Regulation of properties of ebonite compositions and vulcanized anticorrosive coatings using a ftorlon filler
DOI:
https://doi.org/10.15587/1729-4061.2017.99341Keywords:
ebonite compositions, ftorlon filler, vulcanization of coating, electrical capacitance, chemical resistanceAbstract
Ebonite compositions, which are oligo-butadienes-based, are widely used for gumming the chemical equipment and instruments that are operated in aggressive media. For the ebonite compositions with anti-corrosion purposes, of scientific and practical interest was to explore the possibility of using as a filler of chemically resistant polymeric materials, which include the ftorlon powder F-2M. We examined the effect of a ftorlon filler on the rheological properties of ebonite compositions based on 1.2-oligo-butadiene. Results of the study revealed that the compositions on the base of oligo-butadiene, filled with a ftorlon powder, are the weakly structured systems with a pseudo plastic nature of the flow. Fluctuation grids of the compositions filled with ftorlon are easily destroyed under the action of uniform shear and temperature. In order to resolve this issue and to ensure the developed coagulation structure, the compositions need to be introduced with structure-forming additives, in particular aerosil (up to 5 % by weight).
We determined the dependence of strength of a vulcanizate on the sulfur content and the duration of vulcanization of coatings, which is important in order to regulate the properties and technological process of obtaining the chemically resistant coatings with improved properties. As a result of vulcanization of the examined compositions, it is possible to receive coatings with high strength (up to 27 MPa at tearing) and adhesion (9.8–10.2 MPa at tearing) without the use of specialized primers and adhesives. We explored the ohmic-capacitive characteristics and demonstrated chemical resistance of the vulcanized coatings in the 20 % solutions of sulfuric and hydrochloric acids.References
- Zefirov, N. S. et. al. (Eds.) (1998). Himicheskaya enciklopediya. Vol. 5. Moscow: Bol'shaya Rossiyskaya enciklopediya, 782.
- Wypych, G. (2016). Fillers in Commercial Polymers. Handbook of fillers. Toronto: ChemTec. Publishing, 665–761. doi: 10.1016/b978-1-895198-91-1.50017-8
- Figovsky, O., Beilin, D. (2015). Nanostructured liquid ebonite composition for protective coatings. Journal “Scientific Israel – Technological Advantages", 17 (3-4), 61–85.
- Bondareva, E. A., Pushkarev, Ju. N., Kunshenko, B. V. (2011). Reologicheskie svoistva oligobutadienov s preimushhestvennym soderzhaniem 1,2-zven'ev. Pracі Odes'kogo polіtehnіchnogo unіversitetu, 2, 264–269.
- Bondareva, E. A., Pushkarev, Ju. N., Kunshenko, B. V. (2012). Strukturno-mehanicheskie svoistva oligobutadienov "KRASOL LB”, napolnennyh kaolinom. Pracі Odes'kogo polіtehnіchnogo unіversitetu, 1, 282–285.
- Saitarly, S. V., Pushkarev, Ju. N., Kunshenko, B. V. (2012). Strukturno-mehanicheskie svoistva gidrirovannogo 1,2-oligobutadiena NISSO-GI, napolnennogo kaolinom. Pracі Odes'kogo polіtehnіchnogo unіversitetu, 2, 287–291.
- Zuev, Ju. S. (1972). Razrushenie polimerov pod dejstviem agressivnyh sred. Moscow: Himiya, 229.
- Manin, V. N., Gromov, A. N. (1980). Fiziko-himicheskaya stoikost' polimernyh materialov v usloviyah ekspluatacii. Leningrad: Himiya, 248.
- Drobny, J. G. (2016). Fluid and Heat Resistance of Perfluoroelastomers. Fluoroelastomers Handbook, 329–409. doi: 10.1016/b978-0-323-39480-2.00009-9
- Elastomer diaphragm has chemical resistance (2009). World Pumps, 2009 (510), 12. doi: 10.1016/s0262-1762(09)70091-4
- Weil, E. D., Levchik, S. V. (2015). Flame Retardants for Plastics and Textiles. Carl Hanser Verlag GmbH & Co. KG, 398. doi: 10.3139/9781569905791
- Sucheninov, P. A., Adamenko, N. A., Sergeev, D. V. (2009). Razrabotka i issledovanie kompozicionnyh materialov dlya uplotnenii vozdushnyh porshnevyh kompressorov. Izvestiya Volgogradskogo gosudarstvennogo tehnicheskogo universiteta, 3, 66–69.
- PCTFE/Kel-F®/Neoflon®. Aetna Plastics Corp. Available at: http://www.aetnaplastics.com/products/d/pctfe
- Viton™ Fluoroelastomers. Chemours Company. Available at: https://www.chemours.com/Viton/en_US/
- McKeen, L. W. (2014). Fluoropolymers. The Effect of Long Term Thermal Exposure on Plastics and Elastomers, 183–207. doi: 10.1016/b978-0-323-22108-5.00009-6
- Ebnesajjad, S. (2015). Applications of Polytetrafluoroethylene. Fluoroplastics, 461–478. doi: 10.1016/b978-1-4557-3199-2.00021-5
- Vyrazhejkin, E. S., Loginov, B. A. (2008). Ftorpolimery kak materialy dlia himicheskoi zashhity oborudovaniya i truboprovodov. Rossiskii himicheski zhurnal. Ftorpolimernye materialy. Sostoyanie i perspektivy, 3, 26–30.
- Saitarly, S. V., Plavan, V. P., Pushkarev, Yu. N. (2017). Design of polymeric composite materials for coatings and sealants with increased weather resistance. Technology audit and production reserves, 1 (3 (33)), 9–14. doi: 10.15587/2312-8372.2017.93383
- Pushkarev, Ju. N. (2012). Ebonitovye kompozicii i pokrytiya na osnove oligobutadienov. Kharkiv: Burun Kniga, 172.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2017 Svetlana Saitarly, Viktoriia Plavan, Yuriy Pushkarev, Oleksandr Manoilenko, Inna Dmytrenko
This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.
A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.