Experimental determination of the effect of fire-extinguishing agents on a decrease in the temperature indicators of cylindrical lithium-ion batteries

Authors

DOI:

https://doi.org/10.15587/1729-4061.2025.343574

Keywords:

lithium-ion cell, cooling efficiency, temperature reduction, extinguishing agents, water, carbon dioxide

Abstract

This study defines fire hazard parameters for the Panasonic NCR18650B (LiNi0.8Co0.15Al0.05O2) lithium-ion battery (LIB). The task to obtain high-quality fire extinguishing substances and materials to prevent the spread of combustion implies determining the appropriate data experimentally. In particular, establishing the thermophysical characteristics and time dependence of the change in temperature indicators for the Panasonic NCR18650B (LiNi0.8Co0.15Al0.05O2) LIB depending on different fire extinguishing substances is a relevant issue that is resolved in this work.

Based on the results of experimental studies, it was determined that the time of occurrence of the critical temperature inside LIB (~ 170°C) exposed to an external energy source (~ 300°C) is ~ 400 s. The effectiveness of the use of water and carbon dioxide (CO2) on the effectiveness of reducing (cooling) the temperature of the internal filling was experimentally established. Accordingly, the time for reducing the battery temperature to 20°C with water is 400 s; when using CO2, it is 280 s.

The mathematical model reasonably describes the cooling process of the LIB internal filling and accordingly verifies the experimental results of the study. The proposed mathematical model makes it possible to predict the complete cooling of the LIB depending on the type of extinguishing agent and the initial temperature of the substance. Additionally, the LIB heat transfer coefficients α (W/m2·°C) exposed to the action of water and CO2 were established, which are 20 and 50, respectively.

The results make it possible to devise effective fire extinguishing agents and an algorithm for their application, in particular, to set the parameters of the extinguishing time and the required volume of the extinguishing agent in accordance with the power and type of battery. Additionally, the mathematical model built can be used for other types of LIBs with already known thermophysical characteristics

Author Biographies

Oleksandr Lazarenko, Lviv State University of Life Safety

PhD, Associate Professor

Department of Preventive Activities in the Field of Fire and Technogenic Safety

Oleg Pazen, Lviv State University of Life Safety

PhD

Department of Preventive Activities in the Field of Fire and Technogenic Safety

Nadiia Ferents, Lviv State University of Life Safety

PhD, Associate Professor

Department of Preventive Activities in the Field of Fire and Technogenic Safety

Ivan Adolf, Lviv State University of Life Safety

Doctor of Philosophy (PhD)

Fire Safety Research Laboratory

Volodymyr-Petro Parkhomenko, Lviv State University of Life Safety

PhD, Associate Professor

Department of Fire Tactics and Emergency Rescue Operations

References

  1. Feng, X., Ouyang, M., Liu, X., Lu, L., Xia, Y., He, X. (2018). Thermal runaway mechanism of lithium ion battery for electric vehicles: A review. Energy Storage Materials, 10, 246–267. https://doi.org/10.1016/j.ensm.2017.05.013
  2. Nyamathulla, S., Dhanamjayulu, C. (2024). A review of battery energy storage systems and advanced battery management system for different applications: Challenges and recommendations. Journal of Energy Storage, 86, 111179. https://doi.org/10.1016/j.est.2024.111179
  3. Lai, X., Yao, J., Jin, C., Feng, X., Wang, H., Xu, C., Zheng, Y. (2022). A Review of Lithium-Ion Battery Failure Hazards: Test Standards, Accident Analysis, and Safety Suggestions. Batteries, 8 (11), 248. https://doi.org/10.3390/batteries8110248
  4. Murphy, M., Akrami, M. (2024). Advanced Thermal Management of Cylindrical Lithium-Ion Battery Packs in Electric Vehicles: A Comparative CFD Study of Vertical, Horizontal, and Optimised Liquid Cooling Designs. Batteries, 10 (8), 264. https://doi.org/10.3390/batteries10080264
  5. Liu, K., Liu, Y., Lin, D., Pei, A., Cui, Y. (2018). Materials for lithium-ion battery safety. Science Advances, 4 (6). https://doi.org/10.1126/sciadv.aas9820
  6. Altuntop, E. S., Erdemir, D., Kaplan, Y., Özceyhan, V. (2023). A comprehensive review on battery thermal management system for better guidance and operation. Energy Storage, 5 (8). https://doi.org/10.1002/est2.501
  7. Xie, L., Huang, Y., Lai, H. (2020). Coupled prediction model of liquid-cooling based thermal management system for cylindrical lithium-ion module. Applied Thermal Engineering, 178, 115599. https://doi.org/10.1016/j.applthermaleng.2020.115599
  8. Luo, W., Zhu, S., Gong, J., Zhou, Z. (2018). Research and Development of Fire Extinguishing Technology for Power Lithium Batteries. Procedia Engineering, 211, 531–537. https://doi.org/10.1016/j.proeng.2017.12.045
  9. Grandjean, T. R. B., Groenewald, J., Marco, J. (2019). The experimental evaluation of lithium ion batteries after flash cryogenic freezing. Journal of Energy Storage, 21, 202–215. https://doi.org/10.1016/j.est.2018.11.027
  10. Ghiji, M., Novozhilov, V., Moinuddin, K., Joseph, P., Burch, I., Suendermann, B., Gamble, G. (2020). A Review of Lithium-Ion Battery Fire Suppression. Energies, 13 (19), 5117. https://doi.org/10.3390/en13195117
  11. Wang, K., Ouyang, D., Qian, X., Yuan, S., Chang, C., Zhang, J., Liu, Y. (2023). Early Warning Method and Fire Extinguishing Technology of Lithium-Ion Battery Thermal Runaway: A Review. Energies, 16 (7), 2960. https://doi.org/10.3390/en16072960
  12. Majeed, F., Jamal, H., Kamran, U., Noman, M., Ali, M. M., Shahzad, T. et al. (2024). Review–Recent Advances in Fire-Suppressing Agents for Mitigating Lithium-Ion Battery Fires. Journal of The Electrochemical Society, 171 (6), 060522. https://doi.org/10.1149/1945-7111/ad5620
  13. Zhao, J., Xue, F., Fu, Y., Cheng, Y., Yang, H., Lu, S. (2021). A comparative study on the thermal runaway inhibition of 18650 lithium-ion batteries by different fire extinguishing agents. IScience, 24 (8), 102854. https://doi.org/10.1016/j.isci.2021.102854
  14. Tang, X., Hu, J., Liu, T., Hu, S., Zhu, P., Wang, X. (2024). Experimental investigation on the cooling effect of fully submerged fine water mist on lithium-ion batteries in confined space. Applied Thermal Engineering, 239, 122166. https://doi.org/10.1016/j.applthermaleng.2023.122166
  15. Xiao, X., Chen, B., Jin, X., Zeng, Q., Tian, Y., Li, Q. (2024). Experimental Study on the Effect of Synergistic Extinguishing Method Based on Liquid Nitrogen on Lithium-Ion Battery Fire After Thermal Runaway. Fire, 7 (12), 479. https://doi.org/10.3390/fire7120479
  16. Li, X., Li, X., Li, C., Wu, J., Liu, B. (2024). Study on the fire extinguishing effect of compressed nitrogen foam on 280 Ah lithium iron phosphate battery. Heliyon, 10 (11), e31920. https://doi.org/10.1016/j.heliyon.2024.e31920
  17. Ubaldi, S., Di Bari, C., Quinterno, M., De Rosa, A., Mazzaro, M., Ferrigno, G. et al. (2024). Suppression capacity and environmental impact of three extinguishing agents for lithium-ion battery fires. Case Studies in Chemical and Environmental Engineering, 10, 100810. https://doi.org/10.1016/j.cscee.2024.100810
  18. Lazarenko, O., Pazen, O., Velykyi, Y., Parkhomenko, R., Stepaniak, Y. (2024). Determination of Thermal Physical Characteristics of the Panasonic NCR18650b Lithium-Ion Power Supply Element. Proceedings of the Latvian Academy of Sciences. Section B. Natural, Exact, and Applied Sciences., 78 (5-6), 372–379. https://doi.org/10.2478/prolas-2024-0047
  19. Tatsii, R., Pazen, O., Shypot, L. (2021). Research of the temperature field in the system of multilayer cylindrical solid bodies under fire conditions. Fire Safety, 37, 64–71. https://doi.org/10.32447/20786662.37.2020.10
  20. Tatsii, R. M., Pazen, O. Yu. (2018). Direct (Classical) Method of Calculation of the Temperature Field in a Hollow Multilayer Cylinder. Journal of Engineering Physics and Thermophysics, 91 (6), 1373–1384. https://doi.org/10.1007/s10891-018-1871-3
  21. Zhao, C., Hu, W., Meng, D., Mi, W., Wang, X., Wang, J. (2024). Full-scale experimental study of the characteristics of electric vehicle fires process and response measures. Case Studies in Thermal Engineering, 53, 103889. https://doi.org/10.1016/j.csite.2023.103889
Experimental determination of the effect of fire-extinguishing agents on a decrease in the temperature indicators of cylindrical lithium-ion batteries

Downloads

Published

2025-12-31

How to Cite

Lazarenko, O., Pazen, O., Ferents, N., Adolf, I., & Parkhomenko, V.-P. (2025). Experimental determination of the effect of fire-extinguishing agents on a decrease in the temperature indicators of cylindrical lithium-ion batteries. Eastern-European Journal of Enterprise Technologies, 6(10 (138), 22–31. https://doi.org/10.15587/1729-4061.2025.343574