New intercalation modified structures of natural minerals for high-efficient Li+-cationic electricity generation

Authors

  • Іван Іванович Григорчак Lviv Polytechic National University, Ukraine
  • Роман Ярославович Швець Lviv Polytechic National University Bandery 12, Lviv, 79013, Ukraine
  • Тетяна Миколаївна Біщанюк Lviv Polytechic National University Bandery 12, Lviv, 79013, Ukraine
  • Василь Іванович Балук Lviv Polytechic National University Bandery 12, Lviv, 79013, Ukraine
  • Андрій Сергійович Курепа Lviv Polytechic National University Bandery 12, Lviv, 79013, Ukraine
  • Юрій Орестович Кулик Ivan Franko National University of Lviv Universytetska 1, Lviv, 79000, Ukraine
  • Юрій Іванович Семенцов Chuiko Institute of Surface Chemistry of NAS of Ukraine General Naumov 17, Kyiv, 03164, Ukraine
  • Галина Іванівна Довбешко Institute of Physics of NAS of Ukraine Prospect Nauky, 46, Kyiv, 03028, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2014.26266

Keywords:

gibbsite, chalcopyrite, multigraphene, supramolecular structure, intercalation, Gibbs energy, Nyquist diagram, diffusion coefficient

Abstract

The possibility of a direct application of natural minerals of gibbsite (Al(OH)3), chalcopyrite (CuFeS2) and multigraphene for the efficient Li+ - intercalation current formation was experimentally justified. The reason for studying these materials is that they are cheap, environmentally-friendly, affordable and abundant in nature. The dependences of changing the Gibbs free energy and the kinetic parameters of the intercalation reaction on the degree of “guest” lithium loading were analyzed for these materials. It was shown that the distinguishing feature of the Li+ - intercalation current formation in structures under study was that it was significantly affected by the energy topology of surface states, controlled by the nanoscale dimensionality of the power generating particles and their molecular environment, therefore, acting as a powerful “tool” to improve power-generating capacities of the cathodes of the current lithium sources. Based on the data obtained by the impedance spectroscopy, X-ray diffraction analysis and light-scattering spectroscopy, a mechanism of the observed phenomena was proposed.

Author Biographies

Іван Іванович Григорчак, Lviv Polytechic National University

Professor

Department of Applied Physics and Nanomaterials Science

Роман Ярославович Швець, Lviv Polytechic National University Bandery 12, Lviv, 79013

Postgraduate student

Department of Applied Physics and Nanomaterials Science 

Тетяна Миколаївна Біщанюк, Lviv Polytechic National University Bandery 12, Lviv, 79013

Postgraduate student

Department of Applied Physics and Nanomaterials Science

Василь Іванович Балук, Lviv Polytechic National University Bandery 12, Lviv, 79013

Engineer

Department of Applied Physics and Nanomaterials Science

Андрій Сергійович Курепа, Lviv Polytechic National University Bandery 12, Lviv, 79013

PhD, Assistant

Department of Applied Physics and Nanomaterials Science

Юрій Орестович Кулик, Ivan Franko National University of Lviv Universytetska 1, Lviv, 79000

PhD, Assistant

Department of Metal Physics

Юрій Іванович Семенцов, Chuiko Institute of Surface Chemistry of NAS of Ukraine General Naumov 17, Kyiv, 03164

PhD

Галина Іванівна Довбешко, Institute of Physics of NAS of Ukraine Prospect Nauky, 46, Kyiv, 03028

Professor

Department of physics of biological systems

References

  1. Onishchenko, D. V., Tsvetnikov, A. K., Popovich, A. A., Kuryaviy, V. G. (2007). Synthesis of new cathode materials for lithium chemical sources of a currents. Electronic scientific journal "Investigated in Russia", 118, 1232–1242.
  2. Pidluzhna, A. Y., Grigorchak, I. I., Nikipanchuk, M. V., Ostafiychuk, B. K., Budzulyak, I. M., Mitsov, M. M., Yablon’, L. S. (2012, May). Intercalation current generation in oxygen- and sulfur-doped talc. Russ J Electrochem. Pleiades Publishing Ltd., 48 (5), 598–602. doi:10.1134/s1023193512040118
  3. Grygorchak, I. I. (2002). Talc as a new host material in intercalation nanotechnologies. Reports of NAS of Ukraine, 6, 110–113.
  4. Solodkii, N. F., Shamrikov, A. S., Pogrebenkov, V. M. (2009). Mineral resources base of the Urals for ceramic, refractory and glass industries. Handbook. Edited by prof. Maslennikova G. N. Tomsk: Tomsk Polytechnic University, 332.
  5. Isupov, V. P. (1999). Intercalation compounds of aluminum hydroxide. Journal of Structural Chemistry. Springer Science + Business Media, 40 (5), 832–848. doi:10.1007/bf02903444
  6. Isupov, V. P., Nemudry, A. P., Kotsupalo, N. P., Samsonov, T. I. (1982). About interaction of aluminum hydroxide with aqueous solutions of lithium chloride. Conference on the Chemistry and Technology of rare, nonferrous metals and salts: Abstracts of reports. Frunze: Ilim., 336.
  7. Nemudry, A. P., Isupov, V. P., Kotsupalo, N. P. (1983). On the mechanism of interaction of hydrargillite with aqueous solutions of lithium chloride. VI Union Conference on the Chemistry and Technology of Rare Alkaline Elements: Abstracts of reports. Moscow Science, 9–10.
  8. Burba, J. L. (1983). Crystalline lithium aluminates. Patent № 4348295 (USA).
  9. Isupov, V. P., Chupakhina, L. E. (1994). Intercalation Method for the Production of Active Aluminium Hydroxide. Chemistry for Sustainable Development, 2 (2-3), 535–539.
  10. Lavrentyev, A. A., Gabrelian, B. V., Shkumat, P. N., Kulagin, B. B., Nikiforov, I. Y. (2011). The influence of magnetic ordering on the electronic energy structure of CuFeS2. Journal of Structural Chemistry. Pleiades Publishing Ltd., 52, S65–S68 doi:10.1134/s0022476611070080
  11. Stoller, M. D., Park, S., Zhu, Y., An, J., Ruoff, R. S. (2008). Graphene-Based Ultracapacitors. Nano Lett., 8 (10), 3498–3502. doi:10.1021/nl802558y
  12. Wang, Y., Shi, Z., Huang, Y., Ma, Y., Wang, C., Chen, M., Chen, Y. (2009). Supercapacitor Devices Based on Graphene Materials. The Journal of Physical Chemistry C, 113 (30), 13103–13107. doi:10.1021/jp902214f
  13. Hu, J., Lu, Q., Deng, B., Tang, K., Qian, Y., Li, Y., Liu, X. (1999). A hydrothermal reaction to synthesize CuFeS2 nanorods. Inorganic Chemistry Communications, 2 (12), 569–571. doi:10.1016/s1387-7003(99)00154-9
  14. Komatsu, K., Kuribayashi, T., Kudoh, Y., Kagi, H. (2007). Crystal structures of high-pressure phases in the alumina-water system: I. Single crystal X-ray diffraction and molecular dynamics simulation of η-Al(OH)3. Zeitschrift Für Kristallographie, 222 (1), 1–12. doi:10.1524/zkri.2007.222.1.1
  15. Kriens, M., Adiwidjaja, G., Guse, W., Klaska, K. H., Lathe, C., Saalfeld, H. (1996). The crystal structures of LiAl5O8 and Li2Al4O7. Neues Jahrbuch fuer Mineralogie. Monatshefte, 344–350.
  16. Kabanov, B. N., Chekavtsev, A. V., Petukhova, P. I., Tomashova, N. N., Kiselev, I. G. (1986). Cathodic introduction of lithium into graphite, glassy carbon and aluminum. Russian Journal of Electrochemistry, 22 (3), 415–417.
  17. Stoinov, Z. B., Grafov, B. M., Savova-Stoinova, B. S., Yolkin, V. V. (1991). Electrochemical Impedance. Moscow, USSR: Science, 336.
  18. Sementsov, Yu. I, Pjatkovskyy, M. L. (2008). Thermaly expanded graphite. Inorganic materials science. Encyclopeadic edition in two volumes, 2 (2), 410–425
  19. Ferrari, A. C., Basko, D. M. (2013). Raman spectroscopy as a versatile tool for studying the properties of graphene. Nature Nanotechnology, 8 (4), 235–246. doi:10.1038/nnano.2013.46
  20. Nemanich, R., Solin, S. (1979). First- and second-order Raman scattering from finite-size crystals of graphite. Phys. Rev. B., 12 (20), 392. [http://dx.doi.org/10.1103/PhysRevB.20.392].
  21. Nemanich, R. J., Solin, S. A. (1977). Observation of an anomolously sharp feature in the 2nd order Raman spectrum of graphite. Solid State Communications. Elsevier BV, 23, 417–420. doi:10.1016/0038-1098(77)90998-x
  22. Vidano, R. P., Fischbach, D. B., Willis, L. J., Loehr, T. M. (1981). Observation of Raman band shifting with excitation wavelength for carbons and graphites. Solid State Communications, 39 (2), 341–344. doi:10.1016/0038-1098(81)90686-4
  23. Tuck, Clive D. S. (1991). Modern battery technology. New York, USA: Ellis Horwook, 579.

Downloads

Published

2014-08-13

How to Cite

Григорчак, І. І., Швець, Р. Я., Біщанюк, Т. М., Балук, В. І., Курепа, А. С., Кулик, Ю. О., Семенцов, Ю. І., & Довбешко, Г. І. (2014). New intercalation modified structures of natural minerals for high-efficient Li+-cationic electricity generation. Eastern-European Journal of Enterprise Technologies, 4(5(70), 56–65. https://doi.org/10.15587/1729-4061.2014.26266

Issue

Vol. 4 No. 5(70) (2014): Applied physics. Materials Science

Section

Materials Science

License

Copyright (c) 2014 Іван Іванович Григорчак, Роман Ярославович Швець, Тетяна Миколаївна Біщанюк, Василь Іванович Балук, Андрій Сергійович Курепа, Юрій Орестович Кулик, Юрій Іванович Семенцов, Галина Іванівна Довбешко

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.