Identifying of the compositions of the blended fuels of the butanol, gasoline, and water stabilized at low temperatures
DOI:
https://doi.org/10.15587/1729-4061.2023.286349Keywords:
blended fuels, butanol-gasoline-water, stable emulsion at low temperatures, phase separation, non-surfactantAbstract
The work was purposed to identify the compositions the blended fuel of butanol, gasoline, and water forming the stable emulsions at low temperatures. The previous researches reported that the blending of butanol and gasoline generally employed the synthetic surfactants which were expensive and mixed at room temperatures. It is important to analyze the stability of the substances in the wide range of temperature for it alter significantly on the surface of the planet. The references survey revealed that the works of the compositions of the wet butanol and gasoline at low temperatures are yet published. The present work was successful to blend the butanol, gasoline, and water in stable emulsion without using the surfactant and stabilized in the less of room temperature. Compositions of butanol, gasoline (RONs 90), and water emulsified and stabilized at low temperatures without synthetic surfactants were successfully studied. It was found that aqueous butanol and gasoline formed a stable emulsion at low temperatures and discovered the phase was separated if temperature declined. The compositions of pure butanol, gasoline, and water recorded in stable emulsions using butanol 85.00 % ranged from 75.08–79.24 %, 6.77–11.67 %, and 13.25–13.98 %, respectively, blended at temperatures 0.00–29.70 °C. The usage of butanol 99.50 % caused the change of compositions recorded at 0.71–11.34 %, 88.61–99.29 %, and 0.00–0.06 % blended at 0.00–29.00 °C. It was discovered that the increase of butanol percentage of the fuel after the emulsion was stable tended to the emulsion kept one phase. The emulsion fuels found would be applied to the heat-modified engines operating in wide range temperatures which were below room temperature
Supporting Agency
- The work was finished successfully under the support of respected persons at my institution, Sam Ratulangi University, Manado, Indonesia. I thank Rector Professor Berty Sompi, who fully supported the work by providing the Lab facility needed. Furthermore, I greatly appreciate Professor Jeffrey I. Kindangen, who competitively selected the submitted project proposals and managed the research administration documents. Finally, the approval of the research proposal signed by the Dean of Mathematics and Sciences School, Professor Benny Pinontoan, is highly appreciated. We also thank the contributors, the PIC of the Laboratory of Oil and Gas Processing Engineering, Polytechnic of Energy and Minerals, Cepu Blora, Central Java, and Oil and Gas Laboratory, State Polytechnic of Samarinda, East Kalimantan. We appreciate their technical assistance in measuring the emulsion fuel specifications.
References
- Nel, W. P., Cooper, C. J. (2009). Implications of fossil fuel constraints on economic growth and global warming. Energy Policy, 37 (1), 166–180. doi: https://doi.org/10.1016/j.enpol.2008.08.013
- Fontana, M., Marchesan, A. N., Maciel Filho, R., Maciel, M. R. W. (2021). Extractive distillation to produce anhydrous bioethanol with choline chloride with urea (1:2) as a solvent: a comparative evaluation of the equilibrium and the rate-based models. Chemical Engineering and Processing - Process Intensification, 168, 108580. doi: https://doi.org/10.1016/j.cep.2021.108580
- Chansauria, P., Mandloi, R. K. (2018). Effects of Ethanol Blends on Performance of Spark Ignition Engine-A Review. Materials Today: Proceedings, 5 (2), 4066–4077. doi: https://doi.org/10.1016/j.matpr.2017.11.668
- Machado Neto, P. A. (2021). Why Brazil imports so much corn-based ethanol: The role of Brazilian and American ethanol blending mandates. Renewable and Sustainable Energy Reviews, 152, 111706. doi: https://doi.org/10.1016/j.rser.2021.111706
- Sozinho, D. W. F., Gallardo, A. L. C. F., Duarte, C. G., Ramos, H. R., Ruiz, M. S. (2018). Towards strengthening sustainability instruments in the Brazilian sugarcane ethanol sector. Journal of Cleaner Production, 182, 437–454. doi: https://doi.org/10.1016/j.jclepro.2018.01.261
- Agarwal, A. K., Karare, H., Dhar, A. (2014). Combustion, performance, emissions and particulate characterization of a methanol–gasoline blend (gasohol) fuelled medium duty spark ignition transportation engine. Fuel Processing Technology, 121, 16–24. doi: https://doi.org/10.1016/j.fuproc.2013.12.014
- Sangian, H. F., Tamuntuan, G. H., Mosey, H. I. R., Suoth, V., Manialup, B. H. (2017). The Utilization Of Arenga Pinnata Ethanol In Preparing One Phase-Aqueous Gasohol. ARPN Journal of Engineering and Applied Sciences, 12, 7039–7046. Available at: https://www.arpnjournals.org/jeas/research_papers/rp_2017/jeas_1217_6582.pdf
- Ershov, М. А., Grigoreva, E. V., Habibullin, I. F., Emelyanov, V. E., Strekalina, D. M. (2016). Prospects of bioethanol fuels E30 and E85 application in Russia and technical requirements for their quality. Renewable and Sustainable Energy Reviews, 66, 228–232. doi: https://doi.org/10.1016/j.rser.2016.07.054
- Ors, I., Kul, B. S., Yelbey, S., Ciniviz, M. (2021). Detailed Combustion Analysis of Gasohol at Low, Medium and High Loads in a Spark Ignition Engine. Selcuk University Journal of Engineering Sciences, 20 (01), 18–22. Available at: https://www.researchgate.net/publication/349947792_Detailed_Combustion_Analysis_of_Gasohol_at_Low_Medium_and_High_Loads_in_a_Spark_Ignition_Engine
- Li, Y., Gong, J., Yuan, W., Fu, J., Zhang, B., Li, Y. (2017). Experimental investigation on combustion, performance, and emissions characteristics of butanol as an oxygenate in a spark ignition engine. Advances in Mechanical Engineering, 9 (2), 168781401668884. doi: https://doi.org/10.1177/1687814016688848
- Mohebbi, M., Reyhanian, M., Hosseini, V., Muhamad Said, M. F., Aziz, A. A. (2018). Performance and emissions of a reactivity controlled light-duty diesel engine fueled with n-butanol-diesel and gasoline. Applied Thermal Engineering, 134, 214–228. doi: https://doi.org/10.1016/j.applthermaleng.2018.02.003
- Huynh, T. T., Le, M. D., Duong, D. N. (2019). Effects of butanol–gasoline blends on SI engine performance, fuel consumption, and emission characteristics at partial engine speeds. International Journal of Energy and Environmental Engineering, 10 (4), 483–492. doi: https://doi.org/10.1007/s40095-019-0309-9
- Wang, Y., Yu, X., Ding, Y., Du, Y., Chen, Z., Zuo, X. (2018). Experimental comparative study on combustion and particle emission of n-butanol and gasoline adopting different injection approaches in a spark engine equipped with dual-injection system. Fuel, 211, 837–849. doi: https://doi.org/10.1016/j.fuel.2017.09.108
- Lin, Y., Lee, T., Nithyanandan, K., Zhang, J., Li, Y., Lee, C.-F. (2016). Experimental Investigation and Analysis of Combustion Process in a Diesel Engine Fueled with Acetone-Butanol-Ethanol/ Diesel Blends. SAE Technical Paper Series. doi: https://doi.org/10.4271/2016-01-0737
- Hergueta, C., Bogarra, M., Tsolakis, A., Essa, K., Herreros, J. M. (2017). Butanol-gasoline blend and exhaust gas recirculation, impact on GDI engine emissions. Fuel, 208, 662–672. doi: https://doi.org/10.1016/j.fuel.2017.07.022
- Maiti, S., Gallastegui, G., Kaur Brar, S., LeBihan, Y., Buelna, G., Drogui, P., Verma, M. (2015). Quest for sustainable bio-production and recovery of butanol as a promising solution to fossil fuel. International Journal of Energy Research, 40 (4), 411–438. doi: https://doi.org/10.1002/er.3458
- Liu, X., Xue, S., Ikram, R., Zhu, C., Shi, Y., He, M. (2021). Improving the viscosity and density of n-butanol as alternative to gasoline by blending with dimethyl carbonate. Fuel, 286, 119360. doi: https://doi.org/10.1016/j.fuel.2020.119360
- Li, X., Sun, Z., Yang, S., Wang, H., Nour, M. (2021). Flash boiling combustion of isomeric butanol and gasoline surrogate blends using constant volume spray chamber and GDI optical engine. Fuel, 286, 119328. doi: https://doi.org/10.1016/j.fuel.2020.119328
- Fan, Y., Duan, Y., Liu, W., Han, D. (2020). Effects of butanol blending on spray auto-ignition of gasoline surrogate fuels. Fuel, 260, 116368. doi: https://doi.org/10.1016/j.fuel.2019.116368
- Short, D., Vu, D., Durbin, T. D., Karavalakis, G., Asa-Awuku, A. (2015). Particle speciation of emissions from iso-butanol and ethanol blended gasoline in light-duty vehicles. Journal of Aerosol Science, 84, 39–52. doi: https://doi.org/10.1016/j.jaerosci.2015.02.010
- Feinauer, M., Ehrenberger, S., Buchgeister, J. (2021). Life cycle assessment of a farmed wood butanol-gasoline blend as an alternative transport fuel for passenger cars. Fuel, 306, 121651. doi: https://doi.org/10.1016/j.fuel.2021.121651
- Fagundez, J. L. S., Golke, D., Martins, M. E. S., Salau, N. P. G. (2019). An investigation on performance and combustion characteristics of pure n-butanol and a blend of n-butanol/ethanol as fuels in a spark ignition engine. Energy, 176, 521–530. doi: https://doi.org/10.1016/j.energy.2019.04.010
- Yousif, I. E., Saleh, A. M. (2023). Butanol-gasoline blends impact on performance and exhaust emissions of a four stroke spark ignition engine. Case Studies in Thermal Engineering, 41, 102612. doi: https://doi.org/10.1016/j.csite.2022.102612
- Letcher, T. M., Heyward, C., Wootton, S., Shuttleworth, B. (1986). Ternary phase diagrams for gasoline-water-alcohol mixtures. Fuel, 65 (7), 891–894. doi: https://doi.org/10.1016/0016-2361(86)90192-4
- Sangian, H. F., Pasau, G., Tamuntuan, G. H., Widjaja, A., Purwadi, R., Agnesty, S. Y. et al. (2023). Analysis of compositions and fuel specifications of the aqueous emulsion fuels of gasoline (RON 90)-ethanol-water in stable emulsions at low temperatures. Eastern-European Journal of Enterprise Technologies, 1 (6 (121)), 22–32. doi: https://doi.org/10.15587/1729-4061.2023.272512
- Macák, J., Matějovský, L., Pleyer, O., Růžičková, M. A., Jelínek, L. (2022). Passivation of steel in ethanol–gasoline blends induced by diethylene triamine. Electrochimica Acta, 434, 141263. doi: https://doi.org/10.1016/j.electacta.2022.141263
- Amine, M., Barakat, Y. (2021). Effect of cyclohexanol on phase stability and volatility behavior of hydrous ethanol-gasoline blends. Egyptian Journal of Petroleum, 30 (3), 7–12. doi: https://doi.org/10.1016/j.ejpe.2021.04.001
- Kassem, M. G. A., Ahmed, A.-M. M., Abdel-Rahman, H. H., Moustafa, A. H. E. (2019). Use of Span 80 and Tween 80 for blending gasoline and alcohol in spark ignition engines. Energy Reports, 5, 221–230. doi: https://doi.org/10.1016/j.egyr.2019.01.009
- Amine, M., Awad, E. N., Ibrahim, V., Barakat, Y. (2018). Effect of ethyl acetate addition on phase stability, octane number and volatility criteria of ethanol-gasoline blends. Egyptian Journal of Petroleum, 27 (4), 567–572. doi: https://doi.org/10.1016/j.ejpe.2017.08.007
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2023 Hanny Frans Sangian, Dini Lestari, Guntur Pasau, Gerald H. Tamuntuan, Arief Widjaja, Ronny Purwadi, Silvya Yusnica Agnesty, Bayu Sadjab, Messiah Charity Sangian, Ramli Thahir
This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.
A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.