська організація «Екологічно чисте майбутнє». [Електронний ресурс]: [сайт].– Режим доступу: http://www.ekomaybutne.com/ua/.– Заголовок з екрану. – Мова укр.
- Охорона навколишнього середовища та раціональне використання природних ресурсів – 2011 [Текст] / Матеріали ХХI Всеукраїнська наукова конференція аспірантів і студентів. – Донецьк, ДонНТУ – 2011.
- Викиди окремих забруднюючих речовин та діоксиду вуглецю в атмосферне повітря [Електронний ресурс] / Державний комітет статистики України. – Режим доступу : http://www.ukrstat.gov.ua/ – Заголовок з екрану. – Мова укр.
- Паливо-мастильні матеріали, технічні рідини та системи їх забезпечення [Текст] / [упоряд. В. Я. Чабанний та ін.]. – Кіровоград: Центрально-Українське видавництво, 2008. – 353 с.
- Ярмолюк, Б. М. Тенденції застосування додатків до бензинів [Текст] / Б. М. Ярмолюк, Н. П. Короткова, Л. І. Береза // Катализ и нефтехимия. – 2006. – № 14. – С. 53-70.
- Данилов, А. М. Применение присадок в топливах для автомобилей [Текст] : Справ. изд. / А. М. Данилов – М. : Химия, 2000. – 232 с.
- Никитина, Е. А. Моющие присадки для автомобильных бензинов – шаг за шагом. История развития [Текст] / Е. А. Никитина, Д. С. Павлов // Научно-технический журнал «Мир нефтепродуктов. Вестник нефтяных компаний». – 2010. – № 1. – С. 3–9.
- Спосіб оперативного визначення октанового числа бензинів [Текст] : патент на корисну модель № 61644 Україна: МПК G 01 N 25/20 (2006/01) / Степанов М. Б., Василькевич О. І., Ледовських В. М., Ющенко О. В., Бондаренко С. Г., Попова Л. М., Лесик Т. В.; патентовласник: НТУУ «КПІ» – № u 2010 15901; заявл. 29.10.2010; опубл. 25.07.2011, Бюл. №14. – 6 с.
- Степанский, Я. Ю. Корреляция между октановым числом и некоторыми параметрами окисления бензинов [Текст] / Я. Ю. Степанский, Н. П. Евмененко, Г. С. Яблонский [и др.] // Химия и технология топлив и масел. − 1980. − № 8. − С. 54−56.
- Киселев, В. П. Альтернативные методы определения детонационной стойкости бензинов и их компонентов [Текст] / В. П. Киселев, Ю. В. Киселев // Катализ и нефтехимия. – 2001. – №9-10. – С. 77–79.
- Gureev, A., Azev, V. (1996). Automobile gasoline. Properties and application. Moscow: Oil and Gas.
- "Ecological Future" (2012). Retrieved from: http://www.ekomaybutne.com/ua.
- Environmental protection and rational use of natural resources-2011. Col. Works of Materials of the ХХI National Scientific Stud. and post-graduate Stud. Conf. (2011). Donetsk: DonNTU.
- Emissions of certain pollutants and carbon dioxide into the atmosphere (2011). Retrieved from State Statistics Service of Ukraine: http://www.ukrstat.gov.ua.
- Chabannyi, V. (2008). Fuel and Lubricant Materials, Technical Fluids and Supporting Systems. Kirovograd: Central Ukrainian Publishing.
- Yarmolyuk, B., Korotkov, N., Bereza, L. (2006). Trends in the usage of gasoline additives. Catalysis and Petrochemistry. 14, 53-70.
- Danilov, A. (2000). The Usage of Additives in Automobile Hydrocarbon Fuels. Moscow: Chemistry.
- Nikitina, E., Pavlov, D. (2010). Detergents for Gasoline – Step-by-Step. The History of Development. Scientific and Technical Journal "World of Oil Products. The Oil Companies’ bulletin". 1, 3-9.
- Stepanov, N., Vasylkevych, O. Ledovskih, V., Yushchenko, O., Bondarenko, S., Popova, L., Lesyk, T. (2011) Method of operational definition of gasoline Octane Number. Ukraine: IPC G 01 N 25/20 (2006/01) (Patent).
- Stepanskyi, Y., Evmenenko, N., Jablonskyi, G. (1980). The Correlation between the Octane Number and some Parameters of gasoline oxidation. Chemistry and Technology of Fuels and Oils. 8, 54-56.
- Kiselev, V., Kiselev, J. (2001). Alternative definitions antiknock gasoline and components. Catalysis and petrochemistry. 9-10, 77-79.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2014 Ірина Володимирівна Роїк, Олександр Іванович Василькевич, Сергій Григорович Бондаренко, Микола Борисович Степанов
This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.
A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.