Development of affordable coagulant for intensification lighting natural waters
DOI:
https://doi.org/10.15587/1729-4061.2012.5537Keywords:
Coagulant, water lightening, aluminum hydroxochloridesAbstract
The main source of water supply in Ukraine is the Dnieper River, where water has high color and turbidity rates, and domestic coagulants, even at high doses, cannot provide corresponding lightening and decolouration. Thus the development of effective affordable coagulants is an important task. In the article the method of synthesis of aluminum hydroxychlorides of available sodium hydroxyaluminate and its treatment with calcium and magnesium salts and further dissolution of obtained hydroxyaluminates hydrochloric acid are suggested. It is possible to use the solutions of sodium hydroxyaluminate of different concentrations, because when using calcium and magnesium salts it is possible to separate sodium hydroxyaluminate from dilute solutions. This is important when using the wastes of aluminum alkaline etching. Calcium and magnesium hydroxyaluminates react readily with hydrochloric acid solution forming aluminum hydroxychlorides. In the case of magnesium usage 1/3 of aluminum hydroxochloride is formed, and in the case of calcium usage 2/3 of aluminim hydroxochloride is formed. It is suggested to obtain highly basic 5/6 aluminum hydroxochloride by interaction of aluminum metal with 2/3 of aluminum hydroxochloride.
The efficiency of obtained coagulants was studied on the Dnieper River water sampled in different seasons. As it is seen from the results, efficiency of lightening at sedimentation increases with the increase of the initial turbidity of natural waters, as well as with the increase of dose of coagulant. The cleaning efficiency also increases with the basicity increase of coagulantsReferences
- В.А.Потанина, И.Н.Мясников, Л.М.Сурова.Физико-механическая очистка сточных вод оксихлоридом алюминия // Водоснабжение и санитарная техника. –1988.- №10. – с.22-24.
- Гетманцев С.В./ применение коагулянтов на российских водопроводах// ЭКВАТЭК – 2006: 7-й международный конгресс “Вода: экол. и технол.”, Москва, 30 мая – 2 июня, 2006. Тез. докл. – М. - 2006. – с. 166. – рус.
- Шутько А. П., Басов В. П. Использование алюминийсодержащих отходов промышленных производств. – К.: Тэхника, 1989. – 112 с.
- Гомеля Н. Д., Шабанов М. В., Крысенко Т. В. Пути снижения стоимости коагулянтов // Тезисы докладов на VI Международном симпозиуме «Чистая вода России – 2001».- Екатеринбург, 2001.- С. 109.
- Способ получения основного хлорида алюминия: А.с. 386843 СССР, МКИ СО 1 F7/56. / Б. М. Щепачев, Э. А. Левицкий.- № 1326832; Заявлено 10.03.71; Опубл. 21.05.73, Бюл.№ 27.
- М. Д. Гомеля. Отримання основних солей алюмінію – високоефективних коагулянтів для очищення води // Наукові вісті НТУУ “КПІ”. – 1999. - № 2. – С.150 – 154.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2014 Тетяна Олександрівна Шаблій
This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.
A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.