Determination of rational parameters of chemical transesterification technology of sunflower oil
DOI:
https://doi.org/10.15587/1729-4061.2024.313095Keywords:
chemical transesterification of sunflower oil, potassium glyceroxide catalyst, oil crystallization temperatureAbstract
The object of the study is the process of chemical transesterification of sunflower oil.
Liquid vegetable oils are an important component in the products of chemical, cosmetic, paint, food and other industries. Among other oils, sunflower oil is of exceptional industrial importance.
Chemical transesterification technology is used to obtain oils, fats and their mixtures with specified properties required for various industries. An important task is to develop rational conditions for the oil transesterification process using a highly efficient and safe catalyst.
The process of chemical transesterification of refined deodorized frozen sunflower oil according to DSTU 4492 (CAS Number 8001-21-6) using potassium glyceroxide was studied. The original oil has the following parameters: peroxide value 0.2 ½ O mmol/kg, acid value 0.1 mg KOH/g, moisture mass fraction 0.03 %, crystallization temperature –18.38 °С.
The effect of transesterification parameters on the oil crystallization temperature was examined. The catalyst concentration in all experiments was 0.45 % by weight of the oil. The oil crystallization temperature was determined by differential scanning calorimetry. Rational parameters of oil transesterification were defined: temperature 110 °C, duration 1.5 hours. Under these conditions, there is a maximum increase in the oil crystallization temperature (up to –4.1 °С). The effectiveness of the rational oil transesterification parameters was confirmed by changes in the triglyceride composition by chromatography analysis.
The obtained rational conditions for the chemical transesterification of sunflower oil in the presence of the potassium glyceroxide catalyst can also be used in the processes of oil transesterification with other raw materials using this catalyst.
References
- Korchak, M., Bragin, O., Petrova, O., Shevchuk, N., Strikha, L., Stankevych, S. et al. (2022). Development of transesterification model for safe technology of chemical modification of oxidized fats. Eastern-European Journal of Enterprise Technologies, 6 (6 (120)), 14–19. https://doi.org/10.15587/1729-4061.2022.266931
- Esipovich, A., Rogozhin, A., Danov, S., Belousov, A., Kanakov, E. (2018). The structure, properties and transesterification catalytic activities of the calcium glyceroxide. Chemical Engineering Journal, 339, 303–316. https://doi.org/10.1016/j.cej.2018.01.142
- Korchak, M., Bliznjuk, O., Nekrasov, S., Gavrish, T., Petrova, O., Shevchuk, N. et al. (2022). Development of rational technology for sodium glyceroxide obtaining. Eastern-European Journal of Enterprise Technologies, 5 (6 (119)), 15–21. https://doi.org/10.15587/1729-4061.2022.265087
- Korchak, M., Yermakov, S., Maisus, V., Oleksiyko, S., Pukas, V., Zavadskaya, I. (2020). Problems of field contamination when growing energy corn as monoculture. E3S Web of Conferences, 154, 01009. https://doi.org/10.1051/e3sconf/202015401009
- Reyero, I., Arzamendi, G., Zabala, S., Gandía, L. M. (2015). Kinetics of the NaOH-catalyzed transesterification of sunflower oil with ethanol to produce biodiesel. Fuel Processing Technology, 129, 147–155. https://doi.org/10.1016/j.fuproc.2014.09.008
- Staroselska, N., Korchak, M., Ovsiannikova, T., Falalieieva, T., Ternovyi, O., Krainov, V. et al. (2024). Improving the technology of oxidative stabilization of rapeseed oil. Eastern-European Journal of Enterprise Technologies, 1 (6 (127)), 6–12. https://doi.org/10.15587/1729-4061.2024.298432
- Salmasi, M. Z., Kazemeini, M., Sadjadi, S. (2020). Transesterification of sunflower oil to biodiesel fuel utilizing a novel K2CO3/Talc catalyst: Process optimizations and kinetics investigations. Industrial Crops and Products, 156, 112846. https://doi.org/10.1016/j.indcrop.2020.112846
- Kadivar, S., De Clercq, N., Danthine, S., Dewettinck, K. (2016). Crystallization and polymorphic behavior of enzymatically produced sunflower oil based cocoa butter equivalents. European Journal of Lipid Science and Technology, 118 (10), 1521–1538. https://doi.org/10.1002/ejlt.201500267
- Bootello, M. A., Chong, P. S., Máñez, Á., Garcés, R., Martínez‐Force, E., Salas, J. J. (2018). Characterization of Sunflower Stearin‐Based Confectionary Fats in Bulk and in Compound Coatings. Journal of the American Oil Chemists’ Society, 95 (9), 1139–1150. https://doi.org/10.1002/aocs.12126
- Zhu, T., Weng, H., Zhang, X., Wu, H., Li, B. (2018). Mechanistic insight into the relationship between triacylglycerol and crystallization of lipase-catalyzed interesterified blend of palm stearin and vegetable oil. Food Chemistry, 260, 306–316. https://doi.org/10.1016/j.foodchem.2018.03.147
- Zhu, T., Zhang, X., Chen, Z., Li, B., Wu, H. (2020). Understanding the relationship between physical properties and crystallization behavior of interesterified blend-based fast-frozen special fat with varied triacylglycerol composition. LWT, 131, 109799. https://doi.org/10.1016/j.lwt.2020.109799
- Ming, L. O., Ghazali, H. M., Chiew Let, C. (1999). Use of enzymatic transesterified palm stearin-sunflower oil blends in the preparation of table margarine formulation. Food Chemistry, 64 (1), 83–88. https://doi.org/10.1016/s0308-8146(98)00083-1
- Farmani, J., Hamedi, M., Safari, M., Madadlou, A. (2007). Trans-free Iranian vanaspati through enzymatic and chemical transesterification of triple blends of fully hydrogenated soybean, rapeseed and sunflower oils. Food Chemistry, 102 (3), 827–833. https://doi.org/10.1016/j.foodchem.2006.06.015
- Rodríguez, A., Castro, E., Salinas, M. C., López, R., Miranda, M. (2001). Interesterification of tallow and sunflower oil. Journal of the American Oil Chemists’ Society, 78 (4), 431–436. https://doi.org/10.1007/s11746-001-0280-5
- Salas, J. J., Bootello, M. A., Piispa, E., Hornyák, L., Venegas-Calerón, M., Martínez-Force, E., Garcés, R. (2023). The effect of enzymatic interesterification on the high oleic-high stearic sunflower oil fractionation and the physico-chemical properties of stearins. LWT, 184, 115042. https://doi.org/10.1016/j.lwt.2023.115042
- Sytnik, N., Demydov, I., Kunitsa, E. (2015). Effectiveness research of new catalyst for oil and fat interesterification by using chromatographic analysis. Technology Audit and Production Reserves, 6 (4 (26)), 8–13. https://doi.org/10.15587/2312-8372.2015.53285
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Mykola Korchak, Anatolii Shostia, Svitlana Usenko, Liudmyla Floka, Nadiia Hnitii, Liubov Morozova, Vita Glavatchuk, Larysa Marushko, Serhii Nekrasov, Roman Mylostyvyi
This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.
A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.