Determination of the possibility of the synthesis of Zn-Al layered double hydroxides, intercalated with peroxyanions, as a perspective solid disinfectant

Authors

DOI:

https://doi.org/10.15587/1729-4061.2024.303030

Keywords:

Zn–Al double-layer hydroxide, peroxylactic acid, solid disinfectant, intercalation, chemical coprecipitation

Abstract

Infectious diseases in the modern world pose a significant threat to humanity in the form of epidemics and pandemics. To prevent and combat them, it is necessary to carry out antiseptic and disinfectant treatments of various environments, household and industrial surfaces, as well as wounds of various origins. Double-layer hydroxides intercalated with peroxyanions as active oxygen compounds are promising materials for this.

In order to determine the possibility of obtaining Zn-Al double-layer hydroxide intercalated with peroxylactic acid anions, samples were synthesized by the method of chemical co-precipitation in the presence of peroxylactic acid at controlled pH (8, 10) and t=20 ℃. The properties of the synthesized samples were investigated. The content of active oxygen (in terms of H2O2) was determined by the method of iodometric titration with the calculation of the percentage of hydrogen peroxide that was intercalated in double layered hydroxides, remained in the mother solution or was lost. The crystal structure was studied by X-ray phase analysis, the yield of samples was determined gravimetrically, and sedimentation was determined by measuring and normalizing the thickness of the sediment layer.

It was found that the samples synthesized at pH=8 and 10 are biphasic and consist of an oxide phase and a double-layer hydroxide phase. The determined content of active oxygen (in terms of H2O2) in the samples synthesized at pH=8 (0.533 %) and at pH=10 (0.876 %) confirms the success of the synthesis of Zn-Al-peroxylactate double layered hydroxides. Synthesis at elevated pH is promising. A low percentage of H2O2 intercalation was revealed – 4.03–6.54 %, the majority of hydrogen peroxide (82.36-94.44 %) remains in the mother solution.

The yield of the synthesized samples was determined to be 61.9 % and 79.5 % at synthesis pH of 10 and 8, respectively. The sedimentation properties of the samples were studied and their improvement was shown when the pH of the synthesis was increased

Author Biographies

Vadym Kovalenko, Ukrainian State University of Chemical Technolog

PhD, Associate Professor

Department of Analytical Chemistry and Chemical Technology of Food Additives and Cosmetics

Anastasiia Borysenko, Ukrainian State University of Chemical Technology

PhD Student

Department of Analytical Chemistry and Chemical Technology of Food Additives and Cosmetics

Valerii Kotok, Ukrainian State University of Chemical Technology

PhD, Associate Professor

Department of Processes, Apparatus and General Chemical Technology

Volodymyr Verbitskiy, Dragomanov Ukrainian State University

Doctor of Pedagogical Sciences, Professor, Director

Department of Medical, Biological and Valeological Basics of Life and Health Protection

Volodymyr Medianyk, Dnipro University of Technology

PhD, Associate Professor

Department of Mining Engineering and Education

Viktoriia Stoliarenko, Kryvyi Rih State Pedagogical University

PhD, Associate Professor

Department Chemistry and Methods of its Teaching

Yuriy Pepa, State University of Information and Communication Technologies

PhD, Associate Professor, Head of Department

Department of Robotics and Technical Systems

Serhii Simchenko, State University of Information and Communication Technologies

PhD, Associate Professor

Department of Higher Mathematics, Mathematical Mоdeling and Physics

Viktor Ved, Ukrainian State University of Chemical Technolog

Senior Lecturer

Department of Equipment for Chemical Production

Sheikh Ahmad Izaddin Sheikh Mohd Ghazali, Universiti Teknologi MARA (UiTM)

PhD, Associate Professor

Material, Inorganic, and Oleochemistry (MaterInoleo) Research Group

School of Chemistry and Environment

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Determination of the possibility of the synthesis of Zn-Al layered double hydroxides, intercalated with peroxyanions, as a perspective solid disinfectant

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Published

2024-04-30

How to Cite

Kovalenko, V., Borysenko, A., Kotok, V., Verbitskiy, V., Medianyk, V., Stoliarenko, V., Pepa, Y., Simchenko, S., Ved, V., & Ghazali, S. A. I. S. M. (2024). Determination of the possibility of the synthesis of Zn-Al layered double hydroxides, intercalated with peroxyanions, as a perspective solid disinfectant. Eastern-European Journal of Enterprise Technologies, 2(6 (128), 49–55. https://doi.org/10.15587/1729-4061.2024.303030

Issue

Vol. 2 No. 6 (128) (2024): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2024 Vadym Kovalenko, Anastasiia Borysenko, Valerii Kotok, Volodymyr Verbitskiy, Volodymyr Medianyk, Viktoriia Stoliarenko, Yuriy Pepa, Serhii Simchenko, Viktor Ved, Sheikh Ahmad Izaddin Sheikh Mohd Ghazali

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