Influence of fatty acid composition on contact angle and wear rate of Jatropha curcas and sunflower’s mixture by varying compositions mixture

Authors

DOI:

https://doi.org/10.15587/1729-4061.2024.310526

Keywords:

wear rate, contact angle, molecular simulation, Jatropha curcas Linn. oil, sunflower oil

Abstract

United Nation Sustainable Development Goals make sustainability become common goals which drives into investments of innovative product and technology focusing on sustainability. Cutting oils are generally made from mineral oil and the renewable replacement is sought after and one of them are Jatropha curcas and sunflower oil or blend of them. Viscosity and adsorption will influence the properties of cutting oil. The study concern on the relationship between percentage of JCO in the mixture to anti-wear properties and contact angle measured using goniometer contact angle and pin-on-disk tribometer by varying percentage of Jatropha curcas oil in mixtures for 2.5 %, 5 %, 10 %, 20 %, and 30 %. Also, molecular simulation is conducted through molecular dynamic in search of dipole moment, electrostatic potential, polarizability and bond energy. The approach is employed to connect molecular interaction and non-linearity trending of experiment. The experiment shows contact angle and wear scar width and also wear rate become higher when percentage of Jatropha curcas oil is higher. The lowest contact angle is 26.9 deg. and the highest is 36.9 deg. of 2.5 % and 30 % Jatropha oil. The highest wear rate is 6.77e-7 and the lowest is 2.74e-7 of 2.5 % and 30 % Jatropha oil. The simulation gives supporting basis in the finding of experiment in which the viscosity is more prominent in governing wear rate than adsorption. Increases of Jatropha curcas percentages have inversely proportional to dipole moment, polarizability, electrostatic potential and bonding which explain why the fatty acids become more adhere to the fatty acid than to surface. The finding is restricted only for idealized conditions both of molecular structure and surface.

Author Biographies

Moch. Syamsul Ma’arif, Brawijaya University

Master of Mechanical Engineering

Mechanical Engineering Doctorate Program

Department of Mechanical Engineering

I Nyoman Gede Wardana, Brawijaya University

Doctor of Philosophy in Mechanical Engineering, Professor

Department of Mechanical Engineering

Djarot B. Darmadi, Brawijaya University

Doctor of Philosophy in Mechanical Engineering, Professor

Department of Mechanical Engineering

Oyong Novareza, Brawijaya University

Doctor of Philosophy in Mechanical Engineering, Head of Professional Engineer Program

Department of Industrial Engineering

Nanu Admantara, Brawijaya University

Bachelor of Mechanical Engineering

Department of Mechanical Engineering

Iis Siti Aisyah, University of Muhammadiyah Malang

Doctor of Philosophy in Mechanical Engineering, Head of Mechanical Engineering Program

Department of Mechanical Engineering

References

  1. Luna, F. M. T., Cavalcante, J. B., Silva, F. O. N., Cavalcante, C. L. (2015). Studies on biodegradability of bio-based lubricants. Tribology International, 92, 301–306. https://doi.org/10.1016/j.triboint.2015.07.007
  2. Tang, L., Zhang, Y., Li, C., Zhou, Z., Nie, X., Chen, Y. et al. (2022). Biological Stability of Water-Based Cutting Fluids: Progress and Application. Chinese Journal of Mechanical Engineering, 35 (1). https://doi.org/10.1186/s10033-021-00667-z
  3. Afonso, I. S., Nobrega, G., Lima, R., Gomes, J. R., Ribeiro, J. E. (2023). Conventional and Recent Advances of Vegetable Oils as Metalworking Fluids (MWFs): A Review. Lubricants, 11 (4), 160. https://doi.org/10.3390/lubricants11040160
  4. Milano, J., Silitonga, A. S., Tiong, S. K., Ong, M. Y., Masudi, A., Hassan, M. H. et al. (2024). A Comprehensive exploration of jatropha curcas biodiesel production as a viable alternative feedstock in the fuel industry – Performance evaluation and feasibility analysis. Mechanical Engineering for Society and Industry, 4 (1), 17–37. https://doi.org/10.31603/mesi.10610
  5. Abdul Aziz, M. A. A., Hamzah, E., Selamat, M. (2022). Performances of plant based corrosion inhibitors in controlling corrosion of mild steel in sodium chloride environment. Materials Today: Proceedings, 51, 1344–1349. https://doi.org/10.1016/j.matpr.2021.11.385
  6. Zhang, X., Li, C., Zhou, Z., Liu, B., Zhang, Y., Yang, M. et al. (2023). Vegetable Oil-Based Nanolubricants in Machining: From Physicochemical Properties to Application. Chinese Journal of Mechanical Engineering, 36 (1). https://doi.org/10.1186/s10033-023-00895-5
  7. Narayana Sarma, R., Vinu, R. (2022). Current Status and Future Prospects of Biolubricants: Properties and Applications. Lubricants, 10 (4), 70. https://doi.org/10.3390/lubricants10040070
  8. Hermawan, A., Rahardja, I. B., Syam, M. Y., Sukismo, H., Fatah, N., Mardiono, M. (2019). Analysis of Viscosity of Lubricating Oil on Generator Machine Working Hours at KP. Macan Tutul 4203. Journal of Applied Sciences and Advanced Technology, 1 (3), 69–73. Available at: https://jurnal.umj.ac.id/index.php/JASAT/article/view/4312
  9. Rajasozhaperumal, G., Kannan, C. (2023). Comparative evaluation of chemically modified Jatropha oils as sustainable biolubricants in boundary lubrication regime. Tribology International, 186, 108594. https://doi.org/10.1016/j.triboint.2023.108594
  10. Biswas, M. A. S., Rahman, M. M., Ortega, J. A., Peña-Parás, L., Maldonado-Cortés, D., González, J. A. et al. (2022). Lubrication Performance of Sunflower Oil Reinforced with Halloysite Clay Nanotubes (HNT) as Lubricant Additives. Lubricants, 10 (7), 139. https://doi.org/10.3390/lubricants10070139
  11. Wang, Y., Li, C., Zhang, Y., Yang, M., Li, B., Jia, D. et al. (2016). Experimental evaluation of the lubrication properties of the wheel/workpiece interface in minimum quantity lubrication (MQL) grinding using different types of vegetable oils. Journal of Cleaner Production, 127, 487–499. https://doi.org/10.1016/j.jclepro.2016.03.121
  12. Woma, T. Y., Ipilakyaa, T. D., Abdullahi, A. A., Okoro, U. G., Bello, A., Abutu, J. et al. (2023). Evaluation of Friction Co-efficient and Wear Performance of Jatropha Oil Using Standard Steel Ball on Aluminium Disc Tribometer. Journal of Materials and Environmental Science, 14 (10), 1266–1277. Available at: https://www.jmaterenvironsci.com/Document/vol14/vol14_N10/JMES-2023-14108-Woma.pdf
  13. Figueroa, M., García, E., Hernández, E. A. G., Vite-Torres, M. (2014). Friction and Wear of Jatropha curcas Oil Using a Four Balls Tester. Advanced Materials Research, 902, 76–81. https://doi.org/10.4028/www.scientific.net/amr.902.76
  14. Ma, Y., Wu, Y., Lee, J. G., He, L., Rother, G., Fameau, A.-L. et al. (2020). Adsorption of Fatty Acid Molecules on Amine-Functionalized Silica Nanoparticles: Surface Organization and Foam Stability. Langmuir, 36 (14), 3703–3712. https://doi.org/10.1021/acs.langmuir.0c00156
  15. Ma‘arif, Moch. S., Wardana, I. N. G., Darmadi, D. B., Novareza, O., Abidin, Z., Sulistyo, E., Darsono, C. H. (2024). The Influence of Eugenol in Lubrication Properties of Crude Jatropha Curcas Lin. International Journal of Integrated Engineering, 16 (2). https://doi.org/10.30880/ijie.2024.16.02.017
  16. Edem, D. O. (2002). Palm oil: Biochemical, physiological, nutritional, hematological and toxicological aspects: A review. Plant Foods for Human Nutrition, 57 (3/4), 319–341. https://doi.org/10.1023/a:1021828132707
  17. Designation: G 99-95a (Reapproved 2000)e1. Test Method for Wear Testing with a Pin-on-Disk Apparatus. ASTM. Available at: https://cdn.standards.iteh.ai/samples/9915/022a33a120e74c24a23b628770221138/ASTM-G99-95a-2000-e1.pdf
  18. Farrokhnia, M. (2020). Density Functional Theory Studies on the Antioxidant Mechanism and Electronic Properties of Some Bioactive Marine Meroterpenoids: Sargahydroquionic Acid and Sargachromanol. ACS Omega, 5 (32), 20382–20390. https://doi.org/10.1021/acsomega.0c02354
  19. Cho, K. (2005). Polarizabilities. Encyclopedia of Condensed Matter Physics, 341–347. https://doi.org/10.1016/b0-12-369401-9/00603-3
  20. Bibi, S., Ur-rehman, S., Khalid, L., Bhatti, I. A., Bhatti, H. N., Iqbal, J. et al. (2022). Investigation of the adsorption properties of gemcitabine anticancer drug with metal-doped boron nitride fullerenes as a drug-delivery carrier: a DFT study. RSC Advances, 12 (5), 2873–2887. https://doi.org/10.1039/d1ra09319c
Influence of fatty acid composition on contact angle and wear rate of Jatropha curcas and sunflower’s mixture by varying compositions mixture

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Published

2024-10-30

How to Cite

Ma’arif, M. S., Wardana, I. N. G., Darmadi, D. B., Novareza, O., Admantara, N., & Aisyah, I. S. (2024). Influence of fatty acid composition on contact angle and wear rate of Jatropha curcas and sunflower’s mixture by varying compositions mixture . Eastern-European Journal of Enterprise Technologies, 5(6 (131), 15–25. https://doi.org/10.15587/1729-4061.2024.310526

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Technology organic and inorganic substances