Application of oxide-metallic catalysts on valve metals for ecological catalysis

Authors

DOI:

https://doi.org/10.15587/1729-4061.2017.109885

Keywords:

ecological catalysis, oxide-metallic catalyst, plasma-electrolytic oxidation, catalytic activity

Abstract

It is shown that a promising technique for obtaining oxide-metallic catalysts is the plasma-electrolytic oxidation (PEO) of valve metals, particularly aluminum and titanium alloys. Such a mode of synthesis makes it possible to form catalytically active materials with a developed surface, high content of dopants, and a broad scope of application over a single-stage technological process. The d-metals, in particular, manganese and cobalt are most promising as the dopants for oxide-metallic catalysts.

Employing results of the experimental studies, we demonstrated pathways to control the composition and degree of surface development of the mangan- and cobalt-containing oxide-metallic systems by using complex electrolytes. It is established that the obtained oxide coatings are characterized by high catalytic activity in the model conversion reactions of carbon (II) oxide. In terms of such critical process parameters as the degree of conversion and ignition temperature, they are not inferior to, and in some cases, outperform industrial platinum catalysts. The use of manganese-containing oxide-metallic coating of the piston in an internal combustion engine leads to lower fuel consumption and a reduction in the toxicity of gas emissions

Author Biographies

Ann Karakurkchi, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD, Head of Research Laboratory

Research Laboratory of Military Training Faculty

Mykola Sakhnenko, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

Doctor of Technical Sciences, Professor, Head of Department

Department of Physical Chemistry

Maryna Ved, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

Doctor of technical sciences, Professor

Department of General and Inorganic Chemistry

Alexander Galak, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD

Department of Physical Chemistry

Serhii Petrukhin, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD, Associate Professor

Department of Radiation, Chemical, Biological Protection Military Training Faculty

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Published

2017-10-24

How to Cite

Karakurkchi, A., Sakhnenko, M., Ved, M., Galak, A., & Petrukhin, S. (2017). Application of oxide-metallic catalysts on valve metals for ecological catalysis. Eastern-European Journal of Enterprise Technologies, 5(10 (89), 12–18. https://doi.org/10.15587/1729-4061.2017.109885

Issue

Vol. 5 No. 10 (89) (2017): Ecology

Section

Ecology

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Copyright (c) 2017 Ann Karakurkchi, Mykola Sakhnenko, Maryna Ved, Alexander Galak, Serhii Petrukhin

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