Mössbauer studies of spinellides of Mg(FeXCr2-X)O4 system obtained by the hydroxide co-precipitation method

Authors

DOI:

https://doi.org/10.15587/1729-4061.2017.112271

Keywords:

Mössbauer spectroscopy, magnesium ferrite-chromites, spinel, crystalline structure, precipitation method

Abstract

To establish regularities in formation of the magnetic microstructure in magnesium ferrite-chromites by the method of co-precipitation of hydroxides from chlorides of corresponding salts, ferrite spinels were synthesized with Mg(FexCr2-x)O4 composition. It was found by the method of X-ray diffraction analysis that the resulting spinel occupies an intermediate position between normal and inverse spinels. Substitution of chromium for a part of trivalent iron ions in the spinel phases leads to normalization of the spinel structure. The magnetic microstructure of the resulting samples, distribution of iron among sublattices and presence of Fe2+ ions were investigated by the method of Mössbauer spectroscopy.

It was established that the magnetically ordered phase is only present in samples with x>1.6. Due to the non-high sintering temperature, low symmetry of the near surrounding and continuous distribution of effective magnetic fields on the Fe3+ nuclei were observed in the samples. Analysis of the results of Mössbauer and X-ray structural studies has shown deviation of the real near surrounding of the iron ion from the most probable surrounding. No Fe2+ ions were detected by the Mössbauer method in these samples. There is a good agreement in the relation between population of the iron ions among octahedral and tetrahedral sublattices (2.0) found by methods of X-ray and Mössbauer analysis. The obtained information confirms significant dependence of the properties of ferrite-spinels on the features of synthesis and shows necessity of checking the sample characteristics during changes or modifications in the production methods.

Author Biographies

Anna Luсas, Vasyl Stefanyk Precarpathian National University Shevchenka str., 57, Ivano-Frankivsk, Ukraine, 76018

PhD, Associate Professor

Department of Theoretical and Applied Chemistry

Volodymyr Moklyak, G. V. Kurdyumov Institute for Metal Physics of the NAS of Ukraine Akademika Vernadskoho blvd., 36, Kyiv, Ukraine, 03142

PhD, Senior Researcher

Ivan Yaremiy, Vasyl Stefanyk Precarpathian National University Shevchenka str., 57, Ivano-Frankivsk, Ukraine, 76018

Doctor of Physical and Mathematical Sciences, Professor

Department of Materials Science and New Technologies

Sofiya Yaremiy, Ivano-Frankivsk National Medical University Halytska str., 2, Ivano-Frankivsk, Ukraine, 76018

PhD, Assistant

Department of Medical Informatics, Medical and Biological Physics

Ivan Gasyuk, Vasyl Stefanyk Precarpathian National University Shevchenka str., 57, Ivano-Frankivsk, Ukraine, 76018

Doctor of Physical and Mathematical Sciences, Professor

Department of Materials Science and New Technologies

Mykola Matkivskyi, Vasyl Stefanyk Precarpathian National University Shevchenka str., 57, Ivano-Frankivsk, Ukraine, 76018

PhD, Associate Professor

Department of Theoretical and Applied Chemistry

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Published

2017-10-30

How to Cite

Luсas A., Moklyak, V., Yaremiy, I., Yaremiy, S., Gasyuk, I., & Matkivskyi, M. (2017). Mössbauer studies of spinellides of Mg(FeXCr2-X)O4 system obtained by the hydroxide co-precipitation method. Eastern-European Journal of Enterprise Technologies, 5(6 (89), 56–63. https://doi.org/10.15587/1729-4061.2017.112271

Issue

Vol. 5 No. 6 (89) (2017): TECHNOLOGY ORGANIC AND INORGANIC SUBSTANCES

Section

Technology organic and inorganic substances

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Copyright (c) 2017 Anna Luсas, Volodymyr Moklyak, Ivan Yaremiy, Sofiya Yaremiy, Ivan Gasyuk, Mykola Matkivskyi

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