Processing of ethanol-containing waste of oil neutralization in the technology of hand cleaning paste

Authors

DOI:

https://doi.org/10.15587/1729-4061.2021.225233

Keywords:

waste of oil and fat industry, alkaline neutralization of oils, water – glycerin – ethanol system, soapstock, hand cleaning paste, washing ability

Abstract

The graphical dependence of the washing capacity of ethanol-containing soapstock on the concentration in an aqueous solution and the temperature of interaction with the polluted material has been determined. It is proposed to use a 40 % aqueous solution of ethanol-containing soapstock in the hand cleaning paste technology. This soapstock solution has a washing capacity of 92–98 % at the temperature of interaction with the polluted material of 25–40 °C.

The regularity of the effect of the structurant content on the consistency of hand cleaning paste was investigated using an approximating polynomial. This made it possible to substantiate the effective concentration of carboxymethyl cellulose (0.4...0.6 %) and cetysltearyl alcohol (1.8...2.0 %) in the formulation. The obtained regression equation is useful for adjusting the content of structurants in the formulation, depending on the consumer's requirements for the viscosity of the developed detergent.

A comparison of the quality indicators of the developed hand cleaning paste based on ethanol-containing soapstock with a sample of similar “Primaterra Automotive” commercial hand cleaning paste was carried out. The quality indicators of the developed paste are as follows: effective viscosity at 20...22 °С – 32.0 Pa∙s; foaming capacity – 23 mm, foam stability – 62.0 %; washing ability – 92.0 %. It was determined that these quality indicators do not differ significantly in the developed detergent and commercial analogue. The data obtained indicate the prospects of processing ethanol-containing soapstock into the hand cleaning paste based on natural surfactants. The developed detergent due to the content of ethanol, glycerin and hydrogen peroxide has antiseptic properties, which is a competitive advantage among analogues. Such utilization of ethanol-containing soapstock makes the process of oil neutralization environmentally safe and economically viable

Author Biographies

Ihor Petik, Ukrainian Scientific Research Institute of Oils and Fats of the National Academy of Agricultural Sciences of Ukraine

PhD, Head of Laboratory

Department of Studies of Technology for Processing Oils and Fats

Anna Belinska , Ukrainian Scientific Research Institute of Oils and Fats of the National Academy of Agricultural Sciences of Ukraine

PhD, Associate Professor, Researcher

Department of Studies of Technology for Processing Oils and Fats

Ekaterina Kunitsia, Kharkiv Institute of Trade and Economics of Kyiv National University of Trade and Economics

PhD

Department of Innovative Food and Restaurant Technologies

Sergiy Bochkarev, National Technical University «Kharkiv Polytechnic Institute»

PhD, Senior Lecturer

Department of Physical Education

Tetiana Ovsiannikova, National Technical University «Kharkiv Polytechnic Institute»

PhD

Department of Organic Synthesis and Nanotechnology

Viktoriia Kalyna, Dnipro State Agrarian and Economic University

PhD, Associate Professor

Department of Technology of Storage and Processing of Agricultural Products

Anton Chernukha, National University of Civil Defence of Ukraine

PhD

Department of Fire and Rescue Training

Kostiantyn Ostapov, National University of Civil Defence of Ukraine

PhD

Department of Fire Tactics and Rescue Operations

Natalia Grigorenko, National University of Civil Defence of Ukraine

PhD

Department of Management and Organization in the Field of Civil Protection

Olena Petukhova, National University of Civil Defence of Ukraine

PhD, Associate Professor

Department of Fire Prevention in Settlements

References

  1. Boukerroui, A., Belhocine, L., Ferroudj, S. (2017). Regeneration and reuse waste from an edible oil refinery. Environmental Science and Pollution Research, 25 (19), 18278–18285. doi: https://doi.org/10.1007/s11356-017-9971-8
  2. Sytnik, N., Kunitsia, E., Mazaeva, V., Chernukha, A., Kovalov, P., Grigorenko, N. et. al. (2020). Rational parameters of waxes obtaining from oil winterization waste. Eastern-European Journal of Enterprise Technologies, 6 (10 (108)), 29–35. doi: https://doi.org/10.15587/1729-4061.2020.219602
  3. Papchenko, V., Matveeva, T., Bochkarev, S., Belinska, A., Kunitsia, E., Chernukha, A. et. al. (2020). Development of amino acid balanced food systems based on wheat flour and oilseed meal. Eastern-European Journal of Enterprise Technologies, 3 (11 (105)), 66–76. doi: https://doi.org/10.15587/1729-4061.2020.203664
  4. Pal, U. S., Patra, R. K., Sahoo, N. R., Bakhara, C. K., Panda, M. K. (2014). Effect of refining on quality and composition of sunflower oil. Journal of Food Science and Technology, 52 (7), 4613–4618. doi: https://doi.org/10.1007/s13197-014-1461-0
  5. Chew, S.-C., Tan, C.-P., Nyam, K.-L. (2017). Optimization of neutralization parameters in chemical refining of kenaf seed oil by response surface methodology. Industrial Crops and Products, 95, 742–750. doi: https://doi.org/10.1016/j.indcrop.2016.11.043
  6. Petik, I. P., Hladkyi, F. F., Fediakina, Z. P., Bielinska, A. P., Filenko, L. M. (2011). Vplyv komponentnoho skladu osnovy neitralizuiuchoho rozchynu na yoho kharakterystyky. Visnyk Natsionalnoho tekhnichnoho universytetu "KhPI", 58, 31–35. Available at: http://repository.kpi.kharkov.ua/handle/KhPI-Press/15589
  7. Shnyp, I. A., Slepneva, L. M., Kraetskaya, O. F., Zyk, N. V., Luk'yanova, R. S. (2011). Sposoby utilizatsii soapstoka – tekhnogennogo othoda zhiropererabatyvayushchey promyshlennosti. Vestnik Belorusskogo natsional'nogo tekhnicheskogo universiteta, 2, 68–71. Available at: http://rep.bntu.by/handle/data/1079
  8. Zhang, H., Miller, C. A., Garrett, P. R., Raney, K. H. (2003). Mechanism for defoaming by oils and calcium soap in aqueous systems. Journal of Colloid and Interface Science, 263 (2), 633–644. doi: https://doi.org/10.1016/s0021-9797(03)00367-9
  9. Sakai, K., Sangawa, Y., Takamatsu, Y., Kawai, T., Matsumoto, M., Sakai, H., Abe, M. (2010). Sulfonic-Hydroxyl-Type Heterogemini Surfactants Synthesized from Unsaturated Fatty Acids. Journal of Oleo Science, 59 (10), 541–548. doi: https://doi.org/10.5650/jos.59.541
  10. Bhardwaj, G., Cameotra, S., Chopra, H. (2013). Utilization of oleo-chemical industry by-products for biosurfactant production. AMB Express, 3 (1), 68. doi: https://doi.org/10.1186/2191-0855-3-68
  11. Pinzi, S., Pilar dorado, M. (2012). Feedstocks for advanced biodiesel production. Advances in Biodiesel Production, 69–90. doi: https://doi.org/10.1533/9780857095862.1.69
  12. Shavkat, S. M., Demidov, I. N. (2012). Obtaining fatty acid esters of low molecular weight alcohols with using soapstock. Eastern-European Journal of Enterprise Technologies, 6 (6 (60)), 53–56. Available at: http://journals.uran.ua/eejet/article/view/5568/5009
  13. Obtaining fatty acid esters of low molecular weight alcohols with using soapstock. Eastern-European Journal of Enterprise Technologies
  14. Su, E., Wei, D. (2014). Improvement in biodiesel production from soapstock oil by one-stage lipase catalyzed methanolysis. Energy Conversion and Management, 88, 60–65. doi: https://doi.org/10.1016/j.enconman.2014.08.041
  15. Hilten, R., Speir, R., Kastner, J., Das, K. C. (2011). Production of aromatic green gasoline additives via catalytic pyrolysis of acidulated peanut oil soap stock. Bioresource Technology, 102 (17), 8288–8294. doi: https://doi.org/10.1016/j.biortech.2011.06.049
  16. Shabtai, Y. (1990). Production of exopolysaccharides by Acinetobacter strains in a controlled fed-batch fermentation process using soap stock oil (SSO) as carbon source. International Journal of Biological Macromolecules, 12 (2), 145–152. doi: https://doi.org/10.1016/0141-8130(90)90066-j
  17. Daisuk, P., Shotipruk, A. (2020). Recovery of γ-oryzanol from rice bran oil soapstock derived calcium soap: Consideration of Hansen solubility parameters and preferential extractability in various solvents. LWT, 134, 110238. doi: https://doi.org/10.1016/j.lwt.2020.110238
  18. Petik, P. F., Petik, I. P., Fediakina, Z. P., Filenko, L. M. (2015). Development of technological scheme of production of neutralized fat in a polar solvent system and processing soapstock. Visnyk Natsionalnoho tekhnichnoho universytetu "KhPI", 44 (1153), 11–14. Available at: http://repository.kpi.kharkov.ua/handle/KhPI-Press/20920
  19. Kownatzki, E. (2003). Hand hygiene and skin health. Journal of Hospital Infection, 55 (4), 239–245. doi: https://doi.org/10.1016/j.jhin.2003.08.018
  20. Goldman, M., Horev, B., Saguy, I. (1983). Decolorization of β-Carotene in Model Systems Simulating Dehydrated Foods. Mechanism and Kinetic Principles. Journal of Food Science, 48 (3), 751–754. doi: https://doi.org/10.1111/j.1365-2621.1983.tb14890.x
  21. Menegueti, M. G., Laus, A. M., Ciol, M. A., Auxiliadora-Martins, M., Basile-Filho, A., Gir, E. et. al. (2019). Glycerol content within the WHO ethanol-based handrub formulation: balancing tolerability with antimicrobial efficacy. Antimicrobial Resistance & Infection Control, 8 (1). doi: https://doi.org/10.1186/s13756-019-0553-z

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Published

2021-02-23

How to Cite

Petik, I., Belinska , A., Kunitsia, E., Bochkarev, S., Ovsiannikova, T., Kalyna, V., Chernukha, A., Ostapov, K., Grigorenko, N., & Petukhova, O. (2021). Processing of ethanol-containing waste of oil neutralization in the technology of hand cleaning paste . Eastern-European Journal of Enterprise Technologies, 1(10 (109), 23–29. https://doi.org/10.15587/1729-4061.2021.225233

Issue

Vol. 1 No. 10 (109) (2021): Ecology

Section

Ecology

License

Copyright (c) 2021 Игорь Павлович Петик, Анна Павловна Белинская, Катерина Викторовна Куница, Сергей Владимирович Бочкарев, Татьяна Александровна Овсянникова, Виктория Сергеевна Калина, Антон Андреевич Чернуха, Конcтантин Михайлович Остапов, Наталья Владимировна Григоренко, Елена Анатольевна Петухова

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