Identifying patterns in the resistance of thermally modified ash wood to weathering

Authors

DOI:

https://doi.org/10.15587/1729-4061.2025.322368

Keywords:

wood, ash, degree of thermal modification, weathering, moisture removalmoisture removal, drying cracks, strength

Abstract

Weathering of thermally modified wood negatively affects both the appearance of structures and their physical-mechanical characteristics, which further determines their service life. Given this, the object of the study was the resistance of ash wood varying degrees modification to abiotic environmental factors. It was found that the color stability of thermally modified wood samples is higher compared to untreated ones. A decrease in the value of the coordinate L from 68.4 to 33.6 indicates a decrease in lightness, that is darkening of the wood. Analysis of dimensional changes revealed increased swelling for untreated wood and amounted to 7.49 %, and for modified at a temperature of 200 °С – 1.75 %. The difference in shrinkage rates is much smaller – 2.09 % for wood of group III, which is 2 times less than untreated wood. The results confirm that thermal modification makes wood cell walls more hydrophobic by eliminating hydrophilic and hydroxyl groups of hemicelluloses. A linear dependence (R2≈1) of change in the physical characteristics of wood depending on its density due to the degree of modification has been established. Analysis of mechanical properties revealed that thermal modification increases the resistance of wood to compressive across the fibers by 2 times. Therefore, a comprehensive approach to analyzing the impact of weathering on the aesthetic, physical, and mechanical properties of thermally modified wood makes it possible to identify the principles of material stability depending on the treatment schedule. The identified mechanisms of transformation of material parameters contribute to the establishment of optimal parameters of thermal modification, which improve its characteristics. This creates the prerequisites for implementing new technological solutions focused on environmental friendliness and energy efficiency in production

Author Biographies

Oleksandra Horbachova, National University of Life and Environmental Sciences of Ukraine

PhD, Associate Professor

Department of Technology and Design of Wood Products

Serhii Mazurchuk, National University of Life and Environmental Sciences of Ukraine

PhD, Associate Professor

Department of Technology and Design of Wood Products

Vasyl Lomaha, National University of Life and Environmental Sciences of Ukraine

PhD, Assistant

Department of Technology and Design of Wood Products

Nataliia Buiskykh, National University of Life and Environmental Sciences of Ukraine

PhD, Senior Lecturer

Department of Technology and Design of Wood Products

Andrii Matviichuk, V.I. Vernadsky National Library of Ukraine

PhD

Nataliia Marchenko, Technical Committee TC-18 “Forest Resources”

PhD, Associate Professor

References

  1. Kránitz, K., Sonderegger, W., Bues, C.-T., Niemz, P. (2015). Effects of aging on wood: a literature review. Wood Science and Technology, 50 (1), 7–22. https://doi.org/10.1007/s00226-015-0766-0
  2. Kiktev, N., Nykyforova, L., Lendiel, T., Mazurchuk, P., Lendiel, M. (2023). Wireless Subsystem for Control Technological Parameters of Electrophysical Influence to Increase Plant Productivity. CEUR Workshop Proceedings, 3646, 149–159. Available at: https://ceur-ws.org/Vol-3646/Paper_15.pdf
  3. Pinchevska, O., Spirochkin, A., Oliynyk, R., Sedliačik, J. (2018). Selection of the efficient drying schedule in conventional chambers. Acta Facultatis Xylologiae, 60 (2), 125–134. https://doi.org/10.17423/afx.2018.60.2.12
  4. Horbachova, O., Buiskykh, N., Mazurchuk, S., Lomaha, V. (2024). Acetylation of Aspen and Alder Wood - Preliminary Tests. Key Engineering Materials, 986, 45–52. https://doi.org/10.4028/p-d9fylx
  5. Mattonai, M., Watanabe, A., Shiono, A., Ribechini, E. (2019). Degradation of wood by UV light: A study by EGA-MS and Py-GC/MS with on line irradiation system. Journal of Analytical and Applied Pyrolysis, 139, 224–232. https://doi.org/10.1016/j.jaap.2019.02.009
  6. Fathi, H., Kazemirad, S., Nasir, V. (2021). Mechanical degradation of wood under ultraviolet radiation characterized by Lamb wave propagation. Structural Control and Health Monitoring, 28 (6). https://doi.org/10.1002/stc.2731
  7. Yorur, H., Kurt, S., Yumrutas, I. (2014). The Effect of Aging on Various Physical and Mechanical Properties of Scotch Pine Wood Used in Construction of Historical Safranbolu Houses. Drvna Industrija, 65 (3), 191–196. https://doi.org/10.5552/drind.2014.1328
  8. Han, L., Xi, G., Dai, W., Zhou, Q., Sun, S., Han, X., Guo, H. (2023). Influence of Natural Aging on the Moisture Sorption Behaviour of Wooden Structural Components. Molecules, 28 (4), 1946. https://doi.org/10.3390/molecules28041946
  9. Cai, C., Zhou, F. (2022). Sorption Characteristic of Thermally Modified Wood at Varying Relative Humidity. Forests, 13 (10), 1687. https://doi.org/10.3390/f13101687
  10. Liu, X. Y., Liu, M., Lv, M. Q., Lv, J. F. (2019). Photodegradation of three hardwood species by sunlight and xenon light sources. BioResources, 14 (3), 6909–6922. https://doi.org/10.15376/biores.14.3.6909-6922
  11. Horbachova, O., Tsapko, Y., Mazurchuk, S., Tsapko, O. (2022). Mobile technology of thermal modification of wood. Ukrainian Journal of Forest and Wood Science, 13 (3). https://doi.org/10.31548/forest.13(3).2022.22-31
  12. Čermák, P., Rautkari, L., Horáček, P., Saake, B., Rademacher, P., Sablík, P. (2015). Analysis of Dimensional Stability of Thermally Modified Wood Affected by Re-Wetting Cycles. BioResources, 10 (2). https://doi.org/10.15376/biores.10.2.3242-3253
  13. Tsapko, Y., Horbachova, O., Mazurchuk, S., Tsapko, А., Sokolenko, K., Matviichuk, A. (2021). Determining patterns in reducing the level of bio-destruction of thermally modified timber after applying protective coatings. Eastern-European Journal of Enterprise Technologies, 5 (10 (113)), 48–55. https://doi.org/10.15587/1729-4061.2021.242899
  14. Pedersen, N. B., Matthiesen, H., Blanchette, R. A., Alfredsen, G., Held, B. W., Westergaard-Nielsen, A., Hollesen, J. (2020). Fungal attack on archaeological wooden artefacts in the Arctic-implications in a changing climate. Scientific Reports, 10 (1). https://doi.org/10.1038/s41598-020-71518-5
  15. Björdal, C. G., Dayton, P. K. (2020). First evidence of microbial wood degradation in the coastal waters of the Antarctic. Scientific Reports, 10 (1). https://doi.org/10.1038/s41598-020-68613-y
  16. Tsapko, Y., Horbachova, O., Mazurchuk, S., Bondarenko, O. (2023). Research of certain aspects of improving the color resistance of thermomodified wood. World Multidisciplinary Civil Engineering-Architecture-Urban Planning Symposium WMCAUS 2022, 2928, 050009. https://doi.org/10.1063/5.0124506
  17. Tarmian, A., Mastouri, A. (2019). Changes in moisture exclusion efficiency and crystallinity of thermally modified wood with aging. IForest - Biogeosciences and Forestry, 12 (1), 92–97. https://doi.org/10.3832/ifor2723-011
  18. Teacă, C. A., Roşu, D., Bodîrlău, R., Roşu, L. (2013). Structural Changes in Wood under Artificial UV Light Irradiation Determined by FTIR Spectroscopy and Color Measurements – A Brief Review. BioResources, 8 (1). https://doi.org/10.15376/biores.8.1.1478-1507
  19. Cogulet, A., Blanchet, P., Landry, V. (2016). Wood degradation under UV irradiation: A lignin characterization. Journal of Photochemistry and Photobiology B: Biology, 158, 184–191. https://doi.org/10.1016/j.jphotobiol.2016.02.030
  20. Obataya, E., Zeniya, N., Endo-Ujiie, K. (2019). Effects of water-soluble extractives on the moisture sorption properties of spruce wood hygrothermally treated at 120°C and different humidity levels. Wood Material Science & Engineering, 16 (2), 124–131. https://doi.org/10.1080/17480272.2019.1635642
  21. Tsapko, Y., Horbachova, O., Likhnyovskyi, R., Mazurchuk, S., Tsapko, А., Buiskykh, N. et al. (2023). Establishment of patterns in the thermal modification of dry pine wood. Eastern-European Journal of Enterprise Technologies, 4 (10 (124)), 24–36. https://doi.org/10.15587/1729-4061.2023.285509
  22. Bhat, I.-H., Abdul Khalil, H. P. S., Awang, K. B., Bakare, I. O., Issam, A. M. (2010). Effect of weathering on physical, mechanical and morphological properties of chemically modified wood materials. Materials & Design, 31 (9), 4363–4368. https://doi.org/10.1016/j.matdes.2010.03.045
  23. Tsapko, Y., Bondarenko, O., Horbachova, O., Mazurchuk, S., Buyskikh, N. (2021). Research activation energy in thermal modification of wood. E3S Web of Conferences, 280, 07009. https://doi.org/10.1051/e3sconf/202128007009
  24. Martín, J. A., López, R. (2023). Biological Deterioration and Natural Durability of Wood in Europe. Forests, 14 (2), 283. https://doi.org/10.3390/f14020283
  25. Tsapko, Y., Buiskykh, N., Likhnyovskyi, R., Horbachova, O., Tsapko, А., Mazurchuk, S. et al. (2022). Establishing regularities in the application of dry pine wood. Eastern-European Journal of Enterprise Technologies, 4 (10 (118)), 51–59. https://doi.org/10.15587/1729-4061.2022.262203
Identifying patterns in the resistance of thermally modified ash wood to weathering

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Published

2025-02-28

How to Cite

Horbachova, O., Mazurchuk, S., Lomaha, V., Buiskykh, N., Matviichuk, A., & Marchenko, N. (2025). Identifying patterns in the resistance of thermally modified ash wood to weathering. Eastern-European Journal of Enterprise Technologies, 1(12 (133), 6–15. https://doi.org/10.15587/1729-4061.2025.322368

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Materials Science