Synthesis of high-effective steel corrosion inhibitors in water-oil mixtures

Authors

DOI:

https://doi.org/10.15587/1729-4061.2020.194315

Keywords:

corrosion inhibitor, imidazoline, mineralized waters, optimal dose

Abstract

It is a relevant and practically important task for environmental protection to devise effective means to protect metals against corrosion in aggressive media containing water, petroleum products, carbolic acids, and mineral salts. To stop corrosion, corrosion inhibitors are used that must be constantly improved and whose composition must be properly adjusted. The main drawback of the highly effective inhibitors based on alkyl imidazolines, a mixture of alkyl imidazolines with alkyl pyridinium and/or quaternary ammonium compounds soluble in a methanol medium, is their high prices at relatively significant consumption in the corrosive environment. This paper reports the synthesis of steel corrosion inhibitors in oil-containing aqueous environments that meet the stricter ecological and economic requirements. It has been shown that increasing the level of water mineralization improves the corrosive activity of aqueous environments relative to unalloyed steels. The presence of carbon dioxide, hydrogen sulfide, or carboxylic acids leads to the oxidation of water-oil mixtures resulting in the increased rate of steel corrosion. We have studied the effectiveness of the synthesized inhibitors based on oil and polyethylene polyamines containing imidazolines. At a temperature of 80 °C, the mixture that contained 200 cm3of a 3 % sodium chloride solution, 800 cm3of oil, and at the concentration of acetic acid of 0.5 and 3.0 g/dm3 at the inhibitor dose of 50 mg/dm3, has reached the degree of protection of steel against corrosion at the level of 90–92 %. Based on a full factorial experiment, the regression equation has been derived that makes it possible to easily enough calculate an optimal dose of the steel corrosion inhibitor in water-oil mixtures. It has been shown that the synthesized inhibitor shows prospects for protecting metals against corrosion both in the mineralized waters containing oil and in the presence of petroleum products containing water

Author Biographies

Nikolai Gomelya, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute" Peremohy ave., 37, Kyiv, Ukraine, 03056

Doctor of Technical Sciences, Professor, Head of Department

Department of Ecology and Technology of Plant Polymers

Inna Trus, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute" Peremohy ave., 37, Kyiv, Ukraine, 03056

PhD, Senior Lecturer

Department of Ecology and Technology of Plant Polymers

Olena Stepova, National University «Yuri Kondratyuk Poltava Polytechnic» Pershotravnevyi ave., 24, Poltava, Ukraine, 36011

PhD, Associate Professor

Department of Applied Ecology and Environmental Sciences

Oleksandr Kyryliuk, National Academy of the Security Service of Ukraine M. Maksymovycha str., 22, Kyiv, Ukraine, 03022

PhD, Senior Lecturer

Department of National Security

Olena Hlushko, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute" Peremohy ave., 37, Kyiv, Ukraine, 03056

PhD, Associate Professor

Department of Ecology and Тechnology of Plant Polymers

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Published

2020-02-29

How to Cite

Gomelya, N., Trus, I., Stepova, O., Kyryliuk, O., & Hlushko, O. (2020). Synthesis of high-effective steel corrosion inhibitors in water-oil mixtures. Eastern-European Journal of Enterprise Technologies, 1(6 (103), 6–11. https://doi.org/10.15587/1729-4061.2020.194315

Issue

Vol. 1 No. 6 (103) (2020): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2020 Nikolai Gomelya, Inna Trus, Olena Stepova, Oleksandr Kyryliuk, Olena Hlushko

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