Research of sedimentation stability of lipid-magnetite suspensions by the method of spectrophotometry
DOI:
https://doi.org/10.15587/1729-4061.2016.69826Keywords:
magnetite, suspension, method, SAS, sedimentation, stability, spectrophotometry, particle size, stabilizationAbstract
A spectrophotometric method of the assessment of stability and determining of the morphological characteristics of lipid-magnetite suspensions (LMS) was studied. The sizes of the particles of magnetite with a surface-active substance (SAS) were defined. The diameter of the particles is 78 nm. The concentration of the particles of magnetite stabilized by a surface–active substance was determined – the concentration (number in 1 cm3) equals N=1.33 ∙ 1012 cm-3 when obtaining a suspension. A slight decrease in the number of particles of magnetite with SAS in 1 cm3 of suspension was observed over time: during 48 hours, the concentration in 1 cm3 decreased from 1.33 ∙1012 down to 1.13 ∙1012 cm-3. The concentration decreases by approximately 2.25 % per 1 hour. Different LMS were obtained. The optimum ratios of the components were selected in the suspensions: magnetite, stabilizer and dispersion medium.
It was established that LMS can be used as biological–active additives, which possess comprehensive action: lipid-magnetite suspensions (LMS) on the basis of magnetite during oral introduction into human organism render beneficial biological effect with the period of action within the range of 3–4 hours: when entering LMS into human organism, the iron concentration in blood rises, which brings about:
– a short-term decrease in intracranial CSF pressure;
– activation of gastric and duodenum performance;
– increase in urination.
Due to bivalent iron and its ability to form transition complexes with oxygen and peroxide radicals (and hydro peroxides), magnetite also manifests antioxidant activity, which makes it possible to recommend it as an antioxidant, which facilitates improvement of the quality and prolongation of the period of storage of fat– containing products. Furthermore, LMS contain magnetite (which means digestible Fe2+); therefore they can be recommended as anti-anemic agent due to easily digestible bivalent iron. Thus, introduction of LMS into food products increases their quality, nutritional and biological value.
Therefore the studies of LMS are actual and they represent significant theoretical and practical interest.References
- Chapa Gonzalez, C., Martínez Pérez, C. A., Martínez Martínez, A., Olivas Armendáriz, I., Zavala Tapia, O., Martel-Estrada, A., & García-Casillas, P. E. (2014). Development of Antibody-Coated Magnetite Nanoparticles for Biomarker Immobilization. Journal of Nanomaterials, 2014, 1–7. doi: 10.1155/2014/978284
- Unterweger, H., Tietze, R., Janko, C., Zaloga, J., Lyer, S., Taccardi, N., … Duerr, S. (2014). Development and characterization of magnetic iron oxide nanoparticles with a cisplatin-bearing polymer coating for targeted drug delivery. International Journal of Nanomedicine, 1, 3659–3676. doi: 10.2147/ijn.s63433
- Cárdenas, W. H. Z., Mamani, J. B., Sibov, T., Caous, C. A., Amaro Jr., E., & Gamarra, L. F. (2012). Particokinetics: computational analysis of the superparamagnetic iron oxide nanoparticles deposition process. International Journal of Nanomedicine, 2699–2712. doi: 10.2147/ijn.s30074
- Cihanovskaja, I. V., Onoprienko, T. A., Kovalenko, V. A., Onoprienko, V. I. (2009). O perspektivah ispol'zovanija magnetita v kachestve biologicheski aktivnyh dobavok. Himija i tehnologija zhirov. Perspektivy razvitija maslo-zhirovoj otrasli. Kharkiv, NII masel i zhirov, 53–54.
- Iljuha, N. G., Barsova, Z. V., Kovalenko, V. A., Cihanovskaja, I. V. (2010). Tehnologija proizvodstva i pokazateli kachestva pishhevoj dobavki na osnove magnetita. Eastern-European Journal of Enterprise Technologies, 6 (10 (48)), 32–35. Available at: http://journals.uran.ua/eejet/article/view/5847/5271
- Denysova, A. Ju., Cyhanovskaja, Y. V., Skorodumova, O. B., Goncharenko, Ja. M., Pryjmak, G. O., Shevchenko, I. V. (2013). Doslidzhennja vplyvu zhyro-magnetytovoi' suspenzii' na termin zberigannja tvarynnyh zhyriv. Part 1. Progresyvna tehnika ta tehnologii' harchovyh vyrobnyctv, restorannogo ta gotel'nogo gospodarstv i torgivli. Ekonomichna strategija i perspektyvy rozvytku sfery torgivli ta poslug. Kharkiv, 71–72.
- Cho, J., Koo, S. (2015). Characterization of particle aggregation in a colloidal suspension of magnetite particles. Journal of Industrial and Engineering Chemistry, 27, 218–222. doi: 10.1016/j.jiec.2014.12.038
- Lou, W., Charalalampopoulos, T. T. (1994). On the Electromagnetic Scattering and Ab-sorption of Agglomerated Small Spherical Particles. Journal of Physics D: Applied Physics, 27 (11), 2258–2270. doi: 10.1088/0022-3727/27/11/004
- Xu, R. Particle Characterization: Light Scattering Methods [Text] / R. Xu. – N.Y.: Kluwer Academic Publishers, 2001. – 410 p.
- Di Stasio, S. (2000). Feasibility of an optical experimental method for the sizing of primary spherules in sub-micron agglomerates by polarized light scattering. Applied Physics B: Lasers and Optics, 70(4), 635–643. doi: 10.1007/s003400050872
- Mulholland, G. W., Donnelly, M. K., Hagwood, C. R., Kukuck, S. R., Hackley, V. A., & Pui, D. Y. H. (2006). Measurement of 100 nm and 60 nm Particle Standards by Differential Mobility Analysis. Journal of Research of the National Institute of Standards and Technology, 111(4), 257–312. doi: 10.6028/jres.111.022
- Ivanov, L. A., Kizevetter, D. V., Kiselev, N. N. et. al. (2006). Izmenenie svetovozvrashhenija ot stekljannyh mikrosharikov i progon kachestva sveto-vozvrashhajushhih pokrytij. Opt. zhurn., 73 (1), 35–40.
- Kizevetter, D. V., Maljugin, V. I. (2009). Odnovremennoe izmerenie razmerov i skorosti dvizhenija chastic. Zhurn. tehn. fiziki, 79 (2), 90–95.
- Ershov, A. E., Isaev, I. L., Semina, P. N., Markel, V. A., & Karpov, S. V. (2012). Effects of size polydispersity on the extinction spectra of colloidal nanoparticle aggregates. Physical Review B, 85(4). doi: 10.1103/physrevb.85.045421
- Karpov, S. V., Isaev, I. L., Gavriljuk, A. P. (2009). Opticheskie spektry kolloidov serebra s pozicii fiziki fraktalov. Kolloid. zhurn., 71 (3), 314.
- Van de Hjulst, G. (1961). Rassejanie sveta malymi chasticami. Moscow: IL, 536.
- Kerker, M. (1969). The scattering of light and other electromagnetic radiation. N.Y., London, Academic Press, 666.
- Xu, R. (2001). Particle Characterization: Light Scattering Methods. N.Y.: Kluwer Academic Publishers, 410.
- Di Stasio, S. (2000). Feasibility of an optical experimental method for the sizing of primary spherules in sub-micron agglomerates by polarized light scattering. Applied Physics B: Lasers and Optics, 70(4), 635–643. doi: 10.1007/s003400050872
- Kizevetter, D. V., Maljugin, V. I. (2009). Odnovremennoe izmerenie razmerov i skorosti dvizhenija chastic. Zhurn. tehn. fiziki, 79 (2), 90–95.
- Papok, I. M. (2012). Using the dynamic light-scattering method for the analysis of a blood-serum model solution. Moscow Univ. Phys. Bull., 67 (5), 452–456.
- Іljuha, M. G., Cihanovs'ka, І. V., Barsova, Z. V., Tіmofeeva, V. P., Vedernikova, І. O. (2010). Patent. na korisnu model' № 54284, MPK S 01 G 49/00. Sposіb otrimannja magnetitu. Published 10.11.2010. Bjul. № 21, 4.
- Klenin, V. I., Shhegolev, S. Ju., Lavrushin, V. I. (1977). Harakteristicheskie fu-nkcii svetorassejanija dispersnyh chastic. Saratov: Izd-vo SGU, 176.
- Klenin, V. I. (1996). Praktikum po kolloidnoj himii. Moscow: Sol', 56.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2016 Alexandr Alexandrov, Iryna Tsykhanovska, Tatуana Gontar, Nicholas Kokodiy
This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.
A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.