The regularities of fractionation of sunflower oil palmitic type the use of auxiliary substances
DOI:
https://doi.org/10.15587/1729-4061.2013.18730Keywords:
sunflower oil of palmitic type, fractional crystallization, refractive index, optical densityAbstract
The paper deals with studying the regularities of fractionation of sunflower oil of palmitic type using auxiliary substances. The data on the terms of fractional crystallization of saturated oil with auxiliary substances (crystallization initiators) was obtained and method of palmitic sunflower oil fractionation control is given. The obtained results can be used in solving the problems of control and management of crystallization in processing of fat stock and optimization of heat transfer processes which provide the required quality. It was determined that the proposed initiator leads to faster crystallization process. Rational quantity of the initiator for the process of fractional crystallization is 0.5 % to the weight of oil. Due to applying the specified amount of initiator, the crystallization duration is reduced by 3.4 times and constitutes 20 hours versus 68 hours without the initiator. The increase of oil crystallization rate in the presence of initiator leads to less coverage of the liquid fraction and allows achieving higher melting temperature of high-melting fraction. It was found that the value of optical density of the liquid fraction during crystallization varies to a greater extent and optical density is more sensitive to the changes in feedstock composition and crystallization conditions, while monitoring of the change in the value of refractive index during fractional crystallization is insufficient.
References
- Widlak, N. Crystallization and solidification properties of lipids [Текст] / N. Widlak, R. W. Hartel, S. Narine. – USA : Am. Oil Chemists' Soc. (AOCS), 2001. – 246 p.
- Рогов, Б. А. Теплофизические свойства жиров, масел и жиросодержащих эмульсий в процессах кристаллизации [Текст] / Б. А. Рогов, В. В. Ключкин. – СПб. – ВНИИЖ, 1995. – 82 с.
- Himawan, C. Thermodynamic and kinetic aspects of fat crystallization [Текст] / C. Himawan, V. Starov, A. Stapley // Advances in Colloid and Interface Science. – 2006. – Vol. 122. – P. 3–33.
- Metin, S. Crystallization of fats and oils [Текст] / S. Metin, R. W. Hartel, F. Shahidi. – New York : Wiley-Interscience, 2005. – 361 р.
- Sato, K. Crystallization behavior of fats and lipids—a review [Текст] / K. Sato // J. Chem Eng Science. – 2001. – Vol. 56. – P. 2255–2265.
- Кислухина О. В. Ферменты в производстве пищи и кормов [Текст] / О. В. Кислухина. – М. : ДеЛи принт, 2002. – 336 с.
- Wright A. J. The effect of minor component milk fat crystallization [Текст] / A. J. Wright, A. C. Marangoni // J. Am. Oil Chemists' Soc. – 2000. − Vol. 77. – No. 5. – P. 463-475
- Jacobsberg B. Studies in palm oil crystallisation [Текст] / B. Jacobsberg, C. H. Oh // J. Am. Oil Chemists' Soc. – 1976. − Vol. 53. – P. 609–616.
- The physical properties of modified palm oil [Текст] / D. A. Okiy, W. В. Wright, K. G. Berger [et al] // Journal of science of food and agriculture. – 1978. – Vol. 29. – P. 625–628.
- Процессы и аппараты химической технологии [Текст] : [учебник для студентов высших учебных заведений]. В 2 частях. Часть 2 / [Товажнянский Л.Л., Готлинская А.П., Лещенко В.А и др.] ; под ред. Л.Л. Товажнянского. – Харьков : НТУ «ХПИ», 2005. – 523 с. : ил.
- Dry fractionation and crystallization kinetics of high-oleic high-stearic sunflower oil [Текст] / M. A. Bootello, R. Garces, E. Martinez-Force [et al] // J. Am. Oil Chemists' Soc. – 2011. – Vol. 88. – No. 10. – P. 1511-1519.
- А. с. 970219 СССР, МПК G 01 N 33/04. Способ контроля фракционирования молочного жира [Текст] / Чернова Е. Г. (СССР). ¬ 2960554/28-13 ; заявл. 29.05.80 ; опубл. 30.10.82, Бюл. № 40. ¬ 7 с.
- Куниця, К. Визначення раціональних умов фракційної кристалізації соняшникової олії пальмітинового типу із розплаву [Текст] / К. Куниця, О. Литвиненко, Ф. Гладкий // Східно-Європейський журнал передових технологій. – 2013. – T. 4, N. 6(64). - С. 36-43.
- Laposata, M. Fatty acid ethyl esters: Nonoxidative ethanol metabolites with emerging biological and clinical significance [Текст] / M. Laposata // Lipids. – 1999. – Vol. 34. – No. 1. – Р. 281-285.
- Маргарини. Жири кондитерські та для молочної промисловості. Правила приймання та методи випробування: ДСТУ 4463:2005. – [Чинний від 2007-01-01]. – К. : Держспоживстандарт України, 2007. – 42 с. – (Національні стандарти України)
- Жогло, Ф. А. Жиросахара (Получение, свойства, применение) [Текст] / Ф. А. Жогло. – М. : Медицина, 1975. – 112 с.
- Абрамович, А. А. Моноглицериды дистиллированные, свойства и применение в пищевой промышленности [Текст] / А. А. Абрамович, Я. И. Тетельман. – М. : Чезет, 2012. – 165 с.
- Павлова, И.В. Теоретические и экспериментальные основы развития технологии производства заменителя масла какао: автореф. дис. на соискание наук. степени д-ра техн. наук: спец. 05.18.06 [Текст] / И.В. Павлова; [ГНУ ВНИИЖ Россельхозакадемии]. – СПб, 2000. – 55 c.
- Widlak, N., Hartel, R. W., Narine, S. (2001). Crystallization and solidification properties of lipids. – USA : Am. Oil Chemists' Soc. (AOCS), 246.
- Rogov, B. A., Kliuchkyn V. V. (1995). Teplofyzycheskye svoistva zhyrov, masel y zhyrosoderzhashchykh yemulsyi v protsessakh krystallyzatsyy. VNYYZh, 82.
- Himawan, C., Starov, V., Stapley, A. (2006). Thermodynamic and kinetic aspects of fat crystallization. Advances in Colloid and Interface Science, 122, 3–33.
- Metin, S., Hartel, R. W., Shahidi, F. (2005). Crystallization of fats and oils. New York : Wiley-Interscience, 361.
- Sato, K. (2001). Crystallization behavior of fats and lipids—a review. J. Chem Eng Science, 56, 2255–2265.
- Kyslukhyna, O. V. (2002). Fermenty v proyzvodstve pyshchy y kormov. Dely prynt, 336.
- Wright, A. J., Marangoni, A. C. (2000). The effect of minor component milk fat crystallization. J. Am. Oil Chemists' Soc., 77, 5, 463-475.
- Jacobsberg, B., Oh C.H. (1976). Studies in palm oil crystallisation. J. Am. Oil Chemists' Soc., 53, 609–616.
- Okiy, D. A., Wright, W. В., Berger, K. G. et al. (1978). The physical properties of modified palm oil. Journal of science of food and agriculture, 29, 625–628.
- Tovazhnianskyi, L.L., Hotlynskaia, A.P., Leshchenko, V.A. et al. (2005). Protsessy y apparaty khymycheskoi tekhnologyy : [uchebnyk dlia studentov vysshykh uchebnykh zavedenyi]. 523.
- Bootello, M. A., Garces, R., Martinez-Force, E. et al. (2011). Dry fractionation and crystallization kinetics of high-oleic high-stearic sunflower oil. J. Am. Oil Chemists' Soc., 88, 10, 1511-1519.
- Chernova, E. H. (1980) Sposob kontrolia fraktsionirovania molochnoho zhira. А. s. 970219 SSSR, MPK G 01 N 33/04, 7.
- Kunytsia, К.V., Lytvynenko, О.A., Hladkyi, F.F. (2013). Vyznachennia ratsionalnykh umov fraktsiinoi krystallizatsii soniashnykovoi olii palmitynovoho typu. Eastern-European Journal of Enterprise Technologies, 4(6(64)), 36–43.
- Laposata, M. (1999). Fatty acid ethyl esters: Nonoxidative ethanol metabolites with emerging biological and clinical significance. Lipids, 34, 1, 281-285.
- Marharyny. Zhyry kondyterski ta dlia molochnoi promyslovosti. Pravyla pryimannia ta metody vyprobuvannia: DSTU 4463:2005. Derzhspozhyvstandart Ukrainy, 42.
- Zhohlo, F. A. (1975). Zhyrosakhara (Poluchenye, svoistva, prymenenye). Medytsyna, 112.
- Abramovich, A. A., Tetelman, Ya. I. (2012). Monogliceridy distillirovannye, svoystva i primenenie v pischevoy promyshlennosti. Chezet, 165.
- Pavlova, I.V. (2000). Teoreticheskye y eksperymentalnye osnovy razvytyia tekhnologyy proyzvodstva zamenytelia masla kakao, 55.
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