Influence of temperature on the characteristics of Ni(II), Ti(IV) layered double hydroxides synthesised by different methods

Authors

  • Vitalii Solovov Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005, Ukraine https://orcid.org/0000-0003-0646-7683
  • Vadym Кovalenko Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Federal State Educational Institution of Higher Education "Vyatka State University" Moskovskaya str., 36, Kirov, Russian Federation, 610000, Ukraine https://orcid.org/0000-0002-8012-6732
  • Nikolai Nikolenko Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005, Ukraine https://orcid.org/0000-0001-9289-2680
  • Valerii Kotok Ukrainian State University of Chemical Technology Gagarina ave, 8, Dnipro, Ukraine, 49005 Federal State Educational Institution of Higher Education "Vyatka State University" Moskovskaya str., 36, Kirov, Russian Federation, 610000, Ukraine https://orcid.org/0000-0001-8879-7189
  • Elena Vlasova National Metallurgical Academy of Ukraine Gagarin ave., 4, Dnipro, Ukraine, 49600, Ukraine https://orcid.org/0000-0002-6814-409X

DOI:

https://doi.org/10.15587/1729-4061.2017.90873

Keywords:

layered double hydroxide, nickel, titanium, coprecipitation at high supersaturation, homogeneous coprecipitation

Abstract

The influence of temperature on the characteristics of Ni(II)–Ti(IV) LDH was investigated in the work.

Ni(II)–Ti(IV) layered double hydroxides were synthesized from a solution of Ni2+ and Ti4+ with the cationic ratio of Ni2+/Ti4+=5 by using three coprecipitation techniques: titration, coprecipitation at high supersaturation and homogeneous coprecipitation. The prepared samples were characterized by means of X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Differential scanning calorimetry (DSC).

By means of XRD, it was revealed that all samples prepared using titration and coprecipitation at high supersaturation at 65 and 20 oC correspond to Ni-Ti LDH structure. Elevated temperature during sample preparation using titration and coprecipitation at high supersaturation did not have a significant effect on phase composition, but affected the crystallinity. According to XRD results, the sample prepared using homogeneous coprecipitation at 70 oC had a significant content of b-Ni(OH)2. Increasing the synthesis temperature to 80 oC has led to the almost complete disappearance of b-Ni(OH)2 reflections.

By means of TGA and DSC, it was found that titration method leads to formation of samples with higher thermal stability than those prepared by high supersaturation. Elevated temperature and hydrothermal treatment leads to higher thermal stability of the samples. Samples prepared by homogeneous coprecipitation show complicated behavior during thermal decomposition, confirming the presence of cyanate ions in the interlayer gallery.

Author Biographies

Vitalii Solovov, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005

Postgraduate student

Department of Analytical Chemistry and Food Additives and Cosmetics

Vadym Кovalenko, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005 Federal State Educational Institution of Higher Education "Vyatka State University" Moskovskaya str., 36, Kirov, Russian Federation, 610000

PhD, Associate Professor

Department of Analytical Chemistry and Food Additives and Cosmetics

Department of Technologies of Inorganic Substances and Electrochemical Manufacturing

Nikolai Nikolenko, Ukrainian State University of Chemical Technology Gagarina ave., 8, Dnipro, Ukraine, 49005

Doctor of Chemical Sciences, Professor, Head of Department

Department of Analytical Chemistry and Food Additives and Cosmetics

Valerii Kotok, Ukrainian State University of Chemical Technology Gagarina ave, 8, Dnipro, Ukraine, 49005 Federal State Educational Institution of Higher Education "Vyatka State University" Moskovskaya str., 36, Kirov, Russian Federation, 610000

PhD, Associate Professor

Department of Processes, Apparatus and General Chemical Technology

Department of Technologies of Inorganic Substances and Electrochemical Manufacturing

Elena Vlasova, National Metallurgical Academy of Ukraine Gagarin ave., 4, Dnipro, Ukraine, 49600

PhD, Associate Professor

Department of coating, composite materials and metal protection from corrosion

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Published

2017-02-17

How to Cite

Solovov, V., Кovalenko V., Nikolenko, N., Kotok, V., & Vlasova, E. (2017). Influence of temperature on the characteristics of Ni(II), Ti(IV) layered double hydroxides synthesised by different methods. Eastern-European Journal of Enterprise Technologies, 1(6 (85), 16–22. https://doi.org/10.15587/1729-4061.2017.90873

Issue

Vol. 1 No. 6 (85) (2017): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2017 Vitalii Solovov, Vadym Кovalenko, Nikolai Nikolenko, Valerii Kotok, Elena Vlasova

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