Solid-phase spectrophotometric determination of Нg (II) using xylenol orange

Authors

  • Єлизавета Євгеніївна Костенко National University of Food Technologies Vladimirskaya 68, Kiev, Ukraine, 01601, Ukraine
  • Олена Миколаївна Бутенко National University of Food Technologies Vladimirskaya 68, Kiev, Ukraine, 01601, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2014.26201

Keywords:

spectrophotometry, analysis, mercury, concentration, sorption, dyes, immobilization, anion exchanger

Abstract

The following optimal interaction conditions of mercury with xylenol orange in the phase of the polymeric anion exchanger АВ-178-С1 were determined: maximum extraction (87%) of Hg (II) is achieved at pH 5-7 for 20 minutes of phase contact from the volume of 50 cm3. Quantitative sorption is also possible from 500 cm3 of the solution. Herewith, the concentration coefficient is 1667 cm3/g. The detection limit is 0.2 mcg/cm3. Mercury is not virtually adsorbed by the basis (AB-178). The Baer's law is fulfilled in the mercury concentration range (0,1 – 8,0) 105 М (V = 50сm3). opt = 640 nm.

Complexing of Hg (II) with SP XO is affected by: 1:1- Cu (ІІ), Zn (ІІ), Cd (ІІ), Zr (ІV), Fe (ІІІ); 1:50 - Pb (ІІ), Sn (ІV); 1:100 - Co (ІІ), a.e.m., Br, SO42, F, Al (ІІІ); 1:1000 - NO3.

Chemistry of complexing in the studied system was considered. Ratio of components in the complex - Hg : CO-A = 1 : 1 was determined. Conditional stability constant of the complex lg1 = 16,9 0,5 was calculated.

The data obtained were used to develop a new technique for the SPS determination of mercury (II) in chemicals, which is highly competitive with the best standard techniques by sensitivity, selectivity and promptness, and superior to them by the simplicity of the experiment.

The technique was tested on a model mixture. Data validation was carried out using the "made-found" method. Convergence of results, obtained using the new technique and standard (AAS method), verifies them

Author Biographies

Єлизавета Євгеніївна Костенко, National University of Food Technologies Vladimirskaya 68, Kiev, Ukraine, 01601

Professor

Department of Analytical chemistry

Олена Миколаївна Бутенко, National University of Food Technologies Vladimirskaya 68, Kiev, Ukraine, 01601

Assistant professor

Department of Analytical chemistry

References

  1. Zajcev, V. N. (1997). Kompleksoobrazujushhie kremnezemy: sintez, stroenie privitogo sloja i himija poverhnosti. Harkiv: Folio, 240.
  2. Gladyshev, V. P., Levickaja, S. A., Filippova, L. M. (1974). Analiticheskaja himija rtuti. Moscow: Nauka, 224.
  3. Alekseev, V. G. (2010). Ionnye ravnovesija v rastvorah penicillinov, cefalosporinov i ih metallokompleksov. Tverskoj gos. un-t. Tver, 48.
  4. Vladimirova, E. V. (2011). Primenenie vol'tamperometrii na granice razdela dvuh nesmeshivajushhihsja rastvorov jelektrolitov dlja opredelenija antibiotikov makrolidnogo i aminoglikozidnogo rjadov. Moscow university, 28.
  5. Gusev, S. N., Gusev, R. S., Gramma, A. I.; zajaviteli i patentoobladateli Gusev, S. N., Gusev, R. S., Gramma, A. I. (2012). Helatnye kompleksy rtuti s cisteinom i metioninom, sposob ihpoluchenija i lekarstvennyj preparat «Merkurid» - moduljator apoptoza, obladajushhij protivoopuholevym, protivovirusnym, protivoparazitarnym i immunomodulirujushhim dejstviem. Patent 2456001 Russia: MPK Ros. Federacija:A61K 33/28, A61K 31/198, C01G 13/00, A61P 35/00, A61P 31/12, A61P 37/02, A61P 33/00 (2006.01). № 2010107176/15; zajavl. 26.02.10; opubl. 20.07.12, Bjul. № 25, 3.
  6. Mondal, B. C., K. Das, A. (2003). Determination of mercury species with a resin functionalized with a 1,2-bis(o-aminophenylthio)ethane moiety. Analytica Chimica Acta, 477 (1), 73–80. doi:10.1016/s0003-2670(02)01372-7
  7. Dedkova, V. P., Shvoeva, O. P., Savvin, S. B. (2004). Test-metod opredelenija rtuti (ІІ) ditizonom na tverdoj faze voloknistogo anionoobmennika. Zhurn. analit. himii, 59 (4), 429–433.
  8. Kołodyńska, D. (2009). Polyacrylate anion exchangers in sorption of heavy metal ions with the biodegradable complexing agent. Chemical Engineering Journal, 150 (2-3), 280–288. doi:10.1016/j.cej.2008.12.027
  9. Kostenko, E. E., Shtokalo, M. J. (2006). Doslіdzhennja vzaєmodії Cu(II), Pb(II), Zn(II), Hg(II), Cd(II) z tverdofaznim erіohromom chornim T. Eastern-Europen Journal of Enterprise Techologies, 6 (24), 45–48.
  10. Kostenko, E. E., Butenko, O. M. (2014). Tverdofazne spektrofotometrichne viznachennja Hg (II) za dopomogoju hromazurola S. Eastern-Europen Journal of Enterprise Techologies, 3/5 (69), 20–24.
  11. Vengris, T., Binkien, R., Sveikauskait, A. (2001). Nickel, copper and zinc removal from waste water by a modified clay sorbent. Applied Clay Science, 18 (3-4), 183–190. doi:10.1016/s0169-1317(00)00036-3
  12. Pradas, E. G., Sánchez, M. V., Cruz, F. C., Viciana, M. S., Pérez, M. F. (1994). Adsorption of cadmium and zinc from aqueous solution on natural and activated bentonite. J. Chem. Technol. Biotechnol., 59 (3), 289–295. doi:10.1002/jctb.280590312
  13. Viraraghavan, T., Kapoor, A. (1994). Adsorption of mercury from wastewater by bentonite. Applied Clay Science, 9(1), 31–49. doi:10.1016/0169-1317(94)90013-2
  14. Tonle, I. K., Ngameni, E., Walcarius, A. (2005). Preconcentration and voltammetric analysis of mercury(II) at a carbon paste electrode modified with natural smectite-type clays grafted with organic chelating groups. Sensors and Actuators B: Chemical, 110 (2), 195–203. doi:10.1016/j.snb.2005.01.027
  15. Goswami, A., Singh, A. K. (2002). Silica gel functionalized with resacetophenone: synthesis of a new chelating matrix and its application as metal ion collector for their flame atomic absorption spectrometric determination. Analytica Chimica Acta, 454 (2), 229–240. doi:10.1016/s0003-2670(01)01552-5
  16. Etienne, M. (2003). Analytical investigation of the chemical reactivity and stability of aminopropyl-grafted silica in aqueous medium. Talanta, 59 (6), 1173–1188. doi:10.1016/s0039-9140(03)00024-9
  17. Pérez-Quintanilla, D., del Hierro, I., Fajardo, M., Sierra, I. (2006). Preparation of 2-mercaptobenzothiazole-derivatized mesoporous silica and removal of Hg(ii) from aqueous solution. Journal of Environmental Monitoring, 8 (1), 214. doi:10.1039/b507983g
  18. Arendarjuk, E. N., Trofimchuk, A. K., Janovskaja, Je. S., Batkovskaja, L. A. (2001). Sorbcionno-spektroskopicheskoe opredelenie rtuti na γ-aminopropilsilikagele. Ukr. him. zhurn, 67 (9), 33–36.
  19. Simonova, L. N., Bruskina I. M., Trofimchuk A. K., Trjashin, A. S. (1989). Sorbcionno-fotometricheskoe opredelenie razlichnyh form rtuti s pomoshh'ju silikagelja s privitoj N-benzoil-N'-propiltiomochevinoj. Zhurn. analit. himii., 44, 661–665.
  20. Ajvazov, B. V. (1968). Prakticheskoe rukovodstvo po hromatografi. Moscow: Vyssh. shk., 81–88.
  21. Kostenko, E. E., Shtokalo, M. I. (2004). Tverdofaznaja spektrofotometrija – jeffektivnyj metod opredelenija tjazhelyh metallov v pishhevyh ob’ektah. Zhurn. analit. himii, 59 (12), 1276–1282.
  22. Kostenko, E. E. (2011). Hіmіko-analіtichnі vlastivostі sul'foftaleїnovih barvnikіv, іmmobіlіzovanih na anіonіtі AV-17–8 ta їh vikoristannja v analіzі harchovih ob'єktіv. Metodi ta ob‘ekti hіm. analіzu, 6 (1-2), 56–70.
  23. Kostenko, E. E. (2002). Patent № 49538 A. Ukraїna. MPK 7 S01G13/00. Sposіb viznachennja mіkrokіl'kostej merkurіju (ІІ). Zajavnik і vlasnik patentu Nacіonal'nij unіversitet harchovih tehnologіj. № 2001128967; zajavleno 25.12.01; Nadruk. 16.09.2002, Bjul. № 9, 4.
  24. Nikolaeva, T. M., Lazarev, A. I. (1992). Opredelenie zheleza metodom tverdofaznoj spektrofotometrii. Zavodskaja laboratorija, 58 (10), 10–13.
  25. Brykina, G. D., Marchenko, D. Ju., Shpigun, O. A. (1995). Tverdofaznaja spektrofotometrija. Zhurn. analit. himii, 50 (5), 484–491.
  26. Brykina, G. D., Krysina, L. S., Ivanov, V. M. (1988). Tverdofaznaja spektrofotometrija. Zhurn. analit. himii., 43 (9), 1547–1560.

Downloads

Published

2014-08-08

How to Cite

Костенко, Є. Є., & Бутенко, О. М. (2014). Solid-phase spectrophotometric determination of Нg (II) using xylenol orange. Eastern-European Journal of Enterprise Technologies, 4(6(70), 44–48. https://doi.org/10.15587/1729-4061.2014.26201

Issue

Vol. 4 No. 6(70) (2014): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

License

Copyright (c) 2014 Єлизавета Євгеніївна Костенко, Олена Миколаївна Бутенко

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.