Research into ion exchange softening of highly mineralized waters

Authors

DOI:

https://doi.org/10.15587/1729-4061.2016.75338

Keywords:

desalting of water, cationite, water softening, regeneration of cationite, acidity, alkalinity

Abstract

Very often in the processes of water purification it is required to apply the processes of water desalting and conditioning. Their use is predetermined by the increased mineralization and high level of hardness of surface sources of water consumption. It is expedient to use methods of ion exchange for purification of these waters.

We present the results of research into ion exchange softening of highly mineralized waters on weak­ and strong acidic cationites.

It is demonstrated that with the increase in the content of sodium ions in water, total exchanging dynamic capacity of strong acidic cationite KU­2­8 is reduced from 1744 to 1295 mg­eqv/dm3. This decrease in efficiency of the sorption of hardness ions is due to the increasing degree of desorption of calcium and magnesium ions at high concentrations of sodium ions.

We defined conditions of softening highly mineralized solutions on weak acidic cationite Dowex Mac­3 in the Na+ form and it was shown that the efficiency of softening of these solutions depends little on the concentration of sodium ions. It was found that this cationite in the Na+ form is capable to absorb the hardness ions under those conditions when, in the case of strong acidic cationite KU­2­8, their desorption occurs.

We defined conditions of consistent regeneration of strong­ and weak acidic cationites by the solutions of acids. In this case, the solutions after regeneration of strong acidic cationite were further used for regeneration of weak acidic cationite. When carrying out such regeneration, almost total desorption of the hardness ions was achieved from both strong­ and weak acidic cationite.

Author Biographies

Nikolai Gomelya, National Technical University of Ukraine "Kyiv Polytechnic Institute" Peremohy ave., 37, Kyiv, Ukraine, 03056

Doctor of Technical Sciences, Professor, Head of the Department

Department of Ecology and Technology of Plant Polymers

Valentyna Hrabitchenko, National Technical University of Ukraine "Kyiv Polytechnic Institute" Peremohy ave., 37, Kyiv, Ukraine, 03056

Department of Ecology and Technology of Plant Polymers

Anna Trohimennko, Admiral Makarov National university of Shipbilding Stalingrad Heroes ave., 9, Mykolaiv, Ukraine, 54025

Ph.D, Associate professor

Department of Environmental Health and Safety

Tat'jana Shablij, National Technical University of Ukraine "Kyiv Polytechnic Institute" Peremohy ave., 37, Kyiv, Ukraine, 03056

Doctor of Technical Sciences, Associate professor

Department of Ecology and Technology of Plant Polymers

References

  1. Greenlee, L., Lawler, D., Freeman, B., Marrot, B., Moulin, P. (2009) Reverse osmosis desalination: water sources, technology, and today's challenges. Water research, 43 (9), 2317–2348. doi: 10.1016/j.watres.2009.03.010
  2. Shherbatjuk, M., L'vov, V., Serdjuk, A. (2009). Desalting of mineralized mine water using reverse osmosis method. Bulletin of Donetsk National University. Natural Sciences, 1, 430–435.
  3. Trus, I., Gomelja, M., Radovenchik, V. (2013). The impact of mechanical pretreatment on the efficiency of reverse osmosis water desalination. Herald of East Ukrainian National University named after Vladimir Dal, 9 (198), 197–202.
  4. Greenlee, L. F., Testa, F., Lawler, D. F., Freeman, B. D., Moulin, P. (2010). The effect of antiscalant addition on calcium carbonate precipitation for a simplified synthetic brackish water reverse osmosis concentrate. Water Research, 44 (9), 2957–2969. doi: 10.1016/j.watres.2010.02.024
  5. Li, H.-Y., Ma, W., Wang, L., Liu, R., Wei, L.-S., Wang, Q. (2006). Inhibition of calcium and magnesium-containing scale by a new antiscalant polymer in laboratory tests and a field trial. Desalination, 196 (1-3), 237–247. doi: 10.1016/j.desal.2005.11.024
  6. Makarenko, I., Shablij, T., Krysenko, T. (2009). The use of sodium hydroxoaluminate during conditioning of water for cooling systems in industry and energy. Chemistry and water technology, 31 (5), 542–551.
  7. Feng, D., Aldrich, C., Tan, H. (2000). Treatment of acid mine water by use of heavy metal precipitation and ion exchange. Minerals Engineering, 13 (6), 623–642. doi: 10.1016/s0892-6875(00)00045-5
  8. Talhi, F., Makarova, N., Astrelіn, І., Tolstopalova, N. (2008). Research preconditioning water methods with high hardness for the membrane conditioning. Herald of NTUU "KPI", 4, 127–131.
  9. Vaaramaa, K., Lehto, J. (2003). Removal of metals and anions from drinking water by ion exchange. Desalination, 155 (2), 157–170. doi: 10.1016/s0011-9164(03)00293-5
  10. Makarenko, I., Glushko, O., Risuhіn, V., Malіn, V. (2012). Use cation exchenger Dowex Mac-3 in asidic form at stabilization processing of water. Eastern-European Journal of Enterprise Technologies, 3/6 (57), 16–20. Available at: http://journals.uran.ua/eejet/article/view/4034/3699
  11. Makarenko, I. (2014). Stabilizing treatment of seawater during it desalination by reverse osmosis. Ecology and Industry, 4, 60–65.
  12. Alexandratos, S. D. (2009). Ion-Exchange Resins: A Retrospective from Industrial and Engineering Chemistry Research. Industrial & Engineering Chemistry Research, 48 (1), 388–398. doi: 10.1021/ie801242v
  13. Gomelja, N., Shablij, T., Nosacheva, Ju. (2004). Water conditioning for resource saving systems of water consumption. Eco-technologies and Resource Saving, 4, 55–58.
  14. Risuhіn, V., Glushko, O., Makarenko, І. (2012). The influence of the concentration of sulfuric acid and cation resin form of Dowex MAC-3 on the efficiency of its regeneration. Herald of NTU "KhPI", 34, 137–145.
  15. Goltvjanickaja, E., Shablij, T., Gomelja, N., Stavskaja, S. (2011). Evaluating the efficiency of weak acid cation exchanger Dowex MAC-3 in the cationic water softening. Herald of NTUU "KPI". Chemical engineering, environment and resource conservation, 2 (8), 87–92.

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Published

2016-08-30

How to Cite

Gomelya, N., Hrabitchenko, V., Trohimennko, A., & Shablij, T. (2016). Research into ion exchange softening of highly mineralized waters. Eastern-European Journal of Enterprise Technologies, 4(10(82), 4–9. https://doi.org/10.15587/1729-4061.2016.75338