Design and study of nanomodified composite fluoropolymer materials for tribotechnical purposes

Authors

DOI:

https://doi.org/10.15587/1729-4061.2020.214533

Keywords:

anti-friction materials, composite, durability, fluoropolymer coatings, nanopowder, zirconium oxide, carboplastics

Abstract

This paper reports the analytical and experimental studies aimed at designing and modeling fluoropolymer anti-friction materials. The optimal ratios of the total surface of polymer particles to the total surface of filler particles for different brands of fluoropolymer-4 have been determined, as well as the critical concentrations of the modifiers of fluoropolymer anti-friction materials. The calculations of antifriction carboplastics' elasticity modules indicate the existence of adhesion between carbon fiber and polytetrafluoroethylene. When constructing composites that combine high durable and tribotechnical characteristics, it is advisable to combine modifiers with different dispersion and polymer-oligomeric matrices, which enables the implementation of the principle of multilevel modifying. It has been established that the adhesion between carbon fiber and polytetrafluoroethylene can be improved by applying a fluoropolymer coating onto the surface of carbon fibers or by modifying with zirconium oxide nanopowders. The binary fluoropolymer matrix applied to the surface of carbon fiber can be used as an effective base for composite materials. This study has demonstrated that filling polytetrafluoroethylene (PTFE) with coke, carbon fibers (18‒19.5 % by weight), and zirconium oxide nanopowders in the amount of up to 2 % by weight produces materials with high mechanical characteristics and durability. It has been shown that the existence of an oligomer component improves the thermodynamic compatibility at the interface and promotes the plasticization of the PTFE boundary layers. Molecular structure with a certain orientation of coke and carbon fiber in the interphase areas is inherent in the materials with improved physical and mechanical properties

Author Biographies

Aleksandr Dykha, Khmelnytskyi National University Instytuts’ka str., 11, Khmelnytskyi, Ukraine, 29016

Doctor of Technical Sciences, Professor, Head of Department

Department of Tribology, Automobiles and Materials Science

Vladyslav Svidersky, Khmelnytskyi National University Instytuts’ka str., 11, Khmelnytskyi, Ukraine, 29016

PhD, Associate Professor

Department of Tribology, Automobiles and Materials Science

Igor Danilenko, Donetsk Institute for Physics and Engineering named after O.O. Galkin of the National Academy of Sciences of Ukraine Nauki ave., 46, Kyiv, Ukraine, 03680

PhD, Senior Researcher

Department of Physical Materials Science

Viktor Bilichenko, Vinnytsia National Technical University Khmelnytsky highway, 95, Vinnytsya, Ukraine, 21021

Doctor of Technical Sciences, Professor, Head of Department

Department of Automobiles and Transport Management

Yuri Kukurudzyak, Vinnytsia National Technical University Khmelnytsky highway, 95, Vinnytsya, Ukraine, 21021

PhD, Associate Professor

Department of Automobiles and Transport Management

Ludmila Kirichenko, Khmelnytskyi National University Instytuts’ka str., 11, Khmelnytskyi, Ukraine, 29016

Researcher

Research Part

References

  1. Petrova, P. N., Okhlopkova, A. A., Fedorov, A. L. (2012). Development of polymer tribocomposites on the basis of polytetrafluoroethylene with an elevated wear resistance. Inorganic Materials: Applied Research, 3 (4), 329–333. doi: https://doi.org/10.1134/s2075113312040144
  2. Dykha, A. V., Kuzmenko, A. G. (2016). Distribution of friction tangential stresses in the Courtney-Pratt experiment under Bowden’s theory. Journal of Friction and Wear, 37 (4), 315–319. doi: https://doi.org/10.3103/s1068366616040061
  3. Berladir, K. V., Hovorun, T. P., Bilous, O. A., Baranova, S. V. (2018). The modeling of the composition and properties of functional materials based on polytetrafluoroethylene. Functional Materials, 25 (2), 342–347. doi: https://doi.org/10.15407/fm25.02.342
  4. Marchuk, V. Y., Kindrachuk, M. V., Mirnenko, V. I., Mnatsakanov, R. G., Kornіenko, A. O. (2019). Physical Interpretations of Internal Magnetic Field Influence on Processes in Tribocontact of Textured Dimple Surfaces. Journal of Nano- and Electronic Physics, 11 (5), 05013-1–05013-5. doi: https://doi.org/10.21272/jnep.11(5).05013
  5. Marchuk, V., Kindrachuk, M., Kryzhanovskyi, A. (2014). System analysis of the properties of discrete and oriented structure surfaces. Aviation, 18 (4), 161–165. doi: https://doi.org/10.3846/16487788.2014.985474
  6. Baziuk, L. V., Sirenko, H. A. (2013). Thermophysical Properties of Metals and Polymer Compositions. Physics and Chemistry of Solid State, 14 (1), 21–27. Available at: http://nbuv.gov.ua/UJRN/PhKhTT_2013_14_1_4
  7. Dykha, A., Sorokatyi, R., Makovkin, O., Babak, O. (2017). Calculation-experimental modeling of wear of cylindrical sliding bearings. Eastern-European Journal of Enterprise Technologies, 5 (1 (89)), 51–59. doi: https://doi.org/10.15587/1729-4061.2017.109638
  8. Sorokatyi, R., Chernets, M., Dykha, A., Mikosyanchyk, O. (2019). Phenomenological Model of Accumulation of Fatigue Tribological Damage in the Surface Layer of Materials. Mechanisms and Machine Science, 3761–3769. doi: https://doi.org/10.1007/978-3-030-20131-9_371
  9. Sujuan, Y., Xingrong, Z. (2014). Tribological Properties of PTFE and PTFE Composites at Different Temperatures. Tribology Transactions, 57 (3), 382–386. doi: https://doi.org/10.1080/10402004.2013.812759
  10. Tang, G., Chang, D., Wang, D., He, J., Mi, W., Zhang, J., Wang, W. (2012). Mechanical Property Improvement of Carbon Fiber-Reinforced PTFE Composites by PA6 Filler Dispersion. Polymer-Plastics Technology and Engineering, 51 (4), 377–380. doi: https://doi.org/10.1080/03602559.2011.639831
  11. Yan, Y., Jia, Z., Yang, Y. (2011). Preparation and Mechanical Properties of PTFE/Nano-EG Composites Reinforced with Nanoparticles. Procedia Environmental Sciences, 10, 929–935. doi: https://doi.org/10.1016/j.proenv.2011.09.149
  12. Kaplun, P. V., Dykha, О. V., Gonchar, V. А. (2018). Contact Durability of 40Kh Steel in Different Media After Ion Nitriding and Nitroquenching. Materials Science, 53 (4), 468–474. doi: https://doi.org/10.1007/s11003-018-0096-0
  13. Voropaev, V., Skaskevіch, A., Avdeychik, S., Eisymont, Y., Juldasheva, G. (2013). Technology of polytetrafluoroethylene-based nanocomposite materials: Structural and morphological aspect. Applied Technologies and Innovations, 9 (2), 59–68. doi: https://doi.org/10.15208/ati.2013.11
  14. Mashkov, Y. K., Kalistratova, L. F., Kropotin, O. V. (2018). The Development of Methods for Forming Effective Structural Phase States in Polytetrafuoroethylene-Based Polymer Composites. International Polymer Science and Technology, 45 (3), 87–90. doi: https://doi.org/10.1177/0307174x1804500302
  15. Svoderskiy, V. P., Konstantinova, Т. E., Glazunova, V. A., Kirichenko, L. M., Vodjanij, V. І., Zaharchuk, J. О. (2014). Investigation of mechanical and friction properties of polytetrafluoroeethylene carboplastics modified by nanopowder zirconium dioxide. Problems of Tribology, 2, 103–110. Available at: http://nbuv.gov.ua/UJRN/Ptl_2014_2_18
  16. Berladir, K. V., Budnik, О. A., Dyadyura, K. A., Svidersky, V. A., Kravchenko, Y. O. (2016). Physicochemical principles of the technology of formation of polymer composite materials based on polytetrafluoroethylene - a review. High Temperature Material Processes An International Quarterly of High-Technology Plasma Processes, 20 (2), 157–184. doi: https://doi.org/10.1615/hightempmatproc.2016017875
  17. Berladir, K., Sviderskiy, V. (2016). Designing and examining polytetrafluoroethylene composites for tribotechnical purposes with activated ingredients. Eastern-European Journal of Enterprise Technologies, 6 (6 (84)), 14–21. doi: https://doi.org/10.15587/1729-4061.2016.85095
  18. Gujrathi, S. M., Dhamande, L. S., Patare, P. M. (2013). Wear Studies on Polytetrafluroethylene (PTFE) Composites: Taguchi Approach. Bonfring International Journal of Industrial Engineering and Management Science, 3 (2), 47–51. doi: https://doi.org/10.9756/bijiems.4406
  19. Aulin, V., Hrynkiv, A., Lysenko, S., Dykha, A., Zamota, T., Dzyura, V. (2019). Exploring a possibility to control the stressed­strained state of cylinder liners in diesel engines by the tribotechnology of alignment. Eastern-European Journal of Enterprise Technologies, 3 (12 (99)), 6–16. doi: https://doi.org/10.15587/1729-4061.2019.171619
  20. Dykha, A., Marchenko, D., Artyukh, V., Zubiekhina-Khaiiat, O., Kurepin, V. (2018). Study and development of the technology for hardening rope blocks by reeling. Eastern-European Journal of Enterprise Technologies, 2 (1 (92)), 22–32. doi: https://doi.org/10.15587/1729-4061.2018.126196
  21. Kabat, O. S., Kharchenko, B. G., Derkach, O. D., Artemchuk, V. V., Babenko, V. G. (2019). Polymer composites based on fluoroplastic and method for the production there. Voprosy Khimii i Khimicheskoi Tekhnologii, 3, 116–122. doi: https://doi.org/10.32434/0321-4095-2019-124-3-116-122
  22. Bastos-Arrieta, J., Muñoz, M., Ruiz, P., Muraviev, D. N. (2013). Morphological changes of gel-type functional polymers after intermatrix synthesis of polymer stabilized silver nanoparticles. Nanoscale Research Letters, 8 (1), 255. doi: https://doi.org/10.1186/1556-276x-8-255
  23. Buznik, V. M., Vopilov, Y. E., Ivanov, V. K., Sigachev, A. S., Polyakov, V. S., Smirnov, M. A. et. al. (2013). Structure of polytetrafluoroethylene powders obtained by photochemical polymerization of gaseous monomer. Inorganic Materials: Applied Research, 4 (2), 131–137. doi: https://doi.org/10.1134/s2075113313020044
  24. Aleksandr, D., & Dmitry, M. (2018). Prediction the wear of sliding bearings. International Journal of Engineering & Technology, 7 (2.23), 4. doi: https://doi.org/10.14419/ijet.v7i2.23.11872
  25. Dykha, A., Makovkin, O. (2019). Physical basis of contact mechanics of surfaces. Journal of Physics: Conference Series, 1172, 012003. doi: https://doi.org/10.1088/1742-6596/1172/1/012003
  26. Sujuan, Y., Quan, Y., Kunquan, L., Feng, T., Qing, F., Guibin, T., Xing, H. (2018). The Tribological and Sealing Properties of PFA Composites. International Journal of Polymer Science, 2018, 1–6. doi: https://doi.org/10.1155/2018/2302407
  27. Salavati-Niasari, M., Ghanbari, D. (2011). Polymeric Nanocomposite Materials. In book: Advances in Diverse Industrial Applications of Nanocomposites. Available at: https://www.researchgate.net/publication/221911330_Polymeric_Nanocomposite_Materials

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Published

2020-10-31

How to Cite

Dykha, A., Svidersky, V., Danilenko, I., Bilichenko, V., Kukurudzyak, Y., & Kirichenko, L. (2020). Design and study of nanomodified composite fluoropolymer materials for tribotechnical purposes. Eastern-European Journal of Enterprise Technologies, 5(12 (107), 38–48. https://doi.org/10.15587/1729-4061.2020.214533

Issue

Vol. 5 No. 12 (107) (2020): Materials Science

Section

Materials Science

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Copyright (c) 2020 Aleksandr Dykha, Vladyslav Svidersky, Igor Danilenko, Viktor Bilichenko, Yuri Kukurudzyak, Ludmila Kirichenko

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