Decontamination of methyl parathion in activated nucleophilic systems based on carbamide peroxisolvate

Authors

DOI:

https://doi.org/10.15587/1729-4061.2017.119495

Keywords:

nucleophilic substitution, hydrogen peroxide, carbamide peroxysolvate, methyl parathion, peroxoborate, peroxocarbonate.

Abstract

The study has specified the nucleophilic decomposition of meth­yl parathion (O,O-dimethyl-O-(4-nitrophenyl) thiophosphate) by an НОО– anion generated from carbamide peroxysolvate in the presence of ammonium bicarbonate and boric acid. The revealed effect is the supernucleophilic reactivity of the diatheroxoborate anion ( ) ( )− 2 2 B OH OOH , which is two orders of magnitude higher than the analogous value for the НОО– anion. The tests have shown the principle possibility of using solid sources of hydrogen peroxide in degassing nucleophilic systems.

The value of the α-effect ( − − HOOHOk k ) has been determined, which indicates an abnormally high reactivity of the HOO– anion in the decomposition of toxic phosphorus compounds.

The obtained data show that the activation of hydrogen perox­ide with ammonium bicarbonate and boric acid can be considered as a new approach to the creation of soft ecological systems of decon­tamination of nucleophilic and oxidative effects.

The results obtained can be used to develop long-term decon­tamination systems for decomposing highly toxic pesticides and active pharmaceutical ingredients of organophosphorus nature. Such systems can be used to eliminate the consequences of contamination with components of chemical weapons, toxic pesticides, and toxic active pharmaceutical ingredients.

Author Biographies

Lubov Vakhitova, L. M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry National Academy of Sciences of Ukraine Kharkivske shosse str., 50, Kyiv, Ukraine, 02160

PhD, Senior Researcher

Volodymyr Bessarabov, Kyiv National University of Technologies and Design Nemyrovycha-Danchenka str., 2, Kyiv, Ukraine, 01011

PhD, Associate Professor

Department of Industrial Pharmacy

Nadezhda Taran, L. M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry National Academy of Sciences of Ukraine Kharkivske shosse str., 50, Kyiv, Ukraine, 02160

PhD, Senior Researcher

Galina Kuzmina, Kyiv National University of Technologies and Design Nemyrovycha-Danchenka str., 2, Kyiv, Ukraine, 01011

PhD, Associate Professor

Department of Industrial Pharmacy

Glib Zagoriy, Kyiv National University of Technologies and Design Nemyrovycha-Danchenka str., 2, Kyiv, Ukraine, 01011

Doctor of Pharmaceutical Sciences, Professor

Olga Baula, Kyiv National University of Technologies and Design Nemyrovycha-Danchenka str., 2, Kyiv, Ukraine, 01011

PhD, Associate Professor

Department of Industrial Pharmacy

Anatolii Popov, L. M. Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry National Academy of Sciences of Ukraine Kharkivske shosse str., 50, Kyiv, Ukraine, 02160

Doctor of Chemical Sciences, Professor

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Published

2017-12-25

How to Cite

Vakhitova, L., Bessarabov, V., Taran, N., Kuzmina, G., Zagoriy, G., Baula, O., & Popov, A. (2017). Decontamination of methyl parathion in activated nucleophilic systems based on carbamide peroxisolvate. Eastern-European Journal of Enterprise Technologies, 6(10 (90), 31–37. https://doi.org/10.15587/1729-4061.2017.119495

Issue

Vol. 6 No. 10 (90) (2017): Ecology

Section

Ecology

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Copyright (c) 2017 Lubov Vakhitova, Volodymyr Bessarabov, Nadezhda Taran, Galina Kuzmina, Glib Zagoriy, Olga Baula, Anatolii Popov

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