Calculation of phenol-formaldehyde resin polycondensation process according to activity criterion

Authors

  • Владимир Зиновьевич Маслош Institute of Chemical Technology Str. Lenina 31, Rubizhne, Ukraine, 93009, Ukraine
  • Ольга Владимировна Маслош Institute of Technology Str. Donetsk, 43, Severodonetsk, Ukraine, 93400, Ukraine
  • Наталья Николаевна Тараненко Institute of Chemical Technology Str. Lenina 31, Rubizhne, Ukraine, 93009, Ukraine
  • Елена Борисовна Лошкова Institute of Chemical Technology Str. Lenina 31, Rubizhne, Ukraine, 93009, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2013.18197

Keywords:

active groups, oligomer structure, polycondensation process, activity criterion

Abstract

Application of the activity criterion for calculating the polycondensation process of phenol-formaldehyde resins is considered in the paper. Reactive groups, their number and structure occupy a very important place in polycondensation oligomers.

The obtained formula for calculating the activity criterion is very simple and easy to use. Polycondensation constant - the molar ratio of polycondensation components, is always specified by the synthesis conditions. For determining the criterion of oligomers activity it is necessary to know the concentration of reactive groups in the oligomer.

Application of the activity criterion for calculating the polycondensation process greatly facilitates determining the calculation data of polycondensation process.

The calculation of activity criterion is given in the paper on the example of two phenol-formaldehyde resins − namely novolac and resole resins.

Experimental data allow revealing the dependence of the degree of polycondensation oligomer polymerization on the condensation constant and activity criterion.

Author Biographies

Владимир Зиновьевич Маслош, Institute of Chemical Technology Str. Lenina 31, Rubizhne, Ukraine, 93009

Doctor of Technical Sciences, Professor, Head of Department

Department of Technology of Macromolecular Compounds

Ольга Владимировна Маслош, Institute of Technology Str. Donetsk, 43, Severodonetsk, Ukraine, 93400

Ph.D., associate professor

Наталья Николаевна Тараненко, Institute of Chemical Technology Str. Lenina 31, Rubizhne, Ukraine, 93009

Graduate student

Елена Борисовна Лошкова, Institute of Chemical Technology Str. Lenina 31, Rubizhne, Ukraine, 93009

Graduate student

References

  1. Парамонкова, Т. В. Крашение полимеров [Текст] / Т. В. Параманкова. – Л.: Химия, 1980. – 320 с.
  2. Ульрих, П. Полиэфиры и алкидные смолы [Текст] / Пот Ульрих. – М.: Пэйнт-Медиа, 2009.
  3. Слоним, И. Я. Определение строения мочевиноформальдегидных смол циклоцепной структуры методом ЯМР13С [Текст] / И. Я. Слоним, С. Г. Алексеева, Я. Г. Урман, Б. М. Аршава, Б. Я. Аксельрод, Л. Н. Смирнова // ВМС. – 1977. – т. (А) XIX, №4. – С. 793-807.
  4. Охрименко, И. С. Химия и технология пленкообразующих веществ [Текст] : учеб. пос. для вузов / И. С. Охрименко, В. В. Верхоланцев. – Л.: Химия, 1978. – 392 с.
  5. Сорокин, М. Ф. Практикум по химии и технологии пленкообразующих веществ [Текст] / М. Ф.Сорокин, К. А. Лялюшко. – М.: Химия, 1976. – 264 с.
  6. Маслош, В. З. Критерий активности поликонденсационных олигомеров [Текст] / В. З. Маслош, Н. Н. Алексеева, О. В. Маслош, Н. П. Головненко, Р. П. Савяк // Восточно-Европейский журнал передовых технологий. – 2012. – №2/6(56). – С. 4-6.
  7. Калинская, Т. В. Окрашивание полимерных материалов [Текст] / Т. В. Калинская, С. Г. Доброневская, Э. А. Аврутина. – Л.: Химия, 1985. – 183 с.
  8. Гурвич, Я. А. Химия и технология промежуточных продуктов органических красителей и химикатов для полимерных материалов [Текст] / Я. А. Гурвич, С. Т. Кулик. – М.: Высшая школа. 1974. – С. 126-171.
  9. Соколов, Л. Б. Основы синтеза полимеров методом поликонденсации [Текст] / Л. Б. Соколов. – М.: Химия, 1979. – 175 с.
  10. Малкин, А. Я. Реология в процессах образования и превращения полимеров [Текст] / А. Я. Малкин, С. Г. Куличихин. – М.: Химия, 1985. – 240 с.
  11. Paramonkova, T. (1980). Dyeing polymers. L. Chemistry, 320.
  12. Ulrich, P. (2009). Polyesters and alkyd resins. Paint Media, Moscow.
  13. Slonim, I., Alekseev, S., Urman, Y., Arshava, B., Axelrod, B., Smirnov, L. (1977). Determining the structure of urea-formaldehyde resins cyclochain structure by IMR13C. Т. (A) XIX, № 4, 793-807.
  14. Okhrimenko, I.,Verkholantsev, V. (1978). Chemistry and technology of film-forming substances : a manual for schools. L.: Chemistry, 392.
  15. Sorokin, M., Lyalyushko, K. (1976). Workshop on the chemistry and technology of film-forming substances. Publisher "Chemistry", M., 264.
  16. Maslosh, V., Alekseev, N., Maslosh, O., Golovnenkov, N., Savyak, R. (2012). The activity criterion of polycondensation oligomers. Eastern-European Journal Of Enterprise Technologies, 2(6(56)), 4-6.
  17. Kalinskaya, T., Dobronevskaya, S., Avrutina, E. (1985). Staining of polymeric materials. L. Chemistry, 183.
  18. Gurvich, Y., Kulik, S. (1974). Chemistry and Technology of the intermediate products of organic dyes and chemicals for plastics. Moscow High School, 126-171.
  19. Falcons, L. (1979). Basis of the synthesis of polymers by polycondensation. M.: Chemistry, 175.
  20. Malkin, A., Kulichikhin, S. (1985). Rheology in the formation and transformation of the polymers. M.: Chemistry, 240.

Downloads

Published

2013-10-28

How to Cite

Маслош, В. З., Маслош, О. В., Тараненко, Н. Н., & Лошкова, Е. Б. (2013). Calculation of phenol-formaldehyde resin polycondensation process according to activity criterion. Eastern-European Journal of Enterprise Technologies, 5(6(65), 32–35. https://doi.org/10.15587/1729-4061.2013.18197

Issue

Vol. 5 No. 6(65) (2013): Technology of organic and inorganic substanse

Section

Technology organic and inorganic substances

License

Copyright (c) 2014 Владимир Зиновьевич Маслош, Ольга Владимировна Маслош, Наталья Николаевна Тараненко, Елена Борисовна Лошкова

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.