Weste products of steel galvanizing processes for obtaining technology of colored glazes
DOI:
https://doi.org/10.15587/1729-4061.2013.14808Keywords:
waste products galvanizing process, electrolyte, crystal phases, milling, glaze, firingAbstract
The subject of this research is glass-forming compounds pegmatite-slag of thermal pover plants-waste products of galvanizing processes based on frits.
The subject of this research is colored low-melt glazes.
The objective of the work is elaboration of compounds and technology obtaining colored glazes using waste products of steel galvanizing processes.
Up-to-date methods of investigation (X-ray phase analysis, differential thermal analysis, flame photometry and optical electroscopy) have been used in this work. Peculiarities of the formation of slimes of steel parts galvanizing and their properties have been investigated. The processes of gas formation in the process of thermal treatment of slimes have been studied in the range of temperatures 293…1773 K. Regularities of crystallization of coloring crystal phases α-Fe2o3, ZnO•Fe2o3 and Feo•Fe2o3 that ensure obtaining colored glazes have been established.
Technology of obtaining low-melt glazes of brown and cherry-brown colors based on low-melt frit without adding additional ceramic pigments with firing temperature 1343…1373 K has been elaborated. It was established, that with the increase of slime content from 10 to 30 weight % in the composition of glazes the color of coating changes from brown to cherry-brown and the purity of color increases from 31 % to 47 %.
The obtained compositions of such glazes were successfully tested under the manufacturing conditions and confirmed the possibility of producing decorative oven ceramic tiles with improved decorative and maintenance properties.
References
- Синюткин А.Н. Утилизация гальванических шламов / А.Н. Синюткин, В.И. Супрунчук, Е.В. Иванюк, О.Б. Костоглод // Вопросы химии и химической технологии. – 2012. –№2. – С.175-178.
- А.с. 1263683, МКИ С 04 В 41/86. Нефриттованная глазурь / М.В. Бек, М.Г. Пона, З.И. Боровец, А.Б. Хомяк, И.В. Солоха, О.Б. Данчук, О.М.Стояновська, О.И. Колтык. – №3885083; заявл. 11.04.85; опубл. 15.10.86, Бюл. №38.
- Такибзева С.С. Применение промышленных отходов для получения легкоплавких глазурей / С.С. Такибзева, Ч.Х. Нугманова, С.У. Кулахметова // Строительные материалы на основе различных отходов промышленности Казахстана. – Алма-Ата, 1989– С.82-85.
- Тищенко Г.П. Утилизация промышленных отходов гальванических производств/ Г.П. Тищенко, Н.Ю. Мойсеенко, В.С. Журавлев // Обз. инф. Сер. Актуальные вопросы хим. науки и технолог. охраны окруж. среды. НИИтехим. – 1991. – №3. – С.1-84.
- Мороз И.И. Справочник по фарфоро-фаянсовой промышленности / И.И. Мороз, М.С. Комская, Л.Л. Олейникова. – Т.2. – М.: Легкая индустрия, 1980. – 352 с.
- Пищ И.В. Керамические пигменты / И.В. Пищ, Г.Н. Масленникова. – Мн.: Выш. шк., 1987. – 132 с.
- Kerstan W. Keramische Glasuren – Aufbau, Fargebund, Dekortechniken und Rohstoffe/ W. Kerstan // Sprechsaal. – 1988. – 121, №8. – С. 636-639.
- Wakamatsu M. Effect of firing atmosphere on the color of iron glazes / M. Wakamatsu, T. Nobuyuki, I. Shingo //Asashi Glass Found. Ind. Technol. 1 . – 1990. – 56. – P. 243-252.
- Туманов С.Г. Синтез керамических красок / С.Г. Туманов // Физико-химические основы керамики . – М.: Промстройиздат, 1956. – С. 237-292.
- Беленький Е.Ф. Химия и технология пигментов / Е.Ф. Беленький, И.В. Рискин . – Л.: Химия, 1974. – 27 с.
- Siniutkin, A. N., Suprunchuk, V. I., Ivaniuk, E.V., Kostoglod, O. B. (2012). Recycling of galvanizing weste / A.N. Siniutkin, // Voprosy khimii i khimicheskoy tekhnologii, 2, 175-178.
- Bek, M.V., Pona, M.G., Borovets, Z.I., Khomiak, A.B., Solokha, I.V., Danchuk, O.B., Stoianovska, O.M., Koltyk, O.I. (1986) Non-frite glaze / M.V. Bek, // А.S. 1263683, МКI С 04 В 41/86, № 3885083.
- Takibzeva, S.S., Nugmanova, C.K., Kulakhmetova, S.U. (1989) Apply plants-waste for obtaining low-melt glazes / S.S. Takibzeva, // Building materials on a basis of different plant-waste of Kazakhstan, Alma-Ata, 82-85.
- Tishchenko, G.P., Moiseenko, N.U., Zhuravlyov, V.S. (1991) Recycling of plants-waste galvanizing materials / G.P. Tishchenko, / Actual problems of chemical science and technology of environment. NIItechkhim, 3, 1-84.
- Moroz, I.I., Komskaya, M.S., Oleinikova, L.L. (1980) Reference book of porcelain-faience industry / I.I. Moroz, // B.2. – М., Liglit industry, 352.
- Pishch, I.V., Maslennikova, G.N. (1987) Ceramic pigments / I.V. Pishch, // Мinsk, High school, 132 p.
- Kerstan, W. (1988) Keramische Glasuren Aufbau, Fargebund, Dekortechniken und Rohstoffe / W. Kerstan, // Sprechsaal, 121, 8, 636-639.
- Wakamatsu, M., Nobuyuki, T., Shingo, I. (1990) Effect of firing atmosphere on the color of iron glazes / M. Wakamatsu, // Asashi Glass Found. Ind. Technol. 1, 56, 243-252.
- Tumanov, S.G. (1956) Syntesis of the ceramic paints / S.G. Tumanov, // Physical-chemical basis of ceramics, М., Promstroyizdat, 237-292.
- Bielienkiy, I.F., Riskin, I.V. (1974) Chemistry and technology of pigments / I.F. Bielienkiy, // L., Chemistry, 27.
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Copyright (c) 2014 Орест Миронович Вахула, Ігор Вікторович Позняк, Іван Володимирович Солоха, Мирон Григорович Пона, Зенон Іванович Боровець
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