Development of distillation scheme of acetic acid with low iodic compounds content

Authors

  • Максим Евгеньевич Шепелев Institute of Chemical Technology Volodymyr Dahl’s East Ukrainian National University Lenina street 31, Rubezhnoye, Luhans'ka oblast, 93010, Ukraine
  • Сергей Алексеевич Кондратов Institute of Chemical Technology Volodymyr Dahl’s East Ukrainian National University Lenina street 31, Rubezhnoye, Luhans'ka oblast, 93010, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2013.19140

Keywords:

acetic acid, iodides, distillation, mathematical modeling, scheme, carbonylation, methanol, impurities

Abstract

The problem of obtaining acetic acid with low content of iodides is considered in the paper. The purpose of the research is to identify ways of the ingress of iodine impurities into commodity acetic acid and to find ways of reduction of the amount of these pollutants to the level no more than 10 p.p.b. The structure of material flows of current production of acetic acid was studied, using the methods of fractional distillation, chromatographic analysis and mathematical modeling. The formation of more than 30 side compounds with a high and low volatility in the system was revealed. Based on the results it was shown that relatively volatile by-products - low-molecular iodine compounds, are formed of the low-volatile iodine compounds, entering the distillation stage from the synthesis unit. The way of reducing the content of iodine-containing impurities in the commodity acetic acid to the level no more than 10 p.p.b was proposed. The synthesis of the advanced technological scheme was carried out. The research results can be used in the design of production of acetic acid by methanol carbonylation.

Author Biographies

Максим Евгеньевич Шепелев, Institute of Chemical Technology Volodymyr Dahl’s East Ukrainian National University Lenina street 31, Rubezhnoye, Luhans'ka oblast, 93010

Postgraduate

Сергей Алексеевич Кондратов, Institute of Chemical Technology Volodymyr Dahl’s East Ukrainian National University Lenina street 31, Rubezhnoye, Luhans'ka oblast, 93010

Dr. Sc. (chemistry), Professor

The head of the department of mathematics and computer technologies

References

  1. Agreda, V. H. Acetic Acid and Its Derivatives [Текст] / V. H. Agreda // Chemical Industries. – 1993. - 49.
  2. Паулик, Е. Ф. Способ получения алифатических или ароматических карбоновых кислот и/или сложных эфиров [Текст] / Е. Ф. Паулик; заявитель и патентообладатель Monsanto Company // Патент СССР. – 1974. – №453824.
  3. Paulik, E. F. Production of carboxylic acids and esters [Текст] / E. F. Paulik // assignee Monsanto Company, St. Louis, Mo // United States Patent. – 30.10.1973. - №3769329.
  4. Ло, Д. Д. Способ получения уксусной кислоты [Текст]/ Д. Д. Ло и др.; заявитель и патентообладатель БП Кэмикелз Лимитед // Патент РФ. – 2005. – №2336263.
  5. Тьебо, Д. М. Способ непрерывного производства уксусной кислоты и/или метилацетата [Текст] / Д. М. Тьебо, Д. А. Маршан, Ф. Д. Кальк та ін.; заявитель и патентообладатель Ацетикс Шимми // Патент Україна. – 2007. – №79086.
  6. Nobel, D. Process for the preparation of carboxylic acids or corresponding esters in presence of a catalyst based on rhodium and iridium [Текст] / D. Nobel; заявитель и патентообладатель Rhone poulenc chimie // Patent EP. – 15.10.1994. - №0618184.
  7. Ming, L. Ab initio study on the mechanism of rhodium-complex-catalyzed carbonylation of methanol to acetic asid [Текст]/ L. Ming, F. Wenlin, H. Maorong [et al.] // Science in china. Ser. B. – 2001. – № 5. – P. 465-472.
  8. Eubanks, L. S. Purification of carboxylic acids by plural stage distillation with side stream draw-offs [Текст] / L. S. Eubanks; assignee Monsanto Company, St. Louis, Mo // United States Patent. – 30.10.1973. - №3769177
  9. Eby, Roy T. Purification of acetic acid [Текст] / Roy T. Eby; assignee Monsanto Company, St. Louis, Mo // United States Patent. – 02.08.77. - №4039395
  10. William, R. Purification of acetic acid streams by distillation [Текст] / R. William; assignee Monsanto Company, St. Louis, Mo // United States Patent. – 13.11.1973. - №3772156
  11. Prise, Jerry L. Purification of carbonylation products [Текст] / Jerry L. Prise; assignee Monsanto Company, St. Louis, Mo // United States Patent. – 25.07.1978. - №4102922
  12. Prise, Jerry L. Purification of acetic acid streams by distillation [Текст] / Price, et al.; assignee Monsanto Company, St. Louis, Mo // United States Patent. – 14.06.1977. - №4029553
  13. Шатохін, В. Ф. Спосіб виділення оцтової кислоти із продуктів карбонілювання [Текст] / В. Ф. Шатохін, А. Л. Вакуленко, М. І. Рязанцев та ін.; заявитель и патентообладатель ЗАТ «Сєвєродонецьке об’єднання Азот» // Патент Україна. – 15.06.2004. - №36929
  14. Джонес, М. Д. Способ удаления примесей алкилйодидов из жирных карбоновых кислот и/или соответствующих ангидридов кислот, содержащих также примеси ионов металлов [Текст] / М. Д. Джонес, Д. Д. Ватсон, Б. Л. Вильямс; заявитель и патентообладатель БП Кемикэлс Лтд // Патент РФ. – 27.09.1997. - №2091365
  15. Коган, В. Б. Равновесие между жидкостью и паром: справочник пособие в 2 т. [Текст] / В. Б. Коган, В. М. Фридман, В. В. Кафаров // М-Л.: Наука.– Т.1. – 1966. – C. 642.
  16. Зельвенский, Я. Д. Ректификация разбавленных растворов [Текст] / Я. Д. Зельвенский, А. А. Титов, В. А. Шалыгин // Л.: Химия. – 1974. – C.216
  17. Стабников, В. Н. Перегонка и ректификация этилового спирта [Текст]/ В. Н. Стабников // М.: Пищевая промышленность. – 1969. – C.456
  18. Agreda, V.H. (1993). Acetic Acid and Its Derivatives. Chemical Industries, 49.
  19. Paulik, E.F. (1974). The method of aliphatic or aromatic carbonic acids and/or esters production. USSR Patent, № 453824.
  20. Paulik, E.F. (1973). Production of carboxylic acids and esters. United States Patent, № 3769329.
  21. Lo, D. D. (2005). The method of acetic acid production. RU Patent, №2336263.
  22. Tiebo, D. M., Marshan, D. A., Kalk, F. D. et al.(2007). The method of incessant production of acetic acid and/or methylacetate. Ukraine Patent, №79086.
  23. Nobel, D. (1994). Process for the preparation of carboxylic acids or corresponding esters in presence of a catalyst based on rhodium and iridium. European Patent. №0618184.
  24. Ming, L., Wenlin, F., Maorong, H. et al. (2001). Ab initio study on the mechanism of rhodium-complex-catalyzed carbonylation of methanol to acetic asid. Science in China. Ser. B., 5, 465-472.
  25. Eubanks, L. S. (1973). Purification of carboxylic acids by plural stage distillation with side stream draw-offs. United States Patent, № 3769177.
  26. Eby Roy, T. (1977). Purification of acetic acid. United States Patent, № 4039395.
  27. William, R. (1973). Purification of acetic acid streams by distillation. United States Patent, № 3772156.
  28. Prise (1978). Purification of carbonylation products. United States Patent, № 4102922.
  29. Price (1977). Purification of acetic acid streams by distillation. United States Patent, № 4029553.
  30. Shatohin, V. F. (2004). The method of extracting of acetic acid from carbonilation products. Ukraine Patent, №36929.
  31. Djones, M. D. (1997). The method of removal alkiliodide impurities from fatty acids and/or anhydrides containing also metal impurites. RU Patent, №2091365
  32. Kogan, V., Friedman, V., Kafarov, V. (1966). The equilibrium between liquid and vapor, 1440.
  33. Zekvensky, J. D., Titov, A. A., Shaligin, B. A. (1974). Rectification of dilute solutions, 216.
  34. Ctabnikov, V. N. Distillation and rectification of ethyl alcohol. Pischevaja promishlennost, 456.

Downloads

Published

2013-12-17

How to Cite

Шепелев, М. Е., & Кондратов, С. А. (2013). Development of distillation scheme of acetic acid with low iodic compounds content. Eastern-European Journal of Enterprise Technologies, 6(6(66), 36–39. https://doi.org/10.15587/1729-4061.2013.19140

Issue

Vol. 6 No. 6(66) (2013): Technology of organic and inorganic substanse

Section

Technology organic and inorganic substances

License

Copyright (c) 2014 Максим Евгеньевич Шепелев, Сергей Алексеевич Кондратов

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.

A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.