Identifying the influence of the concentration of surfactants on the technological indicators of aerosol emulsion

Authors

DOI:

https://doi.org/10.15587/1729-4061.2024.317819

Keywords:

emulsion system, Emulgin B2, Lanett SX, sodium laureth sulfate, moisturizing agents, propylene glycol, glyceryl cocoate

Abstract

The object of the study is an emulsion system containing emulsifiers (Emulgin B2, Lanett SX), wetting agents (propylene glycol, glyceryl cocoate) and sodium laureth sulfate as a foaming agent. The main problem solved in the study is to ensure rational technological properties of emulsion systems in aerosol form under variable storage and use conditions. The results obtained showed that to ensure maximum emulsion stability during 7 and 30 days of storage, the optimal concentrations of Emulgin B2 are 2.75…3.0 %, and Lanett SX is 2.0…2.5 %. To achieve the desired foaming ability (80…85 %) and foam stability (75…80 %), it is recommended to use sodium laureth sulfate at a concentration of 0.20…0.22 %. It was found that the wetting agents – propylene glycol (7 %) and glyceryl cocoate (1.5 %) – provide optimal system viscosity within 35…40 mPa·s. The stability of the emulsion is ensured by the formation of strong interfacial films using Lanett SX, while Emulgin B2 improves the thermal stability of the system. Foaming properties are provided by the ability of sodium laureth sulfate to reduce interfacial tension, however, too high concentrations can lead to foam oversaturation and deterioration of its stability. The features of the obtained results are that specific concentration limits of the components are justified, at which the necessary stability and functionality of the emulsion system are ensured. This allows solving the problem of achieving optimal characteristics of the emulsion system during storage and use, ensuring comfortable application to the skin and a stable foam structure. The scope of application of the obtained results is the cosmetic industry

Author Biographies

Bogdan Putyatin, National Technical University “Kharkiv Polytechnic Institute”

PhD Student

Department of Biotechnology, Biophysics and Analytical Chemistry

Olga Bliznjuk, National Technical University “Kharkiv Polytechnic Institute”

Doctor of Technical Sciences, Professor, Head of Department

Department of Biotechnology, Biophysics and Analytical Chemistry

Nataliia Masalitina, National Technical University “Kharkiv Polytechnic Institute”

PhD, Associate Professor

Department of Biotechnology, Biophysics and Analytical Chemistry

Valentyna Bezpal'ko, State Biotechnological University

PhD

Department of Crop Production

Liubov Zhukova, State Biotechnological University

PhD

Department of Zoology, Entomology, Phytopathology, Integrated Plant Protection and Quarantine named B. M. Litvinova

Olesia Filenko, National Technical University “Kharkiv Polytechnic Institute”

PhD

Department of Chemical Engineering and Industrial Ecology

Viktoriia Horiainova, State Biotechnological University

PhD

Department of Zoology, Entomology, Phytopathology, Integrated Plant Protection and Quarantine named B. M. Litvinova

Maryna Ponomarova, State Biotechnological University

PhD, Associate Professor

Department of UNESCO "Philosophy of Human Communication and Social and Humanitarian Disciplines"

Anton Ryabev, O. M. Beketov National University of Urban Economy in Kharkiv

PhD

Department of Tourism and Hospitality

Dmytro Beliuchenko, National University of Civil Defence of Ukraine

PhD

Department of Fire and Rescue Training

References

  1. Kovaliova, O., Pivovarov, O., Kalyna, V., Tchoursinov, Y., Kunitsia, E., Chernukha, A. et al. (2020). Implementation of the plasmochemical activation of technological solutions in the process of ecologization of malt production. Eastern-European Journal of Enterprise Technologies, 5 (10 (107)), 26–35. https://doi.org/10.15587/1729-4061.2020.215160
  2. Kovaliova, O., Tchoursinov, Y., Kalyna, V., Koshulko, V., Kunitsia, E., Chernukha, A. et al. (2020). Identification of patterns in the production of a biologically-active component for food products. Eastern-European Journal of Enterprise Technologies, 2 (11 (104)), 61–68. https://doi.org/10.15587/1729-4061.2020.200026
  3. Bliznjuk, O., Masalitina, N., Mezentseva, I., Novozhylova, T., Korchak, M., Haliasnyi, I. et al. (2022). Development of safe technology of obtaining fatty acid monoglycerides using a new catalyst. Eastern-European Journal of Enterprise Technologies, 2 (6 (116)), 13–18. https://doi.org/10.15587/1729-4061.2022.253655
  4. Ilyasoglu Buyukkestelli, H., El, S. N. (2019). Development and characterization of double emulsion to encapsulate iron. Journal of Food Engineering, 263, 446–453. https://doi.org/10.1016/j.jfoodeng.2019.07.026
  5. Varanasi, S., Henzel, L., Mendoza, L., Prathapan, R., Batchelor, W., Tabor, R., Garnier, G. (2018). Pickering Emulsions Electrostatically Stabilized by Cellulose Nanocrystals. Frontiers in Chemistry, 6. https://doi.org/10.3389/fchem.2018.00409
  6. Elaine, E., Bhandari, B., Tan, C. P., Nyam, K. L. (2024). Recent Advances in the Formation, Stability, and Emerging Food Application of Water-in-Oil-in-Water Double Emulsion Carriers. Food and Bioprocess Technology, 17 (11), 3440–3460. https://doi.org/10.1007/s11947-024-03350-y
  7. Bhattacharjee, A., Chakraborty, A., Mukhopadhyay, G. (2018). Double emulsions - A review with emphasis on updated stability enhancement perspective. World Journal of Pharmacy and Pharmaceutical Sciences, 7 (6), 475–493. Available at: https://www.researchgate.net/publication/325568289_DOUBLE_EMULSIONS_-_A_REVIEW_WITH_EMPHASIS_ON_UPDATED_STABILITY_ENHANCEMENT_PERSPECTIVE
  8. Sayyar, Z., Jafarizadeh-Malmiri, H. (2024). Enhancing the efficacy of nano-curcumin on cancer cells through mixture design optimization of three emulsifiers. BMC Chemistry, 18 (1). https://doi.org/10.1186/s13065-024-01160-z
  9. Zheng, Y., Zi, Y., Shi, C., Gong, H., Zhang, H., Wang, X., Zhong, J. (2023). Tween emulsifiers improved alginate-based dispersions and ionic crosslinked milli-sized capsules. Npj Science of Food, 7 (1). https://doi.org/10.1038/s41538-023-00208-z
  10. Blankart, M., Oellig, C., Averweg, S., Schwack, W., Hinrichs, J. (2020). Effect of storage at high temperature on chemical (composition) and techno-functional characteristics of E471 food emulsifiers applied to aerosol whipping cream. Journal of Food Engineering, 277, 109882. https://doi.org/10.1016/j.jfoodeng.2019.109882
  11. Schick, D., Link, K., Schwack, W., Granvogl, M., Oellig, C. (2021). Analysis of mono-, di-, triacylglycerols, and fatty acids in food emulsifiers by high-performance liquid chromatography–mass spectrometry. European Food Research and Technology, 247 (4), 1023–1034. https://doi.org/10.1007/s00217-021-03684-3
  12. Franzol, A., Banin, T. M., Brazil, T. R., Rezende, M. C. (2021). Assessment of kinetic stability of cosmetic emulsions formulated with different emulsifiers using rheological and sensory analyses. Journal of Sol-Gel Science and Technology, 99 (3), 469–481. https://doi.org/10.1007/s10971-021-05587-x
  13. Blankart, M., Kratzner, C., Link, K., Oellig, C., Schwack, W., Hinrichs, J. (2020). Technical emulsifiers in aerosol whipping cream – Compositional variations in the emulsifier affecting emulsion and foam properties. International Dairy Journal, 102, 104578. https://doi.org/10.1016/j.idairyj.2019.104578
  14. Felix-Sagaste, K. G., Garcia-Carrasco, M., Picos-Corrales, L. A., Gonzalez-Ruelas, T., Rodriguez-Mercado, J. A. (2023). Plant-animal extracts and biocompatible polymers forming oil-in-water emulsions: Formulations for food and pharmaceutical industries. Hybrid Advances, 3, 100072. https://doi.org/10.1016/j.hybadv.2023.100072
  15. Oellig, C., Blankart, M., Hinrichs, J., Schwack, W., Granvogl, M. (2020). Determination of mono- and diacylglycerols from E 471 food emulsifiers in aerosol whipping cream by high-performance thin-layer chromatography–fluorescence detection. Analytical and Bioanalytical Chemistry, 412 (27), 7441–7451. https://doi.org/10.1007/s00216-020-02876-2
  16. Raisel, L. B., Colet, R., Nascimento, L. H. do, Cardoso, L., Azambuja, L. L., Souza Zanchetta, B. de et al. 2024). Development of an innovative stabilizer-emulsifier mixture to enhance the quality of ice cream on a structured scale. Journal of Food Measurement and Characterization, 18 (7), 6250–6263. https://doi.org/10.1007/s11694-024-02644-1
  17. Petik, I., Belinska, A., Kunitsia, E., Bochkarev, S., Ovsiannikova, T., Kalyna, V. et al. (2021). Processing of ethanol-containing waste of oil neutralization in the technology of hand cleaning paste. Eastern-European Journal of Enterprise Technologies, 1 (10 (109)), 23–29. https://doi.org/10.15587/1729-4061.2021.225233
  18. Khosharay, S., Rahmanzadeh, M., ZareNezhad, B. (2020). Surface Behavior of Aqueous Solutions of Sodium Lauryl Ether Sulfate, Additives and Their Mixtures: Experimental and Modeling Study. International Journal of Thermophysics, 41 (12). https://doi.org/10.1007/s10765-020-02738-0
Identifying the influence of the concentration of surfactants on the technological indicators of aerosol emulsion

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Published

2024-12-30

How to Cite

Putyatin, B., Bliznjuk, O., Masalitina, N., Bezpal’ko, V., Zhukova, L., Filenko, O., Horiainova, V., Ponomarova, M., Ryabev, A., & Beliuchenko, D. (2024). Identifying the influence of the concentration of surfactants on the technological indicators of aerosol emulsion. Eastern-European Journal of Enterprise Technologies, 6(6 (132), 6–15. https://doi.org/10.15587/1729-4061.2024.317819

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Section

Technology organic and inorganic substances