Sorption of cobalt, chromium and uranium ions on Fe/Ti-pillared montmorillonite

Authors

  • Ігор Володимирович Пилипенко National Technical University of Ukraine “Kyiv Polytechnic Institute” Peremogy ave., 37, Kyiv, Ukraine, 03056, Ukraine https://orcid.org/0000-0002-0236-7266
  • Лариса Миколаївна Спасьонова National Technical University of Ukraine “Kyiv Polytechnic Institute” Peremogy ave., 37, Kyiv, Ukraine, 03056, Ukraine https://orcid.org/0000-0002-7562-7241
  • Ірина Андріївна Ковальчук Institute of Sorption and Problems of NAS Endoecology, Ukraine https://orcid.org/0000-0002-7019-6534
  • Василь Валерійович Веремеєнко National Technical University of Ukraine "Kiev Polytechnic Institute" avenue, 37, Kiev, Ukraine, 03056, Ukraine https://orcid.org/0000-0003-2495-7459

DOI:

https://doi.org/10.15587/1729-4061.2014.26246

Keywords:

pillared montmorillonite, adsorption, polyhydroxocomplex, porous structure, modification, cobalt, chromium, uranium

Abstract

The structural and adsorption properties of montmorillonite pillared with titanium and iron polyhydroxocomplexes are given in the paper. It was found that the composition of the polyhydroxocomplexes significantly affects the properties of the resultant materials. For studying the basic properties of the resultant materials, the X-ray phase analysis, the low-temperature nitrogen adsorption, and adsorption of the metal ions from aqueous solutions were used.

The results of the X-ray phase analysis, with changes in the respective basal reflections, confirm the presence of iron and titanium polyhydroxocomplexes in the interlayer space of the mineral. Synthesized pillared minerals have a well-developed specific surface, micro- and mesoporosity, as confirmed by the low-temperature nitrogen adsorption.

It was found that the pillared montmorillonite shows relatively high adsorption characteristics relatively to chromium and uranium ions. Adsorption on the pillared montmorillonite samples significantly depends on the pH solutions, adsorptive properties and the composition of the polyhydroxocomplexes, which were used for synthesizing adsorbents.

The research results can be useful for developing and synthesizing new types of inorganic ion-exchange materials for extracting cations and anions of various inorganic toxicants from aqueous solutions.

Author Biographies

Ігор Володимирович Пилипенко, National Technical University of Ukraine “Kyiv Polytechnic Institute” Peremogy ave., 37, Kyiv, Ukraine, 03056

Ph.D. student

Chemical Technology of Ceramics and Glass Department

Лариса Миколаївна Спасьонова, National Technical University of Ukraine “Kyiv Polytechnic Institute” Peremogy ave., 37, Kyiv, Ukraine, 03056

Ph.D. in Chemistry, professor assistant

Chemical Technology of Ceramics and Glass Department

Ірина Андріївна Ковальчук, Institute of Sorption and Problems of NAS Endoecology

Ph.D., Senior Researcher 

Василь Валерійович Веремеєнко, National Technical University of Ukraine "Kiev Polytechnic Institute" avenue, 37, Kiev, Ukraine, 03056

Department of Chemical Technology of Ceramics and Glass 

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Published

2014-08-08

How to Cite

Пилипенко, І. В., Спасьонова, Л. М., Ковальчук, І. А., & Веремеєнко, В. В. (2014). Sorption of cobalt, chromium and uranium ions on Fe/Ti-pillared montmorillonite. Eastern-European Journal of Enterprise Technologies, 4(6(70), 57–61. https://doi.org/10.15587/1729-4061.2014.26246

Issue

Vol. 4 No. 6(70) (2014): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2014 Ігор Володимирович Пилипенко, Ірина Андріївна Ковальчук, Василь Валерійович Веремеєнко, Лариса Миколаївна Спасьонова

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