Synthesis and study of optically transparent benzguanamine oligomers with luminescent properties
DOI:
https://doi.org/10.15587/1729-4061.2016.65479Keywords:
synthesis, study, transparency, luminescence, oligomers, polymers, benzguanamine, formaldehyde, spectra, detectorsAbstract
The study of the synthesis of transparent BF oligomers and polymers with luminescent properties, which is an important issue in terms of obtaining new optically transparent luminescent polymers with high operational and spectral properties was carried out. It is shown that modification of benzguanaminе oligomers by glycerol with a content of 20 wt %, allows obtaining materials with high lighttransmittance, low residual stress, shrinkage and water absorption and high physical–mechanical characteristics. At the same time, such an important characteristic of scintillation plastics as BAL, in the aforementioned materials is at level with the PS and PMMA – 40 – 60 to 50 cm – 200 cm. The basic spectral–luminescent properties of transparent oligomers and polymers were investigated. It is shown that they are characterized by the extinction coefficient of up to 9000–12000 and intensity of luminescence with the relative quantum yield of up to 10 % in the range of 360–365 nm. The resulting polymers may be used as the basis of highly transparent products, plastic scintillators and other materials of the optical-luminescent materials science.
References
- Aronggaowa, B., Toda, Y., Ito, N., Shikinaka, K., Shimomura, T. (2013). Transparent Conductive Films Fabricated from Polythiophene Nanofibers Composited with Conventional Polymers. Polymers, 5 (4), 1325–1338. doi: 10.3390/polym5041325
- Yeh, S.-L., Zhu, C.-Y., Kuo, S.-W. (2015). Transparent Heat-Resistant PMMA Copolymers for Packing Light-Emitting Diode Materials. Polymers, 7(8), 1379–1388. doi: 10.3390/polym7081379
- Chauhan, R., Kamani, P. K. (2009). Synthesis and Characterization of Anticorrosive Acrylic Silicone Hybrid Resins. The Journal of Corrosion Sciense end Engineering, 12 (1), 1–16.
- Lu, Y. H., Wang, B., Xiao, G. Y., Hu, Z. Z. (2012). Synthesis of 1,4-Bis(3-amino-5-trifluoromethylphenoxy)Benzene and Properties of the Polyimide Film Therefrom. Advanced Materials Research, 581-582, 297–300. doi: 10.4028/www.scientific.net/amr.581-582.297
- Alias, A. N., Zabidi, Z. M., Ali, A. M. M., Harun, M. K., Yahya, M. Z. A. (2013) Optical characterization and properties of polymeric materials for optoelectronic and photonic applications”. International Journal of Applied Science and Technology, 3, 11–38.
- Majhi, A. K., Thrivikraman, G., Basu, B., Venkataraman, V. (2014). Optically transparent polymer devices for in situ assessment of cell electroporation. European Biophysics Journal, 44 (1-2), 57–67. doi: 10.1007/s00249-014-1001-x
- Wang, Y., Li, T., Li, S., Guo, R., Sun, J. (2015). Healable and Optically Transparent Polymeric Films Capable of Being Erased on Demand. ACS Applied Materials & Interfaces, 7 (24), 13597–13603. doi: 10.1021/acsami.5b03179
- Ahmed, R. M., Saif, M. (2013) Optical Properties of Rhodamine B Dye Doped in Transparent Polymers for Sensor Application, 51 (3), 511–521.
- Koike, Y.,Koike, K. (2010). Progress in low-loss and high-bandwidth plastic optical fibers. Journal of Polymer Science Part B: Polymer Physics, 49 (1), 2–17. doi: 10.1002/polb.22170
- Rauwendaal, C.; Volodin, V. (Ed.) (2008). Identification and elimination of problems in extrusion. St. Petersburg.: Profession, 328.
- Tager, A. A. (2007). Physical chemistry of polymers. 4th edition. Moscow, Scientific World, 576.
- Hammarström, D. (2004). A Model for Simulation of Fiber Suspension Flows. KTH Mechanics, Royal Institute of Technology SE–10044 Stockholm, Sweden, 125.
- Brian Black, W. (2000). Wall slip and boundary effects in polymer shear flows. A dissertation at the University of Wisconsin – Madison. Available at: http://grahamgroup.che.wisc.edu/pub/black_dissert.pdf
- Lebedev, V. V., Blank, T. A., Avramenko, V. L., Eksperiandova, L. P., Mishurov, D. A., Titskaya, V. D., Shadrikov, A. S. (2009). Optically transparent melamine–formaldehyde polymers modified with proton acceptors. Functional materials, 16 (3), 351–354.
- Lebedev, V. V., Avramenko, V. L., Titskaya, V. D. (2008). New scintillation composition based on thermosetting polymers. Presented at 4th Saint–Petersburg Young Scientists Conference.
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Copyright (c) 2016 Vladimir Lebedev
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